DOI QR코드

DOI QR Code

Waterborne Polyurethane Skin Resin Used in the Fabrication of Synthetic Leather Adhesive

합성피혁 스킨용 폴리우레탄 수분산체의 제조 및 primerless 접착 특성 연구

  • Received : 2016.12.29
  • Accepted : 2017.02.08
  • Published : 2017.02.28

Abstract

Shoes, made up of an upper shoe, insole, and outsole, are manufactured by adhering each of the parts together. It has been proven that pre-treating each of these parts greatly improves the adhesive strength when adhering them together. However, harmful materials such as volatile organic compounds (VOCs) are often emitted from organic solvents during pre-treatment, causing environmental concerns such as air pollution in the workplace. Therefore, this study was conducted to develop a water-based polyurethane skin resin for fabricating a synthetic leather and textile adhesive that has greater adhesive strength and does not require pre-treatment. To achieve this, two waterborne polyurethane solutions, one with excellent thermal resistance and light fastness (waterborne polyurethane A) and the other with high adhesive strength (waterborne polyurethane B), were mixed to impart the superior characteristics of each to a third waterborne polyurethane solution. Through this approach, we were able to successfully fabricate an excellent waterborne leather polyurethane resin with ethylene vinyl acetate (EVA) for midsoles (peel strength: 2.9 kgf/cm) and for rubber out-soles (peel strength: 2.4 kgf/cm) without using pre-treatment.

