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Fabrication and Characterization of Carbon Nanotube/Carbon Fiber/Polycarbonate Multiscale Hybrid Composites

  • Received : 2016.08.10
  • Accepted : 2016.10.31
  • Published : 2016.10.31

Abstract

Multiscale hybrid composites, which consist of polymeric resins, microscale fibers and nanoscale reinforcements, have drawn significant attention in the field of advanced, high-performance materials. Despite their advantages, multiscale hybrid composites show challenges associated with nanomaterial dispersion, viscosity, interfacial bonding and load transfer, and orientation control. In this paper, carbon nanotube(CNT)/carbon fiber(CF)/polycarbonate(PC) multiscale hybrid composite were fabricated by a solution process to overcome the difficulties associated with controlling the melt viscosity of thermoplastic resins. The dependence of CNT loading was studied by varying the method to add CNTs, i.e., impregnation of CF with CNT/PC/solvent solution and impregnation of CNT-coated CF with PC/solvent solution. In addition, hybrid composites were fabricated through surfactant-aided CNT dispersion followed by vacuum filtration. The morphologies of the surfaces of hybrid composites, as analyzed by scanning electron microscopy, revealed the quality of PC impregnation depends on the processing method. Dynamic mechanical analysis was performed to evaluate their mechanical performance. It was analyzed that if the position of the value of tan ${\delta}$ is closer to the ideal line, the adhesion between polymer and carbon fiber is stronger. The effect of mechanical interlocking has a great influence on the dynamic mechanical properties of the composites with CNT-coated CF, which indicates that coating CF with CNTs is a suitable method to fabricate CNT/CF/PC hybrid composites.

