DOI QR코드

DOI QR Code

Fabrication and characterization of polysulfone ultrafiltration membrane using polyethylene glycol and tartaric acid: morphology and performance in protein separation

  • Sharma, N. (Department of Chemical Engineering, Indian Institute of Technology Guwahati) ;
  • Purkait, M.K. (Department of Chemical Engineering, Indian Institute of Technology Guwahati)
  • 투고 : 2017.01.04
  • 심사 : 2017.08.15
  • 발행 : 2017.11.25

초록

Increase in the hydrophilicity (HPCT) of polysulfone (PS) membrane and subsequently decrease in fouling can be achieved by surface modification of PS based membranes. Therefore, in this work, ultrafiltration membranes with increased HPCT were prepared using the enantiomeric tartaric acid (D-TA) and racemic tartaric acid (DL-TA). Phase inversion technique was used for the preparation of polyethylene glycol and TA blended PS membrane. Morphological analysis of the fabricated membranes was done by scanning electron microscope and atomic force microscopy. Bovine serum albumin (BSA) solution was taken for finding the permeation and rejection behavior of prepared membranes. Maximum BSA rejection was increased by 70.5% for the modified membrane.

키워드

과제정보

연구 과제 주관 기관 : Indian National Science Academy (INSA)

참고문헌

  1. Abaticchio, P., Bottino, A., Capannelli, G. and Munari, S. (1990), "Characterization of ultrafiltration polymeric membranes", Desalinat., 78, 235-255. https://doi.org/10.1016/0011-9164(90)80045-D
  2. Ahmad, A.L., Abdulkarim, A.A., Ooi, B.S. and Ismail, S. (2013), "Recent development in additives modifications of polyethersulfone membrane for flux enhancement", Chem. Eng. J., 223, 246. https://doi.org/10.1016/j.cej.2013.02.130
  3. Bhadra, S., Singha, N.K. and Khastgir, D. (2008), "Effect of aromatic substitution in aniline on the properties of polyaniline", Eur. Poly. J., 44, 1763. https://doi.org/10.1016/j.eurpolymj.2008.03.010
  4. Calvo, J., Bottino, A., Capannelli, G. and Hernandez, A. (2004), "Comparison of liquid-liquid displacement porosimetry and scanning electron microscopy image analysis to characterise ultrafiltration track-etched membranes", J. Membr. Sci., 239(2), 189-197. https://doi.org/10.1016/j.memsci.2004.02.038
  5. Cappanelli, G., Vigo, F. and Munari, S. (1983), "Ultrafiltration membranes- characterization methods", J. Membr. Sci., 15, 289-313. https://doi.org/10.1016/S0376-7388(00)82305-4
  6. Chakrabarty, B., Ghoshal, A.K. and Purkait, M.K. (2008), "Preparation, characterization and performance studies of polysulfone membranes using PVP as an additive", J. Membr. Sci., 315, 36-47. https://doi.org/10.1016/j.memsci.2008.02.027
  7. Cheryan, M. (1998), Ultrafiltration and Microfiltration Handbook, Technomic Publishing Company Inc. USA, 345.
  8. Chun, M.K., Cho, C.S. and Choi, H.K. (2004), "Characteristics of poly (vinyl pyrrolidone)/poly(acrylicacid) interpolymer complex prepared by template polymerization of acrylic acid: Effect of reaction solvent and molecular weight of template", J. Appl. Poly. Sci., 94, 2390-2394. https://doi.org/10.1002/app.21176
  9. Duarte, A.R.C., Mano, J.F. and Reis, R.L. (2012), "The role of organic solvent on the preparation of chitosan scaffolds by supercritical assisted phase inversion", J. Superc. Fluid., 72, 326-332. https://doi.org/10.1016/j.supflu.2010.12.004
