Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Synthesis of a Platinum-Pincer Complex and Application to Catalytic Silylcyanation

백금 핀서 화합물의 합성 및 Silylcyanation 촉매반응에 대한 응용

  • Kim, Yun Tae (Department of Pharmaceutical Engineering, Hoseo University) ;
  • Yoon, Myeong Sik (Department of Pharmaceutical Engineering, Hoseo University)
  • 김윤태 (호서대학교 제약공학과) ;
  • 윤명식 (호서대학교 제약공학과)
  • Received : 2016.04.04
  • Accepted : 2016.05.24
  • Published : 2016.08.10
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Abstract

A platinum(II) pincer complex composed of two six-membered fused metallacycles was directly synthesized using 1,3-bis(2-pyridyloxy)benzene and $K_2PtCl_4$. The structure of the complex was elucidated via NMR and X-ray crystallography analysis. The stable complex was formed due to the six-membered fused cycle structure around the Pt(II) center which reduced the bond angle strain. The complex was applied to the silylcyanation reaction of aldehydes and imines and showed an efficient catalytic activity with 99% yield.

본 연구에서는 1,3-bis(2-pyridyloxy)benzene과 $K_2PtCl_4$를 이용하여 백금을 중심으로 2개의 6원환을 이루는 백금 핀서 화합물을 합성하였다. NMR과 X-ray를 이용하여 구조를 규명하였고 백금원자를 중심으로 이루는 6원환 구조는 angle strain을 감소시켜 안정한 화합물을 형성하였다. 이 화합물을 알데하이드와 이민의 silylcyanation 반응에 적용하여 본 결과 수율 99%까지 나타내는 효과적인 촉매작용을 보여주었다.

Keywords

References

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