• Title/Summary/Keyword: lightfastness

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Influence of Plasma Treatment & UV Absorbent on Lightfastness Improvement of Brazilin (플라즈마 전처리와 자외선 흡수제에 의한 소목의 내일광성 향상에 관한 연구)

  • 신정숙;손원교
    • The Research Journal of the Costume Culture
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    • v.11 no.1
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    • pp.66-74
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    • 2003
  • This study is to improve the worst lightfastness of a natural dye. To modify the fiber surface, low temperature oxygen plasma was carried out on silk fabric. The result is followed below after the examination of surface shape, dyeability, color change, UV absorbent influence and lightfastness. 1. When electric discharge outputs are 60W, 80W and 100w, and processing times are 10minutes, 20minutes and 40minutes, the etching effect of surface increased as electric discharge outputs and processing times increased. 2. When examined UV absorbent for 5hours, 10hours, 20hours, 40hours and 80hours, the value changes of E are 1.47, 2.51, 2.91, 3.71, 4.51 and 5.31 in case of Al pre-mordanting/ prasma 80W, 20min./ UVabsorbent 5% (100:1), 2.31, 2.47, 3.84, 3.90, 3.61 and 4.42 in case of Al pre-mordanting/prasma 80W, 20min.1 UV absorbent 5% (o.w.f.). The lightfastness decreased when UV absorbent increased. 3. Dyeability of the samples pre-treated with five different methods was in the following order: plasma processing for 20minutes at 60W/Al pre-mordanting > Al pre-mordanting > plasma processing for 20minutes at 60W > Al after-mordanting. non mordanting Plasma treatment had superior effect on dyeability. 4. When UV absorbent was applied in fabric, the sample under higher electric discharge out puts showed more effective in improving lightfastness.

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Copper Salts in the Post-metallization of Non-genotoxic Direct Dyes

  • Bae, Jin-Seok;Freeman, Harold S.
    • Fibers and Polymers
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    • v.3 no.4
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    • pp.147-152
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    • 2002
  • Copper (II) salts are used as metallizing agents in the synthesis of new non-genotoxic direct dyes for cotton. Specifically, cotton fabric is dyed with non-genotoxic disazo direct dyes and then treated with copper salts. The complexes are characterized by neutron activation analysis, absorption spectrometry and standard Salmonella mammalian mutagenicity assay, and the after-treated fabrics are evaluated for lightfastness and washfastness. Direct dyes possessing ortho-propoxy and ortho'-hydroxy substituted systems formed the corresponding nonmutagenic 1:2 dye:metal complex and undergo significant improvement in lightfastness following metallization.

Effect of Chemical Structures of Congo Red and Benzopurpurine 4B on the Dyeing Property and Lightfastness of Cotton Fabric (Congo Red와 Benzopurpurine 4B의 화학구조가 면직물의 염색성 및 광퇴색성에 미치는 영향)

  • 이영희;박준명;김경환
    • Textile Coloration and Finishing
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    • v.2 no.1
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    • pp.8-13
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    • 1990
  • The fading of dyed material by light has long been subject of investigation, yet surprisingly little is known of the fundamental photochemical reactions, because of mainly the complex nature of dye-fibre system. The effect of the chemical structure of dye on lightfastness has been mostly studied when there is substituents on the place satisfied Hammett rule. Therefore, in this investigation the effectiveness of chemical structures of Congo Red and Benzopurpurine 4B unsatisfied Hammett rule on dyeing property and lightfastness of cotton was studied. The results obtained from this study were as follows; 1. Highly polar solvents showed hypsochromic shift. 2. Adsorption isotherm curves of the two dyes were Freundlich type. And Congo Red showed good dyeing property in comparision with Benzopurpurine 4B. 3. The type of the FR curve of the two dyes was first-ordr curve. And the CF curves of the two dyes showed normal fading state during irradiation. 4. During irradiation, the Hue was changed on the part of yellowish. The Value was increasing and the Chroma was decreasing. 5. Benzopurpurine 4B showed good lightfastness in comparision with Congo Red.

