DOI QR코드

DOI QR Code

The Efficiency Characteristics of the Ferroelectric Polymer Added Organic Solar-cells

강유전 고분자를 첨가한 유기태양전지의 효율 특성

  • Park, Ja young (Department of Laser and Optical Information Technology, Cheongju University) ;
  • Jung, Chi Sup (Department of Laser and Optical Information Technology, Cheongju University)
  • 박자영 (청주대학교 레이저광정보공학과) ;
  • 정치섭 (청주대학교 레이저광정보공학과)
  • Received : 2016.03.21
  • Accepted : 2016.06.16
  • Published : 2016.09.01

Abstract

P3HT:PCBM bulk heterojunction solar cells added with ferroelectric polymer were fabricated and characterized. By incorporating P3HT:PCBM solar cell with P(VDF-TrFE) ferroelectric additive, the power conversion efficiency was increased up to nearly 50%. Photoacoustic analysis on this phenomena was carried out for the first time. Through this study, we find that the ferroelectricity of the polymer additive plays the key role in the enhancement of the power conversion efficiency of the organic solar cell by suppressing the non-radiative recombination of charge transfer exciton more effectively.

Keywords

References

  1. F. C. Krebs, Sol. Energy Mater. Sol. Cells, 93, 394 (2004). [DOI: http://dx.doi.org/10.1016/j.solmat.2008.10.004]
  2. C. J. Brabec, Sol. Energy Mater. Sol. Cells, 83, 273 (2004). [DOI: http://dx.doi.org/10.1016/j.solmat.2004.02.030]
  3. C. H. Bang, The Korean Vacuum Society, 16, 167-171 (2007). [DOI: http://dx.doi.org/10.5757/JKVS.2007.16.3.167]
  4. J. Y. Lee, The Korean Physical Society, 21, 20-30 (2012).
  5. D. Veldman,S.C.J. Meskers, and R.A.J. Janssen, Adv. Funct. Mater., 19, 1939-1948 (2009). [DOI: http://dx.doi.org/10.1002/adfm.200900090]
  6. T. Kirchartz, K. Taretto, and U. Rau, J. Phys. Chem. C, 113, 17958-17966 (2009). [DOI: http://dx.doi.org/10.1021/jp906292h]
  7. D. Veldman, O. Ipek, S.C.J. Meskers, J. Sweelssen, M. M. Koetse, S. C. Veenstra, J. M. Kroon, S. S. van Bavel, J. Loos, and R.A.J. Janssen, J. Am. Chem. Soc., 130, 7721-7735 (2008). [DOI: http://dx.doi.org/10.1021/ja8012598]
  8. K. S. Nalwa, J. A. Carr, R. C. Mahadevapuram, H. K. Kodali, S. Bose, Y. Chen, J. W. Petrich, B. Ganapathysubramanian, and S. Chaudhary, Energy Environ, Sci., 2012, 7042 (2012). [DOI: http://dx.doi.org/10.1039/C2EE03478F]
  9. K. Vandewal, K. Tvingstedt, A. Gadisa, O. Inganas, and J. V. Manca, Nature Mater., 8, 904-909 (2009). [DOI: http://dx.doi.org/10.1038/nmat2548]
  10. V. Shrotriya, Y. Yao, G. Li, and Y. Yang, Appl. Phys. Lett., 89, 063505 (2006). [DOI: http://dx.doi.org/10.1063/1.2335377]
  11. Y. Yuan, T. J. Reece, P. Sharma, S. Poddar, S. Ducharme, A. Gruverman, Y. Yang, and J. Huang, Nature Materials, 10, 296 (2011). [DOI: http://dx.doi.org/10.1038/nmat2951]
  12. K. Asadi and P. de Bruyn, Appl. Phys. Lett., 98, 183301 (2011). [DOI: http://dx.doi.org/10.1063/1.3587630]
  13. V. D. Mihailetchi, L.J.A. Koster, J. C. Hummelen, and P.W.M. Blom, Phys. Rev. Lett., 93, 216601-216604 (2004). [DOI: http://dx.doi.org/10.1103/PhysRevLett.93.216601]
  14. L. B. Kreuzer, Optoacoustic Spectroscopy and Detection, Chap 1, Y. H. Pao Ed. (Academic Press, 1977)
  15. B. Yang, J. Cox, Y. Yuan, F. Guo, and J. Huang, Appl. Phys. Lett., 99, 133302 (2011). [DOI: http://dx.doi.org/10.1063/1.3643450]
  16. T. Kirchartz, K. Taretto, and U. Rau, J. Phys. Chem. C, 113, 17958 (2009). [DOI: http://dx.doi.org/10.1021/jp906292h]
  17. D. Shvydka and V. G. Karpov, Appl. Phys. Lett., 92, 053507 (2008). [DOI: http://dx.doi.org/10.1063/1.2835972]