Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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The Phase Transition and Thermochromic Characteristics of W/Mg-codoped Monoclinic VO2 Nanoparticle and Its Composite Film

  • Park, Heesun (Department of Chemistry, Pukyong National University) ;
  • Kim, Jongmin (Department of Chemistry, Pukyong National University) ;
  • Jung, Young Hee (Research Laboratory, Mapro, Inc. Hanlim) ;
  • Kim, Yeong Il (Department of Chemistry, Pukyong National University)
  • Received : 2017.02.08
  • Accepted : 2017.02.13
  • Published : 2017.04.20
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Abstract

Monoclinic $VO_2(M)$ nanoparticles codoped with 1.5 at. % W and 2.9 at. % Mg were synthesized by the hydrothermal treatment and post-thermal transformation method of $V_2O_5-H_2C_2O_4-H_2O$ with $Na_2WO_4$ and $Mg(NO_3)_2$. The composite thin film of the W/Mg-codoped $VO_2(M)$ with a commercial acrylic block copolymer was also prepared on PET substrate by wet-coating method. The reversible phase transition characteristics of the codoped $VO_2(M)$ nanoparticles and the composite film were investigated from DSC, resistivity and Vis-NIR transmittance measurements compared with the undoped and Wdoped $VO_2(M)$ samples. Mg-codoping into W-doped $VO_2(M)$ nanoparticles synergistically enhanced the transition characteristics by increasing the sharpness of transition while the transition temperature ($T_c$) lowered by W-doping was maintained. The codoped composite film showed the prominently enhanced NIR switching efficiency compared to only W-doped $VO_2(M)$ film with a lowered $T_c$.

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References

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