Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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Preparation and Comparison the Physical Properties of Polyurethane-Urea Using Biomass Derived Isosorbide

바이오매스 유래 이소소르비드를 이용한 폴리우레탄-우레아의 제조 및 특성 비교

  • Park, Ji-Hyeon (Department of Organic Material Science and Engineering, Pusan National University) ;
  • Park, Jong-Seung (Department of Organic Material Science and Engineering, Pusan National University) ;
  • Choi, Pil-Jun (Korea Institute of Footwear and Leather Technology) ;
  • Ko, Jae-Wang (Korea Institute of Footwear and Leather Technology) ;
  • Lee, Jae-Yeon (Korea Institute of Footwear and Leather Technology) ;
  • Sur, Suk-Hun (Korea Institute of Footwear and Leather Technology)
  • 박지현 (부산대학교 유기소재시스템공학과) ;
  • 박종승 (부산대학교 유기소재시스템공학과) ;
  • 최필준 (한국신발피혁연구원) ;
  • 고재왕 (한국신발피혁연구원) ;
  • 이재년 (한국신발피혁연구원) ;
  • 서석훈 (한국신발피혁연구원)
  • Received : 2019.08.22
  • Accepted : 2019.09.18
  • Published : 2019.09.27
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Abstract

Polyurethane-ureas(PUUs) were prepared from 4,4'-methylenebis(cyclohexyl isocyanate) and various diols including isosorbide. Isosorbide is starch-derived monomer that exhibit a wide range of glass transition temperature and are therefore able to be used in many applications. PUU was synthesized by a pre-polymer polymerization using a catalyst. Successful synthesis of the PUU was characterized by fourier transform-infrared spectroscopy. Thermal properties were determined by differential scanning calorimetry, thermogravimetric analysis, and dynamic mechanical analysis. It was found that by tuning isosorbide content in the resin, their glass transition temperature(Tg) slightly decreased. Physical properties were also determined by tensile strength and X-ray diffraction. There is no significant differences between petroleum-derived diol and isosorbide in XRD analysis. Moreover, their physical and optical properties were determined. The result showed that the poly(tetramethylene ether glycol)/isosorbide-based PUU exhibited enhanced tensile strength, transmittance, transparency and biodegradability compared to the existing diols. After 11 weeks composting, the biodegradability of blends increased in ISB-PUU. The morphology of the fractured surface of blend films were investigated by scanning electron microscopy.