Keywords

References

  1. Kim, M., Park, Y.-B., Okoli, O.I., and Zhang, C., "Processing, Characterization, and Modeling of Carbon Nanotube-reinforced Multiscale Composites," Composites Science and Technology, Vol. 69, No. 3-4, 2009, pp. 335-342. https://doi.org/10.1016/j.compscitech.2008.10.019
  2. Zhou, Y., Pervin, F., Lewis, L., and Jeelani, S., "Fabrication and Characterization of Carbon/epoxy Composites Mixed with Multi-walled Carbon Nanotubes," Materials Science and Engineering: A, Vol. 475, No. 1-2, 2008, pp. 157-165. https://doi.org/10.1016/j.msea.2007.04.043
  3. Hwang, S.-H., Park, Y.-B., Yoon, K.-H., and Bang, D.-S., "Smart Materials and Structures Based on Carbon Nanotube Composites," in: Siva, Y (ed.), Carbon Nanotubes-Synthesis, Characterization, Application, InTech, 2011, pp. 371-396.
  4. Bekyarova, E., Thostenson, E.T., Yu, A., Kim, H., Gao, J., Tang, J., Hahn, H.T., Chou, T.-W., Itkis, M.E., and Haddo, R.C., "Multiscale Carbon Nanotube-Carbon Fiber Reinforcement for Advanced Epoxy Composites," Langmuir, Vol. 23, No. 7, 2007, pp. 3970-3974. https://doi.org/10.1021/la062743p
  5. Diez-Pascual, A.M., Naffakh, M., Marco, C., Gomez-Fatou, M.A., and Ellis, G.J., "Multiscale Fiber-reinforced Thermoplastic Composites Incorporating Carbon Nanotubes: A Review," Current Opinion in Solid State and Materials Science, Vol. 18, 2013, pp. 62-80.
  6. Biron, M., "Thermoplastic Composites," 2013, pp.769-829.
  7. Uematsu, Y., Kitamura, T., and Ohtani, R., "Delamination Behavior of a Carbon-fiber-reinforced Thermoplastic Polymer At High Temperatures," Composites Science and Technology, Vol. 53, 1994, pp. 333-341.
  8. Qiu, J., Zhang, C., Wang, B., and Liang, R., "Carbon Nanotube Integrated Multifunctional Multiscale Composites," Nanotechnology, Vol. 18, No. 27, 2007, pp. 275708. https://doi.org/10.1088/0957-4484/18/27/275708
  9. Gojny, F.H., Wichmann, M.H.G., Fiedler, B., Bauhofer, W., and Schulte, K., "Influence of Nano-modification on the Mechanical and Electrical Properties of Conventional Fibre-reinforced Composites," Composites Part A: Applied Science and Manufacturing, Vol. 36, No. 11, 2005, pp. 1525-1535. https://doi.org/10.1016/j.compositesa.2005.02.007
  10. Rahmanian, S., Thean, K.S., Suraya, A.R., Shazed, M.A., Mohd Salleh, M.A., and Yusoff, H.M., "Carbon and Glass Hierarchical Fibers: Influence of Carbon Nanotubes on Tensile, Flexural and Impact Properties of Short Fiber Reinforced Composites," Materials & Design, Vol. 43, 2013, pp. 10-16. https://doi.org/10.1016/j.matdes.2012.06.025
  11. Garcia, E., Wardle, B., Johnhart, A., and Yamamoto, N., "Fabrication and Multifunctional Properties of a Hybrid Laminate with Aligned Carbon Nanotubes Grown In Situ," Composites Science and Technology, Vol. 68, No. 9, 2008, pp. 2034-2041. https://doi.org/10.1016/j.compscitech.2008.02.028
  12. Abot, J.L., Song, Y., Schulz, M.J., and Shanov, V.N., "Novel Carbon Nanotube Array-reinforced Laminated Composite Materials with Higher Interlaminar Elastic Properties," Composites Science and Technology, Vol. 68, No. 13, 2008, pp. 2755-2760. https://doi.org/10.1016/j.compscitech.2008.05.023
  13. Qian, H., Greenhalgh, E.S., Shaffer, M.S.P., and Bismarck, A., "Carbon Nanotube-based Hierarchical Composites: A Review," Journal of Materials Chemistry, Vol. 20, No. 23, 2010, pp. 4751. https://doi.org/10.1039/c000041h
  14. Lee, S.-B., Choi, O., Lee, W., Yi, J.-W., Kim, B.-S., Byun, J.-H., Yoon, M.-K., Fong, H., Thostenson, E.T., and Chou, T.-W., "Processing and Characterization of Multi-scale Hybrid Composites Reinforced with Nanoscale Carbon Reinforcements and Carbon Fibers," Composites Part A: Applied Science and Manufacturing, Vol. 42, No. 4, 2011, pp. 337-344. https://doi.org/10.1016/j.compositesa.2010.10.016
  15. Zhang, L., Su, D., Jin, L., and Li, C., "Polyamide 6 Composites Reinforced with Glass Fibers Modified with Electrostatically Assembled Multiwall Carbon Nanotubes," Journal of Materials Science, Vol. 47, No. 14, 2012, pp. 5446-5454. https://doi.org/10.1007/s10853-012-6434-y
  16. Rausch, J., and Mader, E., "Health Monitoring in Continuous Glass Fibre Reinforced Thermoplastics: Tailored Sensitivity and Cyclic Loading of CNT-based Interphase Sensors," Composites Science and Technology, Vol. 70, No. 13, 2010, pp. 2023-2030. https://doi.org/10.1016/j.compscitech.2010.08.003
  17. Rausch, J., and Mader, E., "Health Monitoring in Continuous Glass Fibre Reinforced Thermoplastics: Manufacturing and Application of Interphase Sensors Based on Carbon Nanotubes," Composites Science and Technology, Vol. 70, No. 11, 2010, pp. 1589-1596. https://doi.org/10.1016/j.compscitech.2010.05.018
  18. Mader, E., Rausch, J., and Schmidt, N., "Commingled Yarns - Processing Aspects and Tailored Surfaces of Polypropylene/glass Composites," Composites Part A: Applied Science and Manufacturing, Vol. 39, No. 4, 2008, pp. 612-623. https://doi.org/10.1016/j.compositesa.2007.07.011
  19. Barber, A.H., Zhao, Q., Wagner, H.D., and Baillie, C.A., "Characterization of E-glass-polypropylene Interfaces Using Carbon Nanotubes as Strain Sensors," Composites Science and Technology, Vol. 64, No. 13-14, 2004, pp. 1915-1919. https://doi.org/10.1016/j.compscitech.2004.02.004
  20. Agnihotri, P., Basu, S., and Kar, K.K., "Effect of Carbon Nanotube Length and Density on the Properties of Carbon Nanotube-coated Carbon Fiber/polyester Composites," Carbon, Vol. 49, No. 9, 2011, pp. 3098-3106. https://doi.org/10.1016/j.carbon.2011.03.032
  21. Warrier, A., Godara, A., Rochez, O., Mezzo, L., Luizi, F., Gorbatikh, L., Lomov, S.V., VanVuure, A.W., and Verpoest, I., "The Effect of Adding Carbon Nanotubes to Glass/epoxy Composites in the Fibre Sizing and/or the Matrix," Composites Part A: Applied Science and Manufacturing, Vol. 41, No. 4, 2010, pp. 532-538. https://doi.org/10.1016/j.compositesa.2010.01.001
  22. Hwang, S.-H., Park, H.W., Park, Y.-B., Um, M.-K., Byun, J.-H., and Kwon, S., "Electromechanical Strain Sensing Using Polycarbonate-impregnated Carbon Nanotube-graphene Nanoplatelet Hybrid Composite Sheets," Composites Science and Technology, Vol. 89, 2013, pp. 1-9. https://doi.org/10.1016/j.compscitech.2013.09.005
  23. Nielsen, L.E., and Landel, R.F., "Mechanical Properties of Polymers and Composites," Second ed., CRC Press, 1993.
  24. Dong, S., and Gauvin, R., "Application of DMA for Multiscale Composites," Polymer Composites, Vol. 14, 1993.
  25. Liao, K., and Li, S., "Interfacial Characteristics of a Carbon Nanotube-polystyrene Composite System," Applied Physics Letters, Vol. 79, No. 25, 2001, pp. 4225. https://doi.org/10.1063/1.1428116

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