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A Case Study of Mine Environmental Restoration using Coal Ash

발전회를 이용한 광산환경 복원사례 연구

  • Yoo, Jong-Chan (Korea Institute of Geoscience and Mineral Resources (KIGAM)) ;
  • Ji, Sang-Woo (Korea Institute of Geoscience and Mineral Resources (KIGAM)) ;
  • Ahn, Ji-Whan (Korea Institute of Geoscience and Mineral Resources (KIGAM)) ;
  • Kim, Chun-Sik (Hanil Cement Co., Ltd.) ;
  • Shin, Hee-Young (Korea Institute of Geoscience and Mineral Resources (KIGAM))
  • Received : 2017.02.17
  • Accepted : 2017.03.27
  • Published : 2017.04.30

Abstract

Globally, there has been a lot of research related to recycling coal ash from power plant stations. This research is happening because there is a considerable shortage of sites for reclamation of increased coal ash every year. In addition, a variety of environmental pollutants have appeared because of mining activity. Abandoned coal mine, pits, and mine tailing piles caused pollutants to come to the surface resulting in serious damage for humans and the environment. Therefore in this study, we investigated whether or not coal ashes have the ability to prevent several environmental problems by mining in Korea and a manageable form recycling coal ashes. In overseas countries, there is a sufficient field of applicable cases where coal ash is used for neutralizing AMD (Acid Mine Drainage), covering of the waste materials, grouting, and soil amendments. However in Korea, since the coal ash is classified as a 'waste', there is an insufficient field applicable cases so far. Therefore it is necessary to establish a specific standard and management system for the utilization of coal ash based on the relevant precedent cases applied abroad in order to prevent environmental pollution caused by mining activity in Korea.

전 세계적으로 매년 증가하는 발전회의 매립을 위한 부지는 현저히 부족한 실정이며, 이를 재활용 하는 방안에 관한 연구는 지금까지 활발히 진행 중이다. 또한, 휴 폐광산의 갱구, 폐석 더미, 지하공동에서 발생하는 다양한 광해는 심각한 인명피해 및 환경오염을 일으킨다. 따라서 본 연구에서는 국내 석탄, 금속, 석회석 광산에서 발생하는 AMD (Acid Mine Drainage), 지반침하 등의 광해방지에서 발전회의 활용 가능성에 대한 연구를 수행하였다. 발전회는 그 물리화학적인 특성에 따라 AMD 중화, 노천광산에서의 차폐재, 지하광산의 채움재 및 토양 개량제로써 활용할 수 있으며, 미국, 호주, 일본, 캐나다 등의 국외에서는 관련 지침을 마련하여 현장 적용사례가 충분히 확보된 상태이다. 하지만 국내의 경우 현장 적용을 위한 몇몇 연구들은 수행돼 왔지만, 현재 발전회를 사업장폐기물로 분류하고 있기 때문에 현장 적용사례가 미흡하며, 이와 관련된 연구도 부족한 실정이다. 따라서 국내에서도 국외의 관련 선행 적용사례들을 참고하여 광해방지사업에서 발전회의 활용을 위한 구체적인 기준 및 관리체계가 필요할 것이다.