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References

  1. H. Chbib, M. Faisal, A. E. Hussieny, I. S. Fahim, and N. M. Everitt, The Future of Biodegradable Plastics from an Environmental and Business Perspective, Modern Approaches on Material Science, 1(2), 43(2019).
  2. J. S. Oh and S. B. Kwak, Biopolymers in Automotive Components : Bio-Polyurethane, Rubber Technology, 16(2), 75(2015).
  3. J. V. Cauich-rodriguez, L. H. Chan-chan, F. Hernandezsanchez, and J. M. Cervantes-uc, "Degradation of Polyurethanes for Cardiovascular Applications", Intech Open Access Publisher, London, pp.51-82, 2012.
  4. M. Rose and R. Palkovits, Isosorbide as a Renewable Platform Chemical for Versatile Applications-Quo Vadis?, Chem Sus Chem, 5, 167(2012). https://doi.org/10.1002/cssc.201100580
  5. T. S. Gaaz, A. B. Sulong, M. N. M. Ansari, A. A. H. Kadhum, A. A. A. Amiery, andM. H. Nassir, Effects of Starch Loading on theThermo-Mechanical and Morphological Properties of Polyurethane Composite, Materials, 10, 777(2017). https://doi.org/10.3390/ma10070777
  6. F. Fenouillot, A. Rousseau, G. Colomines, R. Saint- Loup, and J. P. Pascault, Polymers from Renewable 1,4:3,6-dianhydrohexitols(isosorbide, isomannide and isoidide): A Review, Progress in Polymer Science, 35, 578(2010). https://doi.org/10.1016/j.progpolymsci.2009.10.001
  7. C. H. Lee, M. Kato, and A. Usuki, Preparation and Properties of Bio-based Polycarbonate/clay Nanocomposites, Materials Chemistry, 21, 6844(2011). https://doi.org/10.1039/c1jm10087d
  8. R. M. Gohil, Properties and Strain Hardening Character of Polyethylene Terephthalate Containing Isosorbide, Polymer Engineering and Science, 49, 544(2009). https://doi.org/10.1002/pen.20840
  9. V. Besse, R. Auvergne, S. Carlotti, G. Boutevin, B. Otazaghine, S. Caillol, J. P. Pascault, and B. Boutevin, Synthesis of Isosorbide Based Polyurethanes: An Isocyanate Free Method, Reactive and Functional Polymers, 73, 588(2013). https://doi.org/10.1016/j.reactfunctpolym.2013.01.002
  10. J. Lukaszczyk, B. Janicki, and M. Kaczmarek, Synthesis and Properties of Isosorbide based Epoxy Resin, European Polymer Journal, 47, 1601(2011). https://doi.org/10.1016/j.eurpolymj.2011.05.009
  11. F. Zhang, Q. Wang, L. Wang, and Y. Bai, Implementing Plant-derived Isosorbide and Isomannide as Comonomers for Polyester Synthesis: Effects of Crystallization Properties on Optical Properties, Applied Polymer, 134, 45444(2017). https://doi.org/10.1002/app.45444
  12. J. H. Moon, S. B. Kwak, J. Y. Lee, and J. S. Oh, Recent Development in Polyurethanes for Automotives, Elastomers and Composites, 52(4), 249(2017). https://doi.org/10.7473/EC.2017.52.4.249
  13. J. W. Ock, P. G. Kim, H. S. Cho, O. K. Kwon, W. W. Jung, and J. S. Koh, Synthesis and Characterization of Eco-friendly Polyurethane Incorporating Soybean-oilbased Polyol, Textile Science and Engineering, 52(5), 320(2015). https://doi.org/10.12772/TSE.2015.52.320
  14. H. N. Kim, D. W. Lee, H. Ryu, G. S. Song, and D. S. Lee, Preparation and Characterization of Isosorbide- Based Self-Healable Polyurethane Elastomers with Thermally Reversible Bonds, Molescules, 24, 1061 (2019). https://doi.org/10.3390/molecules24061061
  15. K. I. Ra, B. S. Seo, S. W. Seo, and H. S. Lee, Effects of Cross-Linking Agent on Mechanical Properties and Thermal Stability of Polyurethanes, Textile Science and Engineering, 38(4), 155(2001).
  16. T. S. Kim and C. Y. Park, Morphological, Thermal and Dynamical Properties of Polyurethane ProductwithVarious Contents of Acrylic Polyol, Elastomers and Composites, 48(4), 276(2013). https://doi.org/10.7473/EC.2013.48.4.276
  17. J. R. Fried, "Polymer Science and Technology, 2nd ed.", Prentice Hall PTR, New Jersy, pp.180-182, 2003.
  18. R. Hernandez, J. Weksler, A. Padsalgikar, and J. Runt, Microstructural Organization of Three-phase Polydimethylsiloxane- based Segmented Polyurethanes, Macromolecules, 40, 5441(2007). https://doi.org/10.1021/ma070767c
  19. K. Kojio, K. Matsuo, S. Motokucho, K. Yoshinaga, Y. Shimodaira, and K. Kimura, Simultaneous Small-angle X-ray Scattering/wide-angle X-ray Diffraction Study of the Microdomain Structure of Polyurethane Elastomers during Mechanical Deformation, Polymer Journal, 43, 692(2011). https://doi.org/10.1038/pj.2011.48
  20. J. Hu, C. Tao, A. Yuan, J. Bao, Q. Cheng, G. Xu, and Y. Huang, Effects of Isosorbide on the Microphase Separation and Properties of Waterborne Polyurethane Coatings, Polymer, 43(2), 169(2019).
  21. K. K. Choi, Preparation and Characterization of Castor Oil Based Biopolyurethane, M.S. Thesis, Hanyang University, 2015.
  22. S. Y. Oh, M. S. Kang, J. C. Knowles, and M. S. Gong, Synthesis of Bio-based Thermoplastic Polyurethane Elastomers containing Isosorbide and Polycarbonate Diol and their Biocompatible Properties, Journal of Biomaterials Applications, 30(3), 327(2015). https://doi.org/10.1177/0885328215590054