  10. Fane, A.G., Fell, C.J.D. and Waters, A.G. (1981), "The relationship between membrane surface pore characteristics and flux for ultrafiltration membranes", J. Membr. Sci., 9, 245-262. https://doi.org/10.1016/S0376-7388(00)80267-7
  11. Geise, G.M., Lee, H.S., Miller, D.J., Freeman, B.D., McGrath, J.E. and Paul, D.R. (2010), "Water purification by membranes: the role of polymer science", J. Poly. Sci. Part B: Polym. Phys., 48, 1685. https://doi.org/10.1002/polb.22037
  12. Ghaemi, N., Madaeni, S.S., Abdolhamid, A., Rajabi, H., Daraei, P. and Falsafi, M. (2012), "Effect of fatty acids on the structure and performance of cellulose acetate nano filtration membranes in retention of nitroaromatic pesticides", Desalinat., 301, 26-41. https://doi.org/10.1016/j.desal.2012.06.008
  13. Ghaemi, N., Madaeni, S.S., Alizadeh, A., Daraei, P., Badieh, M.M.S., Falsafi, M. and Vatanpour, V. (2012), "Fabrication and modification of polysulfone nanofiltration membrane using organic acids: Morphology, characterization and performance in removal of xenobiotics", Separat. Purif. Technol., 96, 214-228. https://doi.org/10.1016/j.seppur.2012.06.008
  14. Ghosh, R. and Cui, Z.F. (1998), "Fractionation of BSA and lysozyme using ultrafiltration: effect of pH and membrane pretreatment", J. Membr. Sci., 139, 17-28. https://doi.org/10.1016/S0376-7388(97)00236-6
  15. Hand, A.J., Sun, T., Barber, D.C., Hose, D.R. and MacNeil, S. (2009), "Automated tracking of migrating cells in phase-contrast video microscopy sequences using image registration", J. Micros., 234, 62-79. https://doi.org/10.1111/j.1365-2818.2009.03144.x
  16. Huisman, J.H., Pradanos, P. and Hermandez, A. (2000), "The effect of protein-protein and protein-membrane interactions on membrane fouling in ultrafiltration", J. Membr. Sci., 179, 79-90. https://doi.org/10.1016/S0376-7388(00)00501-9
  17. Hunter, R.J. (1981), Zeta Potential in Colloid Science, Academic Press, London.
  18. Ingole, P.G., Sawant, S.Y., Ingole, N.P., Pawar, R.R., Bajaj, H.C., Singh, K., ... & Lee, H.K. (2016), "Preparation of activated carbon incorporated polysulfone membranes for dye separation", Membr. Water Treat., 7(6), 477-493. https://doi.org/10.12989/mwt.2016.7.6.477
  19. Kamusewitz, H., Schossig-Tiedemann, M., Keller, M. and Paul, D. (1997), "Characterization of polymeric membranes by means of scanning force microscopy (SFM) in comparison to results of scanning electron microscopy (SEM) ", Surf. Sci., 377-379, 1076-1081. https://doi.org/10.1016/S0039-6028(96)01549-X
  20. Kim, J.H. and Lee, K.H. (1998), "Effect of PEG additive on membrane formation by phase inversion", J. Membr. Sci., 138, 153-163. https://doi.org/10.1016/S0376-7388(97)00224-X
  21. Kimmerle, K. and Strathmann, H. (1990), "Analysis of the structure-determining process of phase inversion membranes", Desalinat., 79, 283-302. https://doi.org/10.1016/0011-9164(90)85012-Y
  22. Kobayashi, T., Reddy, P.S., Ohta, M., Abe, M. and Fujii, N. (2002), "Molecularly imprinted polysulfone membranes having acceptor sites for donor dibenzo furan as novel membrane adsorbents: charge transfer interaction as recognition origin", Chem. Mater., 14, 2499-2505. https://doi.org/10.1021/cm0109692
  23. Li, Q., Bi, Q., Lin, H., Bian, L. and Wang, X. (2013), "A novel ultrafiltration (UF) membrane with controllable selectivity for protein separation", J. Membr. Sci., 427, 155-167. https://doi.org/10.1016/j.memsci.2012.09.010
