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Effect of Rare Earth Metal on Catalyst for Hydrogenation Reaction

희토류가 수소화 촉매에 미치는 영향

  • An, Jae Young (Department of Chemical Engineering, Kongju National University) ;
  • Jeon, Jong-Ki (Department of Chemical Engineering, Kongju National University)
  • Received : 2018.02.09
  • Accepted : 2018.03.13
  • Published : 2018.03.30

Abstract

As industry and medicine developed, many people became interested in the quality of life. As the concern for health became higher, vegetarian or vegetable oils became more popular than meat. With the development of processes primarily using nickel catalysts today, the shelf life of vegetable oils has increased and mobility has become more convenient. Currently nickel catalysts for the curing of oil are dominated by foreign companies in the world market. On the other hand, the mass production technology of domestic nickel catalyst is backward, and the entire amount is imported from foreign countries. Therefore, there is a need for active research and development of a catalyst that can be commercialized in korea. In this study, nickel as a main active catalyst was used as a base for hydrogen curing reaction, and the effect of rare earth on catalytic activity was investigated. A certain amount of rare earths could induce the dispersion of nickel to increase efficiency and use as co-catalyst.

산업과 의학이 발전되면서 많은 인구는 삶의 질에 관심을 가지게 되었다. 건강에 대한 시각이 높아지면서 육류보다 채식 또는 식물성 오일을 선호하게 되었다. 오늘날 주로 니켈 촉매를 사용한 공정이 개발되면서 식물성 오일의 보존기간이 늘어나고 이동성이 편리해졌다. 현재 유지경화용 니켈 촉매는 외국기업이 세계시장을 장악하고 있다. 한편, 국내 니켈 촉매의 대량 생산 기술은 퇴보 되어 전량 외국에서 수입하고 있는 실정이다. 따라서 활발한 기초연구가 필요하고 국내에서 상용화 할 수 있는 촉매개발이 필요하다. 본 연구는 수소화 반응으로부터 유지경화에 기반이 되는 니켈을 주 활성 촉매제로 사용하였고, 희토류가 촉매의 활성에 주는 영향을 알아보았다. 일정량의 희토류는 니켈의 분산을 유도하여 효율을 증가시키고 조촉매로써 사용이 가능하였다.

Keywords

References

  1. Z. Babaee, H. Nikoopour, H. Safafar, “A Comparison of Commercial Nickel Catalysts Effects on Hydrogenation of Soybean Oil,” World Appl Sci J, Vol. 2, No. 6, pp. 621-626, (2007).
  2. V. L. Barrio, P. L. Arias, J. F. Cambra, M. B. Guemez, B. Pawelec, J. L. G. Fierro, "Aromatics Hydrogenation on Silica-Alumina Supported Palladium-Nickel Catalysts," Appl. Catal., A, Vol. 242, pp. 17-30, (2003). https://doi.org/10.1016/S0926-860X(02)00489-1
  3. R. R. Allen, "World Conference on Soya Processing and Utilization," JAOCS, pp. 166-169, (1981).
  4. H. B. W. Patterson, "Hydrogenation of Fats and Oils," Appl. Sci. Publishers, London, (1990).
  5. G. A. Martin, J. A. Dalmon, "Benzene Hydrogenation over Nickel Catalysts at Low and High Temperatures: Structure-Sensitivity and Copper Alloying Effects," Journal of catalysis, Vol. 75, pp. 233-242, (1982). https://doi.org/10.1016/0021-9517(82)90205-6
  6. A. V. Kravtsov, V. A. Zuev, I. A. Kozlov, A. V. Milishnikov, E. D. Ivanchina, E. M. Uriev, E. N. Ivashkina, V. A. Fetisova, I. O. Shnidorova, “Development of Control System for Nickel-Containing Catalyst in Dienes Hydrogenation,” Pet. Coal, Vol. 51, No. 4, pp. 248-254, (2009).
  7. D. Lee, D. Kim, M. Kang, J. M. Kim, I. Lee, "Efficient Hydrogenation Catalysts of Ni or Pd on Nanoporous Carbon Workable in an Acidic Condition," Bull. Korean Chem. Soc., Vol. 28, No. 11, (2007).
  8. T. Kim, I. Cha, H. Lee, W. Ahn, “A Study on the Preparation of Oil Hydrogenation Catalysts Using Nickel Extracted from Spent Catalysts,” J. Korean Ind. Chem., Vol. 5, No. 6, pp. 925-934, (1994).
  9. S. L. Kiperman, "Some Problems of Chemical Kinetics in Heterogeneous Hydrogenation Catalysis," Stud. Surf. Sci. Catal., Vol. 27, No. 1, (1986).
  10. S.-H. Lee, H. Matsushita, G. Koch, J. Zimmermann, B. Clapham, K. D. Janda, "Smart Cleavage Reactions: the Synthesis of an Array of Ureas from Polymer-Bound Carbamates," J. Comb. Chem., Vol. 6, pp. 822-827, (2004). https://doi.org/10.1021/cc049916i
  11. B. H. Ahn, “Synthesis of Monodispersed Magnetic Polymer Particle,” J. Korean Soc. Ind. Eng. Chem., Vol. 19, No. 3, pp. 316-321, (2008).
  12. A. V. Kravtsov, A. C. Khadartsev, A. A. Shatovkin, A. V. Milishnikov, E. D. Ivanchina, E. M. Ivashkina, E. N. Uriev, "Computer Modeling of Higher Paraffins Dehydrogenation Process on Pt Catalysts," Oil Processing and Oil Chem., pp. 35-40, (2007).
  13. C. N. Satterfield, "Heterogeneous Catalysis in Practice," McGraw-Hill Book Co., New York, pp. 80-83, (1980).
  14. C. A. BROWN, "Catalytic Hydrogenation. V.' The Reaction of Sodium Borohydride with Aqueous Nickel Salts. P-1 Nickel Boride, a Convenient, Highly Active Nickel Hydrogenation Catalyst," J. Org. Chem., Vol. 56, No. 6, (1970).
  15. J. Dusan, R. b. Radoman, M. Ljiljana, S. Miroslav, M. Branislav, "Nickel Hydrogenation Catalyst for Tallow Hydrogenation and for the Selective Hydrogenation of Sun¯Ower Seed Oil and Soybean Oil," Catal. Today, Vol. 43, pp. 21-28, (1998). https://doi.org/10.1016/S0920-5861(98)00133-3