Keywords

References

  1. Cho, H., Maeng, J.-H., 2016 : A study on Eco-friendly Use of Coal Ash at Mine Reclamation Sites, J. Korea Soc. Waste Manage., 33(4), pp. 328-337. https://doi.org/10.9786/kswm.2016.33.4.328
  2. Ministry of Trade, Industry and Energy, 2016 : Recycling guidelines for steel slag and coal ash companies.
  3. Park, S. M. et al., 2015 : Selective recovery of dissolved Fe, Al, Cu, and Zn in acid mine drainage based on modeling to predict precipitation pH, Environ. Sci. Pollut. Res., 22(4), pp. 3013-3022. https://doi.org/10.1007/s11356-014-3536-x
  4. ASTM (American Society for Testing and Materials) E2277-14, 2014 : Standard Guide for Design and Construction of Coal Ash Structural Fills.
  5. ASTM (American Society for Testing and Materials) E2243-13, 2013 : Standard Guide for Use of Coal Combustion Products (CCPs) for Surface Mine Reclamation: Re-contouring and Highwall Reclamation.
  6. ASTM (American Society for Testing and Materials) E2060-06, 2014 : Standard Guide for Use of Coal Combustion Products for Solidification/Stabilization of Inorganic Wastes.
  7. ASTM (American Society for Testing and Materials) E50, 2016 : Standard Practices for Apparatus, Reagents, and Safety Considerations for Chemical Analysis of Metals, Ores, and Related Materials.
  8. JCOAL (Japan Coal Energy Center) : Programs for Coal Resources Development.
  9. USEPA, 2001 : Coal Remining - Best Management Practices Guidance Manual.
  10. BS EN 450-1, 2012 : Fly Ash for Concrete. Definition, Specifications and Conformity Criteria.
  11. BS EN 197-1, 2011 : Cement. Composition, Specifications and Conformity Criteria for Common Cements.
  12. BS EN 3892 Part 1, 1982 : Pulverised fuel ash for use as a cementitious component in structural concrete.
  13. BS EN 3892 Part 2, 1996 : Specification for pulverisedfuel ash for use as a Type I addition.
  14. BS EN 3892 Part 3 1997 : Specification for pulverised-fuel ash for use in cementitious grouts.
  15. DOE (Department of Energy), 2006 : Use of Coal Combustion Products in Mine-Filling Applications: A Review of a Vailable Literature and Case Studies.
  16. CCSD (Cooperative Research Centre for Coal in Sustainable Development), 2006 : Use of Coal Ash in Mine Backfill and Related Applications.
  17. MEND (Mine Environment Neutral Drainage), 2006 : Paste Backfill Geochemistry - Environmental Effects of Leaching and Weathering.
  18. Park, S.-U. et al., 2015 : Evaluation of Some Rare Metals and Rare Earth Metals Contained in Coal Ash of Coalfired Power Plants in Korea, J. Korean Inst. Resource Recycling, 24(4), pp. 67-75. https://doi.org/10.7844/kirr.2015.24.4.67
  19. Heifrich et al., 2005 : Case study: CCPs' potential to lower greenhouse gas emissions for Australia, Proceedings of World of Coal Ash Symposium, Lexington, Kentucky, USA, pp. 20.
  20. Kalyoncu, R. 2001 : Coal combustion products-production and uses, Proceeding of 18th Pittsburg International Coal Conference, Newcastle, Australia, pp. 16.
  21. Young A., 2002 : Ashes to ashes: returning CCBs to the ground at Navajo Mine, Proceedings of Interactive Technical Forum on Coal Combustion By-Products and Western Coal Mine, Golden, Colorado (ed. K.C. Borries and D. Throgmoton), pp. 105-114.
  22. vom Berg, Feureborn, 2005 : Present situation and perspectives of CCP management in Europe, Proceedings of World of Coal Ash Symposium, Lexington, Kentucky, USA, pp. 10.
  23. Oh, M.-T., Sung, Y. J., 2012 : Evaluation of Applicability of Bottom Ash as Inorganic Filler, J. Korea TAPPI, 44(5), pp. 80-86.