  24. Li, Y.S., Yan, L., Xiang, C.B. and Hong, L.J. (2006), "Treatment of oily wastewater by organic-inorganic composite tubular ultrafiltration (UF) membranes", Desalinat., 196, 76-83. https://doi.org/10.1016/j.desal.2005.11.021
  25. Li1, J., Nie, S., Wang, L., Sun, S., Ran, F. and Zhao, C. (2013), "One-pot synthesized poly(vinyl pyrrolidone-co-methyl methacrylate-co-acrylic acid) blended with poly(ether sulfone) to prepare blood-compatible membrane", J. Appl. Poly. Sci., 130, 39463-39472.
  26. Liou, R.M., Chen, S.H., Lai, C.L., Hung, M.Y. and Huang, C.H. (2011), "Effect of ammonium groups of sulfonated polysulfone membrane on its pervaporation performance", Desalinat., 278, 91-97. https://doi.org/10.1016/j.desal.2011.05.006
  27. Machado, P.S.T., Habert, A.C. and Borges, C.P. (1999), "Membrane formation mechanism based on precipitation kinetics and membrane morphology: flat and hollow fiber polysulfone membranes", J. Membr. Sci., 155, 171-183. https://doi.org/10.1016/S0376-7388(98)00266-X
  28. Mansourizadeh, A. and Ismail, A.F. (2010), "Effect of additives on the structure and performance of polysulfone hollow fiber membranes for $CO_2$ absorption", J. Membr. Sci., 348, 260-267. https://doi.org/10.1016/j.memsci.2009.11.010
  29. Mulder, M. (1996), Basic Principles of Membrane Technology, Kluwer Academic Publishers, Netherlands 56, 49-51.
  30. Musale, D.A. and Kulkarni, S.S. (1997), "Relative rates of protein transmission through poly (acrylonitrile) based ultrafiltration membranes", J. Membr. Sci., 136, 13-23. https://doi.org/10.1016/S0376-7388(97)00179-8
  31. Qiu, S., Wu, L.G., Pan, X.J., Zhang, L., Chen, H.L. and Gao, C.J. (2009), "Preparation and properties of functionalized carbon nanotube/PSF blend ultrafiltration membranes", J. Membr. Sci., 342, 165-172. https://doi.org/10.1016/j.memsci.2009.06.041
  32. Reuvers, J. and Smolders, C.A. (1987), "Formation of membranes by means of immersion precipitation. Part II. The mechanism of formation of membranes prepared from the system cellulose acetate- acetone-water", J. Membr. Sci., 34, 67-86. https://doi.org/10.1016/S0376-7388(00)80021-6
  33. Sevilla, P., Rivas, J.M., Garcia-Blanco, F., Garcia-Ramos, J.V. and Sanchez-Cortes, S. (2007), "Identification of the antitumoral drug emodin binding sites in bovine serum albumin by spectroscopic methods", Biochem. Biophys. Acta, 1774, 1359-1369.
  34. Sharma, N. and Purkait, M.K. (2015), "Preparation of hydrophilic polysulfone membrane using polyacrylic acid with polyvinyl pyrrolidone", J. Appl. Poly. Sci., 132, 41964-41976.
  35. Sharma, N. and Purkait, M.K. (2016), "Enantiomeric and racemic effect of tartaric acid on polysulfone membrane during crystal violet dye removal by MEUF process", J. Water Proc. Eng., 10, 104-112. https://doi.org/10.1016/j.jwpe.2016.02.009
  36. Sharma, N. and Purkait, M.K. (2016), "Racemic and enantiomeric effect of tartaric acid on the hydrophilicity of polysulfone membrane", Membr. Water Treat., 7(3), 257-275. https://doi.org/10.12989/mwt.2016.7.3.257
  37. Sharma, N. and Purkait, M.K. (2017), "Impact of synthesized amino alcohol plasticizer on the morphology and hydrophilicity of polysulfone ultrafiltration membrane", J. Membr. Sci., 522, 202-215. https://doi.org/10.1016/j.memsci.2016.08.068
