대한화학회지 (Journal of the Korean Chemical Society)

  • 제62권2호
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  • Pages.79-86
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  • 2018
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  • 1017-2548(pISSN)
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  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
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Adsorption of Cu(II) Ions onto Myristica Fragrans Shell-based Activated Carbon: Isotherm, Kinetic and Thermodynamic Studies

  • Syahiddin, D.S. (Department of Chemical Engineering, Faculty of Engineering, Syiah Kuala University) ;
  • Muslim, A. (Department of Chemical Engineering, Faculty of Engineering, Syiah Kuala University)
  • 투고 : 2017.09.15
  • 심사 : 2018.02.08
  • 발행 : 2018.04.20
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초록

This study reported the adsorption of Cu(II) ions onto activated carbon prepared from Myristica Fragrans shell (MFS AC) over independent variables of contact time, activating chemical (NaOH) concentration, initial adsorbate concentration, initial pH of adsorbate solution and adsorption temperature. The MFS AC structure, morphology and total surface area were characterized by FTIR, SEM and BET techniques, respectively. The Cu(II) ions adsorption on the MFS AC (activated using 0.5 M NaOH) fitted best to Freundlich adsorption isotherm (FAI), and the FAI constant obtained was 0.845 L/g at $30^{\circ}C$ and pH 4.5. It followed the pseudo first order of adsorption kinetic (PFOAK) model, and the PFOAK based adsorption capacity was 107.65 mg/g. Thermodynamic study confirmed the Cu(II) ions adsorption should be exothermic and non-spontaneous process, physical adsorption should be taken place. The total surface area and pore volume based on BET analysis was $99.85m^2/g$ and 0.086 cc/g, respectively.

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