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Korea Photovoltaic Society (한국태양광발전학회)
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Optical Characterization of Azo-dye Attached on Photonic Crystal: The Cause of Large Absorption Band Shift

  • Kim, Byoung-Ju (Department of New & Renewable Energy, Kyungil University) ;
  • Kwon, Ki-Chul (Department of New & Renewable Energy, Kyungil University) ;
  • Yu, A-Reum (Department of New & Renewable Energy, Kyungil University) ;
  • Kang, Kwang-Sun (Department of New & Renewable Energy, Kyungil University)
  • Received : 2017.03.10
  • Accepted : 2017.03.26
  • Published : 2017.06.30
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Abstract

Large absorption band shift has been observed for the azo-dye (disperse red-13, DR-13) attached on the surface of silica spheres. Urethane linkage has been utilized to form covalent bond between azo-dye (-OH) and 3-isocyanatopropyltriethoxysilane (ICPTES, -N=C=O). The synthesized ICPTES-DR-13 (ICPDR) molecules were attached to the silica spheres by the hydrolysis and condensation reaction. Although the absorption peak of DR-13 in methanol is at 510 nm, the absorption peak of the ICPDR-silica spheres shifts to 788 nm. The large absorption peak shift is due to the formation of intramolecular charge-transfer band with large aggregated ICPDR.

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References

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