  38. Silverstein, R.M., Bassler, G.C. and Morrill, T.C. (1991), Spectrometric Identification of Organic Compounds, John Wiley & Sons Inc., New York.
  39. Sinha, M.K. and Purkait, M.K. (2015), "Preparation of fouling resistant PSF flat sheet UF membrane using amphiphilic polyurethane macromolecules", Desalinat., 355, 155-168. https://doi.org/10.1016/j.desal.2014.10.017
  40. Sinha, M.K. and Purkait, M.K. (2013), "Increase in hydrophilicity of polysulfone membrane using polyethylene glycol methyl ether", J. Membr. Sci., 437, 7-16. https://doi.org/10.1016/j.memsci.2013.03.003
  41. Sivakumar, M., Malaisamy, R., Sajitha, C.J., Mohan, D., Mohan, V. and Rangarajan, R. (1999), "Ultrafiltration application of cellulose acetate-polyurethane blend membranes", Euro. Polym. J., 35, 1647-1651. https://doi.org/10.1016/S0014-3057(98)00262-6
  42. Stuart, B. (2004), Infrared Spectroscopy: Fundamentals and Applications, John Wiley & Sons, Ltd.
  43. Tweddle, T.A., Kutowy, O., Thayer, W.L. and Sourirajan, S. (1983), "Polysulfone ultrafiltration membranes", Ind. Eng. Chem. Product Res. Dev., 22, 320-326. https://doi.org/10.1021/i300010a030
  44. Vatanpour, V., Madaeni, S.S., Moradian, R., Zinadini, S. and Astinchap, B. (2012), "Novel antifouling nanofiltration polyether sulfone membrane fabricated from embedding $TiO_2$ coated multiwalled carbon nanotubes", Separat. Purif. Technol., 90, 69-82. https://doi.org/10.1016/j.seppur.2012.02.014
  45. Wang, J.Y., Xu, Y.Y., Zhu, L.P., Li, J.H. and Zhu, B.K. (2008), "Amphiphilic ABA copolymers used for surface modification of polysulfone membranes, Part 1: Molecular design, synthesis, and characterization", Polym., 49, 3256-3264. https://doi.org/10.1016/j.polymer.2008.05.033
  46. Wang, Y., Wang, T., Su, Y., Peng, F., Wu, H. and Jiang, Z. (2005), "Remarkable reduction of irreversible fouling and improvement of the permeation properties of poly(ether sulfone) ultrafiltration membranes by blending with pluronic F127", Langmuir, 21, 11856-11862. https://doi.org/10.1021/la052052d
  47. Wei, X., Wang, Z., Wang, J. and Wang, S. (2012), "A novel method of surface modification to polysulfone ultrafiltration membrane by preadsorption of citric acid or sodium bisulfite", Membr. Water Treat., 3, 35-49. https://doi.org/10.12989/mwt.2012.3.1.035
  48. Yan, X., He, G., Gu, S., Wua, X., Dua, L. and Wanga, Y. (2012), "Imidazolium-functionalized polysulfone hydroxide exchange membranes for potential applications in alkaline membrane direct alcohol fuel cells", Int. J. Hydro. Energy, 37, 5216-5224. https://doi.org/10.1016/j.ijhydene.2011.12.069
  49. Yang, L., Chen, X.Q. and Jiao, F.P. (2009), "Extractive resolution of racemic mandelic acid through a bulk liquid membrane containing binary chiral carrier", J. Braz. Chem. Soc., 8, 1493-1498.
  50. Zhang, Y., Shana, L., Tua, Z. and Zhang, Y. (2008), "Preparation and characterization of novel Ce doped non stoichiometric nano silica/polysulfone composite membranes", Separat. Purif. Technol., 63, 207-212. https://doi.org/10.1016/j.seppur.2008.05.015
  51. Zheng, Q.Z., Wang, P. and Yang, Y.N. (2006), "Rheological and thermodynamic variation in polysulfone solution by PEG introduction and its effect on kinetics of membrane formation via phase-inversion process", J. Membr. Sci., 279, 230-237. https://doi.org/10.1016/j.memsci.2005.12.009