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Characterization of Milled Carbon Fibers-filled Pitch-based Carbon Paper for Gas Diffusion Layer

미분쇄 탄소섬유가 첨가된 피치계 탄소섬유기반 기체확산층용 탄소종이 특성

  • Ham, Eun-Kwang (Korea Institute of Carbon Convergence Technology) ;
  • Yoon, Dong-Ho (R&D Center, KUK IL Paper MFG. Co., Ltd.) ;
  • Kim, Byoung-Suhk (Department of Organic Materials and Fiber Engineering, Chonbuk National University) ;
  • Seo, Min-Kang (Korea Institute of Carbon Convergence Technology)
  • Received : 2016.08.16
  • Accepted : 2016.10.31
  • Published : 2016.10.31

Abstract

In this work, the pitch-based carbon paper (P-CP) was prepared by re-impregnating of binder pitches and PAN-based milled carbon fibers (MCF) at low temperature carbonization process. The influence of MCF content on physicochemical properties of MCF/P-CP was investigated. As a result, the tensile strength of MCF/P-CP was increased sharply from 10 wt.% to 20 wt.% of MCF. Also, the increase of MCF content led to the decrease of interfacial contact resistivity and the improvement of electrical and thermal conductivity of MCF/P-CP. These results were probably due to the increase of density of MCF/P-CP, resulting in the formation of electrically and thermally conductive paths of the carbon paper.

본 연구에서는 피치계 탄소섬유기반 탄소종이에 바인더 피치와 PAN계 미분쇄 탄소섬유를 첨가하여 저온탄화를 통해 재함침된 탄소종이를 제작하였으며, 미분쇄 탄소섬유의 첨가가 탄소종이의 기계적 및 전기적 특성과 열전도도에 미치는 영향을 알아보았다. 실험 결과, 인장강도는 미분쇄 탄소섬유 함량 10 wt.%부터 20 wt.%까지 첨가하였을 때 크게 증가하였다. 또한, 미분쇄 탄소섬유 함량이 증가함에 따라 계면접촉저항은 감소하였으며, 전기전도도 및 열전도도는 증가하였다. 이러한 결과는 미분쇄된 탄소섬유의 첨가가 탄소종이의 밀도를 증가시킴에 따라 전기적 및 열적 전달 경로가 형성되었기 때문이라고 판단된다.

