Journal of Electrochemical Science and Technology

The Korean Electrochemical Society (한국전기화학회)
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Cathodic Electrochemical Deposition of Highly Ordered Mesoporous Manganese Oxide for Supercapacitor Electrodes via Surfactant Templating

  • Lim, Dongwook (Department of Chemistry and Chemical Engineering, Center for Design and Applications of Molecular Catalysts, Inha University) ;
  • Park, Taesoon (Department of Chemistry and Chemical Engineering, Center for Design and Applications of Molecular Catalysts, Inha University) ;
  • Choi, Yeji (Department of Chemistry and Chemical Engineering, Center for Design and Applications of Molecular Catalysts, Inha University) ;
  • Oh, Euntaek (Department of Chemistry and Chemical Engineering, Center for Design and Applications of Molecular Catalysts, Inha University) ;
  • Shim, Snag Eun (Department of Chemistry and Chemical Engineering, Center for Design and Applications of Molecular Catalysts, Inha University) ;
  • Baeck, Sung-Hyeon (Department of Chemistry and Chemical Engineering, Center for Design and Applications of Molecular Catalysts, Inha University)
  • Received : 2019.10.01
  • Accepted : 2019.12.09
  • Published : 2020.05.31
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Abstract

Highly ordered mesoporous manganese oxide films were electrodeposited onto indium tin oxide coated (ITO) glass using sodium dodecyl sulfate (SDS) and ethylene glycol (EG) which were used as a templating agent and stabilizer for the formation of micelle, respectively. The manganese oxide films synthesized with surfactant templating exhibited a highly mesoporous structure with a long-range order, which was confirmed by SAXRD and TEM analysis. The unique porous structure offers a more favorable diffusion pathway for electrolyte transportation and excellent ionic conductivity. Among the synthesized samples, Mn2O3-SDS+EG exhibited the best electrochemical performance for a supercapacitor in the wide range of scan rate, which was attributed to the well-developed mesoporous structure. The Mn2O3 prepared with SDS and EG displayed an outstanding capacitance of 72.04 F g-1, which outperform non-porous Mn2O3 (32.13 F g-1) at a scan rate of 10 mV s-1.

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References

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