  24. Oh, S.-J. et al., 2011 : Evaluating Stabilization Efficiency of Coal Combustion Ash (CCA) for Coal Mine Wastes: Column Experiment, Korean J. Soil Sci. Fert., 44(6), pp. 1071-1079. https://doi.org/10.7745/KJSSF.2011.44.6.1071
  25. Lee, S.-E. et al., 2012 : A study on the Model Test for Mine Filling using Coal ASh, Tunner & Underground Space, 22(6), pp. 449-461. https://doi.org/10.7474/TUS.2012.22.6.449
  26. Cho, K.-S., Roh, Y., Chung, D.-H., 2007 : A Biogeochemical Study on the Heavy Metal Leaching from Coal Fly Ash Disposed by Dangjin Fire Plant in the Coastal Environment, J. Korean Earth Sci. Soc., 28(1), pp. 112-122. https://doi.org/10.5467/JKESS.2007.28.1.112
  27. Gazea, B., Adan, K., Kontopoulos, A., 1996 : A review of passive systems for the treatment of acid mine drainage, Miner. Eng., 9(1), pp. 23-42. https://doi.org/10.1016/0892-6875(95)00129-8
  28. Johnson, D. B., Hallberg, K. B. 2005 : Acid mine drainage remediation options: a review, Sci. total Environ., 338(1), pp. 3-14. https://doi.org/10.1016/j.scitotenv.2004.09.002
  29. Potvin, Y., Thomas, Ed., Fourie, A., 2005 : Handbook on Mine Fill, Australia Centre for Geomechanics, Perth, pp. 179.
  30. Mulligan, C., Young, E. N., Gibbs, B. F., 2001 : Remediation technologies for metal-contaminated soils and groundwater: an evaluation, Eng. Geol., 60(1), pp. 193-207. https://doi.org/10.1016/S0013-7952(00)00101-0
  31. Gitari, M. et al., 2006 : Treatment of acid mine drainage with fly ash: removal of major contaminants and trace elements, J. Environ. Sci. Heal., A, 41(8), pp. 1729-1747. https://doi.org/10.1080/10934520600754425
  32. Petrik, L. F. et al., 2003 : Utilization of South African fly ash to treat acid coal mine drainage, and production of high quality zeolites from the residual solids, Proceedings of the Ash Utilization Symposium, Lexington, KY, USA.
  33. Potgieter-Vermaak, S. et al., 2006 : Comparison of limestone, dolomite and fly ash as pre-treatment agents for acid mine drainage, Miner. Eng., 19(5), pp. 454-462. https://doi.org/10.1016/j.mineng.2005.07.009
  34. Aljoe, W. W., Renninger, S. 1999 : CCB's in Mining Applications-An Overview of Projects Sponsored by DOEFETC, Proceedings of the International Ash Utilization Symposium, Kentucky, USA, pp. 50.
  35. Gray, T. et al., 1997 : Plan for injection of coal combustion byproducts into the Omega Mine for the reduction of acid mine drainage, American Society for Surface Mining and Reclamation, Princeton, WV, USA.
  36. Surender, D., Petrik, L., 2005 : Development of a Codisposal Protocol for the neutralization and amelioration of acid mine drainage with fly ash, Proceedings of World of Coal Ash Symposium, Lexington, Kentucky, USA.
  37. Rios, C. A., Williams, C. D., Roberts, C. L., 2008 : Removal of heavy metals from acid mine drainage (AMD) using coal fly ash, natural clinker and synthetic zeolites, J. Hazard. Mater., 156(1), pp. 23-35. https://doi.org/10.1016/j.jhazmat.2007.11.123
  38. Canty, G. A., Everett, J. W., 2006 : Alkaline injection technology: Field demonstration, Fuel, 85(17), pp. 2545-2554. https://doi.org/10.1016/j.fuel.2006.05.010
  39. Polat, H. et al., 2004 : A new methodology for removal of boron from water by coal and fly ash, Desalination, 164(2), pp. 173-188. https://doi.org/10.1016/S0011-9164(04)00176-6
  40. Genthe B. et al., 2013 : Health risk implications from simultaneous exposure to multiple environmental contaminants, Ecotox. Environ. Safe., 93(1), pp. 171-179. https://doi.org/10.1016/j.ecoenv.2013.03.032
  41. Kwon, S.-D., Kim, S.-J., 1999 : A Study on the Treatment of the Acid Mine Drainage using the Steel Mill Slag, J. Korean Soc. of Groundwater Environ., 6(4), pp. 206-212.
