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Characteristics for Heavy Metal Pollution in Road Dust from Daebul Industrial Complex: Classification by Particle Size and Magnetic Separation

대불산업단지 도로먼지 내 중금속류 오염 특성: 입도와 자성에 따른 구분

  • Jeong, Hyeryeong (Marine Environmental Research Center, Korea Institute of Ocean Science & Technology (KIOST)) ;
  • Choi, Jin Young (Marine Environmental Research Center, Korea Institute of Ocean Science & Technology (KIOST)) ;
  • Ra, Kongtae (Marine Environmental Research Center, Korea Institute of Ocean Science & Technology (KIOST))
  • 정혜령 (한국해양과학기술원 해양환경연구센터) ;
  • 최진영 (한국해양과학기술원 해양환경연구센터) ;
  • 나공태 (한국해양과학기술원 해양환경연구센터)
  • Received : 2020.04.01
  • Accepted : 2020.08.05
  • Published : 2020.08.31

Abstract

In this study, we investigated physical and chemical properties such as grain size, heavy metal pollution, magnetic properties, and their environmental impacts of road dusts (RD) collected from 14 sampling points in Daebul industrial Complex. Heavy metal concentrations in RD were in the order of Fe>Zn>Cu>Pb>Cr>Ni>As>Cd>Hg, and this pollution pattern was related to major industries and traffic activities in this area. The results of the correlation analysis between heavy metal elements and particle size in RD showed that Fe and all of analyzed heavy metals had a significant correlation with each other and metal concentrations had a significantly negative correlation (p<0.05). However, due to the input of large metal particles some heavy metal concentrations in the particle fraction of >1000 ㎛ were highest. Pollution load per unit area of this fraction was the highest among the grain size fractions. Cr, Ni, Cu, Zn, Cd, Pb levels in RD decreased and the levels of Cr, Ni, Cu, Zn, Cd, and Pb were reduced to 85 (As) -22 (Ni)% of the whole after removal of MFs fraction from RD. The mean heavy metal levels in the study area did not exceed the soil contamination guide value of Korea, indicating that heavy metal levels in RD were not a concern. However, at some sampling points, Zn concentrations were exceeded the soil contamination guide value for the 3rd areas of Korea and this result indicated that further studies of the impact of RD on the surrounding environment through re-suspension or non-point pollution, and of effective management methods are required.

본 연구에서는 대불산업단지 내 14개 지점에서 채취한 도로먼지의 입도, 중금속 성분, 자기특성 등 물리 화학적 특성을 파악하고, 오염도 평가를 통해 주변 환경에 미치는 영향에 대한 고찰을 시행하였다. 도로먼지 내 금속농도는 Fe>Zn>Cu>Pb>Cr>Ni>As>Cd>Hg 순이었으며, 중금속류 오염은 연구지역의 주요 산업 및 교통 활동에 영향을 받은 것으로 나타났다. 도로먼지 내 중금속 원소와 입도와의 상관관계 분석결과는 Fe 및 모든 분석된 원소가 서로 유의한 상관관계를 가지며, 입자크기와는 유의한 음의 상관성을 가짐을 보여주었다(p<0.05). 그러나 큰 금속 입자들의 노면 유입으로 인해 일부 금속의 경우 >1000 ㎛의 입자의 중금속류 농도가 가장 높았으며, 이 분율의 단위면적당 오염부하량이 다른 입도분율보다 높았다. 도로먼지에서 자성입자의 분리 후 Cr, Ni, Cu, Zn, Cd, Pb의 농도 수준이 전체의 85(As)-22(Ni)%로 감소함을 알 수 있었다. 연구지역 도로먼지의 평균 중금속 오염도는 3지역 토양환경 우려기준을 초과하지 않아 우려할 수준은 아닌 것으로 나타났으나, 일부 지점의 경우 Zn 농도 기준을 초과해 재 비산이나 비점오염유출 등을 통해 도로먼지가 주변 환경에 미치는 영향과 효과적 관리방법에 대한 더욱 자세한 연구가 필요한 것으로 판단된다.

Keywords

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