자원리싸이클링 (Resources Recycling)

  • 제29권5호
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  • Pages.55-63
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  • 2020
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  • 2765-3439(pISSN)
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  • 2765-3447(eISSN)
한국자원리싸이클링학회 (The Korean Institute of Resources Recycling)
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유기인산계 추출제로 합성한 이온성액체에 의한 묽은 염산용액에서 코발트(II)와 니켈(II)의 추출분리

Solvent Extraction Separation of Co(II) and Ni(II) from Weak Hydrochloric Acid Solution with Ionic Liquids Synthesized from Organophosphorus Acids

  • 문현승 (목포대학교 공과대학 신소재공학과) ;
  • 송시정 (목포대학교 공과대학 신소재공학과) ;
  • ;
  • 이만승 (목포대학교 공과대학 신소재공학과)
  • Moon, Hyun Seung (Department of Advanced Material Science & Engineering, Institute of Rare metal, Mokpo National University) ;
  • Song, Si Jeong (Department of Advanced Material Science & Engineering, Institute of Rare metal, Mokpo National University) ;
  • Tran, Thanh Tuan (Department of Advanced Material Science & Engineering, Institute of Rare metal, Mokpo National University) ;
  • Lee, Man Seung (Department of Advanced Material Science & Engineering, Institute of Rare metal, Mokpo National University)
  • 투고 : 2020.09.15
  • 심사 : 2020.10.06
  • 발행 : 2020.10.30
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⟨ 이전 논문 다음 논문 ⟩

초록

묽은 염산용액에서 이온성액체에 의한 코발트(II)와 니켈(II)의 분리를 조사하기 위해 이온성액체의 종류와 농도 및 수상의 초기 pH를 변화시켜 추출실험을 수행했다. 본 논문에서는 유기인산(D2EHPA, PC88A, Cyanex 272, Cyanex 301)을 Aliquat 336과 반응시켜 제조한 이온성액체와 Aliquat 336의 염소이온을 SCN과 치환한 이온성액체를 사용했다. 세 종류의 이온성액체(ALi-D2, ALi-PC, ALi-CY272)에 코발트(II)가 니켈(II)보다 추출이 잘 되었으며 평형 pH가 초기 pH보다 높았다. ALi-CY301의 경우 코발트(II)와 니켈(II)의 선택도는 추출조건에 의존했다. 또한 상기 이온성액체에 TBP의 첨가가 두 금속의 추출에 미치는 영향도 조사했다. 추출제로 ALi-SCN를 사용하는 조건에서 코발트(II)가 선택적으로 추출되어 두 금속을 완전히 분리하는 것이 가능했다.

In order to investigate the separation of Co(II) and Ni(II) by ionic liquids from weak hydrochloric acid solutions, extraction experiments were performed by changing the type and concentration of ionic liquids and the initial pH of the aqueous phase. Two kinds of ionic liquids based on Aliquat 336 were employed in this work; one was synthesized by reacting organophosphorus acids(D2EHPA, PC88A, Cyanex 272, Cyanex 301) with Aliquat 336 and the other was prepared by exchanging the chloride ion of Aliquat 336 with SCN-. The three types of ionic liquids (ALi-D2, ALi-PC, and ALi-CY272) showed better extraction of Co(II) than Ni(II), and the equilibrium pH was higher than the initial pH. In the case of ALi-CY301, the selectivity of Co(II) and Ni(II) depended on the extraction conditions. In addition, the effect of the addition of TBP to the ionic liquid on the extraction of two metals was also investigated. Employment of ALi-SCN as an extractant resulted in selective extraction of Co(II) and complete separation of the two metal ions was possible.

키워드

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