  42. Kost, D. A., Vimmerstedt, J. P. Stehouwer, R. C., 1997 : Reclamation of Acid, Toxic Coal Spoils Using Wet Flue Gas Desulfurization BY-Products, Fly ash, and Sewage Sludge. Final report.
  43. Capp, J. P., Adams, L. M., 1971 : Reclamation of coal mine wastes and strip spoil with fly ash. ACS Div, Fuel Chem, Preprints, 15(2), pp. 26.
  44. Fail, J. L., 1987 : Growth response of two grasses and a legume on coal fly ash amended strip mine spoils, Plant and soil, 101(1), pp. 149-150. https://doi.org/10.1007/BF02371045
  45. Hunter, G. D., Whiteman, P. C., 1975 : Revegetation of mine wastes, Mt. Isa, Queensland. 2. Amendment of nutrient status and physical properties of tailings for plant growth, Aus. J. Exp. Agr. Anim. Husbandry, 15(77), pp. 803-811. https://doi.org/10.1071/EA9750803
  46. Ye, Z. H. et al., 2000 : Revegetation of Pb/Zn mine tailings, Guangdong Province, China, Restoration Ecology, 8(1), pp. 87-92. https://doi.org/10.1046/j.1526-100x.2000.80012.x
  47. Lopareva-Pohu, A. et al., 2011 : Influence of Fly Ash Aided Phytostabilisation of Pb, Cd and Zn Highly Contaminated Soils on Lolium Perenne and Trifolium Repens Metal Transfer and Physiological Stress, Environ. Pollut., 159, pp. 1721-1729. https://doi.org/10.1016/j.envpol.2011.02.030
  48. Jala, S. Goyal, D., 2006 : Fly ash as a soil ameliorant for improving crop production-a review, 97, pp. 1136-1147. https://doi.org/10.1016/j.biortech.2004.09.004
  49. Pandey, V. C., Abhilash, P. C., Singh, N., 2009 : The Indian perspective of utilizing fly ash in phytoremediation, phytomanagement and biomass production, J. Environ. Manage., 90, pp. 2943-2958. https://doi.org/10.1016/j.jenvman.2009.05.001
  50. Hong, C. O. et al., 2006 : Evaluating Possibility of Heavy Metal Accumulation by Fly Ash Application in Rice Paddy Soils, Korean J. Environ. Agri., 25(4), pp. 331-338. https://doi.org/10.5338/KJEA.2006.25.4.331
  51. Hallberg, R. O., Granhagen, J. R., Liljemark, A., 2005 : A fly ash/biosludge dry cover for the mitigation of AMD at the falun mine, Chem. Erde-Geochem., 65, pp. 43-63. https://doi.org/10.1016/j.chemer.2005.06.008
  52. Menghini et al., 2005 : Beneficial use of FBC coal ash for mine reclamation in the anthracite region at the wheelabrator Frackville and mount carmel co-gen sites, Proceeding of Regulation, risk, and reclamation with coal combustion by-products at mines: a technical interactive forum, Lexington, Kentucky, USA, pp. 33-43.
  53. Ziemkiewicz, P. F., Skousen, J., 2000 : Use of coal combustion products for reclamation, Green Lands Magazine, pp. 36-47.
  54. Mollamahmutoglu, M., Yilmaz, Y., 2001 : Potential use of fly ash and bentonite mixture as liner or cover at waste disposal areas, Environ. Geol., 40(11-12), pp. 1316-1324. https://doi.org/10.1007/s002540100355
  55. Dutta, A. B., Sarkar, T., 2016 : Fly ash an alternative for mine void filling in India, Int. J. Sci. Technol., 5(4), pp. 144-148.
  56. Ahmaruzzaman, M., 2010 : A review on the utilization of fly ash, Prog. Energ. Combust., 36(3), pp. 327-363. https://doi.org/10.1016/j.pecs.2009.11.003
  57. UKQAA (United Kingdom Quality Ash Association), 2004 : Case Study : Grouting of lime stone caverns Mons Hill Dudley, West Midlands, UK.
  58. Mishra, M. K., Karanam, U. M. R., 2006 : Grotechnical Characterisation of fly ash composites for backfilling mine voids, Geotech. Geol. Eng., 24(6), pp. 1749-1765. https://doi.org/10.1007/s10706-006-6805-8
  59. Lee, K.-H., Kim, S.-K., 2012 : Eco-Friendly Backfill Materials with Bottom Ash, J. Korea Academia-Ind., 13(3), pp. 1385-1390.

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