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The Effect of Resin Finishing on Cotton Fabrics Dyed with Direct Dyes (직접염료 염색포의 수지가공에 대한 영향)

  • Seol Jung-Hwa;Choi Suck-Chul;Chung Doo-Jin
    • Journal of the Korean Society of Clothing and Textiles
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    • v.9 no.2
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    • pp.13-26
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    • 1985
  • In this study, when cotton fabrics dyed with Direct dyes are treated under various resin concentration 2, 4, 8, 12, $14\%$ with ureaformaldehyde(UF) and melamineformaldehyde(MF) resin which can be imparted the crease recovery to textiles, chang of properties on lightfastness, washfastness, crease recovery, breaking strength, etc. and color changes are investigated. the results are as follows 1) Color difference(${\Delta}$E) increased but K/S value decreased according to the increase of resin cone. such tendency showed that MF treated fabrics and soaping fabrics were evident than UF treated fabrics and non-soaping fabrics. 2) In lightfastness, ${\Delta}$E and K/S value of resin treated fabrics were reduced as compared with untreated fabrics according to the increase of resin cone. The lower ${\Delta}$E and K/S value of MF than ${\Delta}$E and K/S value of UF showed low lightfastness of MF. pH of resin treted fabrics was almost unaffected with lightfastness. 3) In washfastness, ${\Delta}$E and K/S value of resin treated fabrics decreased slightly as com-pared with untreated fabricsaccording tothe increase of resin cone. The ${\Delta}$E and K/S value of MF decreased lower than UF. But in the case of the higher resin cone. than about $8\%$, they were not almost differentiated. 4) As resin cone. increased, crease recovery considerably increased but breaking strength and elongation decreased. The fabrics treated with UF were good crease recovery, whereas the fabrics treated with MF were good breaking strength. 5) Soaping appeared to improve the lightfastness, washfastness, crease recovery but appeared to work adverse effect on breaking strength.

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Effect of Pre-treatment with BTCA on Lightfastness of Cotton Fabric dyed with Combination of Safflower red / Amur Cork Tree (BTCA 전처리가 홍화/황벽 혼합 면염색물의 일광견뢰성에 미치는 영향)

  • Jeong, Sun-Young;Jang, Jeong-Dae
    • Fashion & Textile Research Journal
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    • v.10 no.6
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    • pp.1051-1057
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    • 2008
  • Safflower red and Amur Cork Tree dyes have used for dyeing on cotton fabrics largely. But they have low degree of lightfastness, So this study investigated the effect of BTCA pre-treatment on lightfastness of cotton fabrics dyed with Safflower red and Amur Cork Tree. The result is as the following; By FT-IR spectra, crosslingking was proved in cotton fabric pre treated with BTCA. K/S value of Safflower red dyed cotton fabric pretreated with BTCA was much more decreased than untreated cotton fabric with BTCA. It showed that the hue of the Safflower red dyed cotton fabric changed from reddish purple to red. However, K/S value of Amur Cork Tree dyed cotton fabric pre treated with BTCA was much more increased than untreated cotton fabric with BTCA. It showed that the hue of the Amur Cork Tree dyed cotton fabric changed from green yellow to yellow. For K/S value of Combination dyed cotton fabric pre treated with BTCA, Safflower red color was much more decreased than untreated cotton fabric. But Amur Cork Tree color was much more increased than untreated cotton fabric. It changed from reddish purple, red, yellowe red, to yellow in hue. ${{\Delta}E^*}_{ab}$ of Combination dyed cotton fabric in 40 hours irradiation was 15.7, however ${{\Delta}E^*}_{ab}$ of Combination dyed cotton fabric treated with 2% BTCA was 8.0, and that treated with 3% BTCA was 9.8. So, pre-treatment with BTCA to combination dyed cotton fabric with Safflower red and Amur Cork Tree showed more effective improvement of Lightfastness than untreated cotton fabric with BTCA.