Keywords

References

  1. Lee, K.S., Sim, S.M., and Kim, D.M., "Performance of Fuel Cell with PEMFC Fabricated under Different Pressure", Transactions of the Korean Hydrogen and New Energy Society, Vol. 24, No. 1, 2013, pp. 70-75. https://doi.org/10.7316/KHNES.2013.24.1.070
  2. Kim, S.H., Lee, Y.G., Seo, S.H., Joo, H.J., and Yoon, S.J., "Structural Design and Installation of Tracking-type Floating PV Generation System", Composites Research, Vol. 27, No. 2, 2014, pp. 59-65. https://doi.org/10.7234/composres.2014.27.2.059
  3. Heo, S.I., Oh, K.S., Jang, J.H., Yang, Y.C., and Han, K.S., "A Study on Precuring Condition of the 2-step Manufacturing Method for PEMFC Composite Bipolar Plates", Composites Research, Vol. 20, No. 2, 2007, pp. 10-16.
  4. Kim, B.J., Lim, S.D., Sohn, Y.J., Kim, C.S., Yang, T.H., and Kim, Y.C., "The Effect of Stack Clamping Pressure on the Performance of a Miniature PEMFC Stack", Transactions. of the Korean Hydrogen and New Energy Society, Vol. 20, No. 6, 2009, pp. 499-504.
  5. Stambula, S., Gauquelin, N., Bugnet, M., Gorantla, S., Turner, S., Sun, S., Liu, J., Zhang, G., Sun, X., and Botton, G.S., "Chemical Structure of Nitrogen-Doped Graphene with Single Platinum Atoms and Atomic Clusters as a Platform for the PEMFC Electrode", The Journal of Physical Chemistry C, Vol. 118, 2014, pp. 3890-3900. https://doi.org/10.1021/jp408979h
  6. Chun, J.H., Jo, D.H., Lee, J.Y., and Kim, S.H., "Numerical Study on the Effect of Gas diffusion layer (GDL) Properties in Cathode on the Performance of Polymer Electrolyte Membrane Fuel Cell (PEMFC)", Korean Chemical Engineering Research, Vol. 50, No. 3, 2012, pp. 556-561. https://doi.org/10.9713/kcer.2012.50.3.556
  7. Assumma, L., Nguyen, H.D., Iojoiu, C., Lyonnard, S., Mercier, R., and Espuche, E., "Effects of Block Length and Membrane Processing Conditions on the Morphology and Properties of Perfluorosulfonated Poly(arylene ester sulfone) Multiblock Copolymer Membranes for PEMFC", Applied Materials Interfaces, Vol. 7, 2015, pp. 13808-13820. https://doi.org/10.1021/acsami.5b01835
  8. Park, S.J., Seo, M.K., Park, M.L., and Kim, H.Y., Carbon Materials, Myoungmoon Pub. Co., Seoul, Republic of Korea, 2015.
  9. Ko, T.J., Kim, S.H., Hong, B.K., Lee, K.R., Oh, K.H., and Moon, M.W., "High Performance Gas Diffusion Layer with Hydrophobic Nanolayer under a Supersaturated Operation Condition for Fuel Cells", Applied Materials Interfaces, Vol. 7, 2015, pp. 5506-5513. https://doi.org/10.1021/acsami.5b00088
  10. Lee, J.H., Yoo, Y.J., and Park, S.J., "Preparation and Electrical Properties of Carbon Paper Using Chopped Carbon Fiber", Applied Chemistry for Engineering, Vol. 24, No. 2, 2013, pp. 121-125.
  11. Kim, S.J., Park, S.B., and Park, Y.I., "Fabrication of Gas Diffusion Layer for Fuel Cells Using Heat Treatment Slurry Coating Method", Journal of the Korean Society for Heat Treatment, Vol. 25, No. 2, 2012, pp. 65-73. https://doi.org/10.12656/jksht.2012.25.2.065
  12. Jeong, H.S., Kim, J.I., Lee, S.H., Lim, C.H., Ahn, B.K., and Kim, C.J., "Analysis of Mass Transport in PEMFC GDL", Transactions of the Korean Society of Mechanical Engineers B, Vol. 36, No. 10, 2012, pp. 979-988. https://doi.org/10.3795/KSME-B.2012.36.10.979
  13. Jabbour, L., Robin, C., Nandjou, F., Vincent, R., Micoud, F., Poirot-Crouvezier, J.P., d'Arbigny, J., and Gerard, M., "Feasibility of In-plane GDL Structuration: Impact on Current Density Distribution in Large-area Proton Exchange Membrane fuel Cells", Journal of Power Sources, Vol. 299, 2015, pp. 380-390. https://doi.org/10.1016/j.jpowsour.2015.09.043
  14. Tamayol, A., McGregor, F., and Bahrami, M., "Single Phase Through-pane Permeability of Carbon Paper Gas Diffusion Layers", Journal of Power Sources, Vol. 204, 2012, pp. 94-99. https://doi.org/10.1016/j.jpowsour.2011.11.084
  15. Park, J.M., Oh, H.Y., Cho, J.H., Min, K.D., Lee, E.S., and Jyoung, J.Y., "Study on the Durability Characteristics of the PEM Fuel Cells having Gas Diffusion Layer with Different Micro Porous Layer Penetration Thickness", Transactions of the Korean Hydrogen and New Energy Society, Vol. 24, No. 3, 2013, pp. 216-222. https://doi.org/10.7316/KHNES.2013.24.3.216
  16. Shim, J.P., Han, C.S., Sun, H.J., Park, G.S., Lee, J.J., and Lee, H.K., "Preparation and Characterization for Carbon Composite Gas Diffusion Layer on Polymer Electrolyte Membrane Fuel Cells", Transactions of the Korean Hydrogen and New Energy Society, Vol. 23, No. 1, 2012, pp. 34-42. https://doi.org/10.7316/khnes.2012.23.1.034
  17. Choi, J.M., Kim, T.J., Hyun, M.S., Peck, D.H., Kim, S.K., Lee, B.R., Park, J.S., and Jung, D.H., "Preparation of Bipolar Plated for Fuel Cell Using CNT/Graphite Nano-Composite", Carbon Science, Vol. 6, No. 3, 2005, pp. 181-187.
  18. Hung, C.J., Liu, C.H., Wang, C.H., Chen, W.H., Shen, C.W., Liang, H.C., and Ko, T.H., "Effect of Conductive Carbon Material Content and Structure in Carbon Fiber Paper Made from Carbon Felt on the Performance of a Proton Exchange Membrane Fuel Cell", Renewable Energy, Vol. 78, 2015, pp. 364-373. https://doi.org/10.1016/j.renene.2015.01.021
  19. Lee, J.J., Kim, I.T., Zhang, Y., Lee, H.K., and Shim, J.P., "Comparison of Cell Performance with Physical Properties of Gas Diffusion Layers in PEMFCs", Journal of the Korean Electrochemical Society, Vol. 10, No. 4, 2007, pp. 270-278. https://doi.org/10.5229/JKES.2007.10.4.270
  20. Zamel, N., Litovsky, E., Li, X., and Kleiman, J., "Measurement of the Through-plane Thermal conductivity of Carbon Paper Diffusion Media for the Temperature Range from -50 to $+120^{\circ}C$", International Journal of Hydrogen Energy, Vol. 36, No. 2, 2011, pp. 12618-12625. https://doi.org/10.1016/j.ijhydene.2011.06.097

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