Keywords

References

  1. C. S. Yoo and J. H. Chun, "Application of Polyurethane as Adhesive", Polym. Sci. Tech., 1999, 10, 578.
  2. C. Hepburn, "Polyurethane Elastomer," Elsevier, London, 1982, pp.122-173.
  3. D. Dieterich, "Aqueous Emulsions, Dispersions and Solution of Polyurethane; Synthesis and Properties", Progress in Organic Coatings, 1981, 9, 281-340. https://doi.org/10.1016/0033-0655(81)80002-7
  4. S. L. Cooper and A. V. Tobosky, "Properties of Linear Elastomeric Polyurethanes", J. Appl. Polym. Sci., 1966, 10, 1837-1844. https://doi.org/10.1002/app.1966.070101204
  5. S. Mohanty and N. Krishnamurti, "Synthesis and Characterization of Aqueous Cationomeric Polyurethanes and Their Use as Adhesives", J. Appl. Polym. Sci., 1996, 62, 1993-2003. https://doi.org/10.1002/(SICI)1097-4628(19961219)62:12<1993::AID-APP3>3.0.CO;2-D
  6. M. C. Delpech and F. M. B. Coutinho, "Waterborne Anionic Polyurethanes and Poly(urethane-urea)s: Influence of the Chain Extender on Mechanical and Adhesive Properties", Polymer Testing, 2000, 19, 939-952. https://doi.org/10.1016/S0142-9418(99)00066-5
  7. D. H. Shao, J. J. Huang, G. N. Chen, J. T. Yeh, and K. N. Chen, "Thermal and Combustion Behaviors of Aqueous-based Polyurethane System with Phosphorus and Nitrogen Containing Curing Agent", Polym. Degrad. Stab., 1999, 65, 359-371. https://doi.org/10.1016/S0141-3910(99)00025-7
  8. J. S. Shin, J. M. Park, Y. H. Lee, and H. D. Kim, "Preparation and Properties of Eco-friendly Waterborne Polyurethane-urea Primer for Thermoplastic Polypropylene Applied to Automobile Interiors", Clean Technology, 2014, 20, 232-240. https://doi.org/10.7464/ksct.2014.20.3.232
  9. R. A. Pethrick in "Polymer Surface Modification and Characterization", C. M. Chan Ed., Hanser Publishers, New York, 1993, p.20.
  10. F. Garbassi, M. Morra, and E. Occhiello, "Polymer Surfaces: from Physics to Technology", John Willey and Sons, Chichester, 1994, p.35.
  11. M. J. Choi, D. H. Kim, and G. N. Kim, "Studies on the Surface Changes and Adhesion of EVA Foam by Plasma Treatment", Adhesion and Interface, 2008, 9, 9-12.
  12. D. H. Park, D. H. Moon, and C. U. Lee, "Study on Bond Used in Shoes Manufacturing Industry", J. Assoc. Korean Ind. Hyg., 1991, 1, 200-213.
  13. Y. T. Shin, M. G. Hong, J. J. Choi, W. K. Lee, G. B. Lee, B. W. Yoo, M. G. Lee, and K. C. Song, "Preparation of Waterborne Polyurethane/Silica Nanocomposites Using Tetraethylorthosilicate", Korean Chem. Eng. Res., 2010, 48, 428-433.
  14. Y. T. Shin, M. G. Hong, J. J. Choi, W. K. Lee, G. B. Lee, B. W. Yoo, M. G. Lee, and K. C. Song, "Preparation and Properties of Aminosilane Terminated Waterborne Polyurethane", Korean Chem. Eng. Res., 2010, 48, 434-439.
  15. H. K. Shin, M. W. Huh, and N. S. Yoon, "Fabrication of Silicacontaining Breathable Waterproof Polyurethane Dispersion Film", Textile Coloration and Finishing, 2015, 27, 126-131. https://doi.org/10.5764/TCF.2015.27.2.126
  16. S. M. Lai and S. D. Liu, "Properties and Preparation of Thermoplastic Polyurethane/Silica Hybrids Using a Modified Sol-Gel Process", Polym. Eng. Sci., 2007, 47, 77-86. https://doi.org/10.1002/pen.20669
  17. T. Kiyotsukuri, T. Masuda, N. Tsutsumi, and W. S. M. Nagata, "Poly(Ethylene-Terephthalate) Copolymers with a Smaller Amount of Poly(Ethylene Glycol)s and Poly(Butylene Glycol)s", Polymer, 1995, 36, 2629-2635. https://doi.org/10.1016/0032-3861(95)91211-O
  18. T. Kiyotsukuri, T. Masuda, and N. Tsutsumi, "Preparation and Properties of Poly(ethylene terephthalate) Copolymers with 2,2-dialkyl-1,3-propanediols", Polymer, 1994, 35, 1274-1279. https://doi.org/10.1016/0032-3861(94)90023-X
  19. S. Ioan, G. Grigorescu, and A. Stanciu, "Dynamic-mechanical and Differential Scanning Calorimetry Measurements on Crosslinked Poly(ester-siloxane)-urethanes", Polymer, 2001, 42, 3633-3639. https://doi.org/10.1016/S0032-3861(00)00747-3
  20. S. Ioan, G. Grigorescu, and A. Stanciu, "Poly(ester-siloxane)-urethanes Compositional Parameters on Differential Scanning Calorimetry and Dynamic Mechanical Measurements", Eur. Polym. J., 2002, 38, 2295-2303. https://doi.org/10.1016/S0014-3057(02)00108-8
  21. J. P. Sheth, A. Aneja, G. L. Wilkes, E. Yilgor, G. E. Atilla, Y. Iskender, and F. L. Beyer, "Influence of System Variables on the Morphological and Dynamic Mechanical Behavior of Polydimethylsiloxane Based Segmented Polyurethane and Polyurea Copolymer: A Comparative Perspective", Polymer, 2004, 45, 6919-6932. https://doi.org/10.1016/j.polymer.2004.06.057
  22. C. Z. Yang, C. Li, and S. L. Cooper, "Synthesis and Characterization of Polydimethylsiloxane Polyurea-urethanes and Related Zwitterionomers", J. Polym. Sci., Part B: Polym. Phys., 1991, 29, 75-86. https://doi.org/10.1002/polb.1991.090290110
  23. G. Oertel and L. Abele, Ed., "Polyurethane Handbook", 2nd Eds., Hanser Publishers, New York, 1985, p.54.