Relation between Chemical Structure of Yellow Disperse Dyes and Their Lightfastness

  • Kim, Sung-Dong;Park, Eun-Jin
    • Fibers and Polymers
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    • v.2 no.3
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    • pp.159-163
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    • 2001
  • Five yellow disperse dyes were synthesized and their dyeing, fastness and photodegradation behaviors were investigated. It was found that dyes derived from phenylindole and N-alkylaminobenzene showed dye uptake directly proportional to the dye concentration, but the build-up of dyes derived from carbazole and pyridone were not good. The wavelength at maximum absorption. molar extinction coefficient. and the tendency to the photodegradation were strongly dependent on the electron donating ability of the coupling component. The dye, whose coupling component was phenylindole, possessed the excellent dyeing properties and the high degree of lightfastness. UVA had an effect on the inhibition of the photodegradation especially for the easily photodegradabte dyes.

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Anti-static behavior of Synthetic fabrics treated by anti-static agents (대전방지처리된 합성섬유의 대전성에 관한 연구)

  • Choi Suk-Chul;Kim Mi-Sung
    • Journal of the Korean Society of Clothing and Textiles
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    • v.11 no.1
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    • pp.51-62
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    • 1987
  • In this study, electrostatic behavior of polyester and nylon fabric treated with anti-static agents were investigated. The effects of the concentration of the agents and curing conditions on the electrostatic charge of the fabrics were studied. And washfastness, lightfastness and physicalproperties of the treated fabrics were also investigated. The results were as follows: 1) Polyethylene glycol alkylester was more effective in antistatic behavior than polyethylene laurylphosphate, and polyester is more effective in anti-static behavior than nylon. 2) Concentration of anti-static agents were suitable in concentration of $4\%$. 3) Glyoxal resin was more effective in anti-static behavior than melamine resin, and it was also good in the retaing anti-static behavior after treatments of lightfastness and washfastness. 4) As the condition of curing treatment, $190^{\circ}C$, 1min. for glyoxal resin and $130^{\circ}C$, 4min. for melamine resin is appropriate. 5) In comparison of anti-static behavior according to treating conditions, the simultaneous treatment was more effective than any other treatments. 6) Change of electrostatic charge of anti-static nylon cloths after treatments of lightfastness and washfastness increased greatly in above 10 laundering time and 20 fade-O-meter time. 7) In physical properties according to concentration of treating agents. decrease of physical properties scarcely appeared in concentration of treating agents $4\~5\%$.

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Studies on the Natural Dyes(12) -Dyeing Properties of Amur Cork Tree Colors for Silk- (천연염료에 관한 연구(12) -황벽 색소의 견섬유에 대한 염색성-)

  • 조경래;강미정
    • Textile Coloration and Finishing
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    • v.12 no.4
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    • pp.239-247
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    • 2000
  • The coloring matter was extracted from the heartwood of Amur cork tree by distilled water. Change of UV-Visible spectra of coloring matter solution by extraction condition and stability for irradiation were determined, and the effect of repeated dyeing with condition of dyebath and mordanting method on shade depth and lightfastness were also investigated. The results are as follows : 1) Absorbance of Amur cork tree extract increased with the lapse of extraction time. λmax of color solution extracted from Amur cork tree was found at 420, 333, and 262nm. 2) Absorbance of Amur cork tree extract decreased remarkably after 2hr irradiation. 3) The K/S of silk fabrics increased with the increase of dyeing temperature, time, amounts of Amur cork tree for extraction, and pH of color solution. 4) K/S of silk fabrics dyed by repeated dyeing method was affected by pH and concentration of color solution. 5) Lightfastness of silk twice dyed with Amur cork tree extract after pre-mordanted by 8%(o.w.f) chromium acetate was moderately improved.

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