DOI QR코드

DOI QR Code

Flow Characteristics Analyses within the Electrolysis Reactor using the CFD Simulation Technique

CFD 모사 기법을 이용한 전해반응기 내부 흐름 특성 분석

  • 정종식 (욱성화학(주) 기술연구소) ;
  • 이승재 (GS건설(주) 환경공정설계팀) ;
  • 이재복 (경성대학교 건설환경도시공학부)
  • Received : 2016.09.01
  • Accepted : 2016.12.19
  • Published : 2016.12.23

Abstract

The objective of this study was to investigate design factors of the electrolysis reactor through the CFD(computational fluid dynamics) simulation technique. Analyses of velocity vector, streamline, chloride ion concentration distribution showed differences in flow characteristics between the plate type electrode and the porous plate type electrode. In case of the porous plate type electrode, chlorine gas bubbles generated from the anode made upward density flow with relatively constant velocity vectors. Electrolysis effect was more expected with the porous plate type electrode from the distribution of chloride ion concentration. The upper part of the electrolysis reactor with the porous plate type electrode had comparatively low chloride concentration because chloride was converted to the chlorine gas formation. Decreasing the size and increasing total area of rectifying holes in the upper part of cathodes, and widening the area of the rectifying holes in the lower part of cathodes could improve the circulation flow and the efficiency of electrolysis reactor.

Keywords

References

  1. Brillas, E., Calpe, J. C. and Casado, J. (2000) Mineralization of 2,4-D by Advanced Electrochemical Oxidation Processes, Wat. Res., 34(8), 2253-2262. https://doi.org/10.1016/S0043-1354(99)00396-6
  2. Chiang, L. C., Chang, J. E. and Wen, T. C. (1995) Indirect Oxidation Effect in Electrochemical Oxidation Treatment of Landfill Leachate, Wat. Res., 29(2), 671-678. https://doi.org/10.1016/0043-1354(94)00146-X
  3. Dziewinski, J., Marczak, S., Nuttall, E. and Smith, W. (1996) Electrochemical Treatment of Mixed and Hazardous Wastes, Mat. Res. Soc. Sypm. Proc., 412, 509-516.
  4. Guohua, C. (2004) Electrochemical Technologies in Wastewater Treatment, Separation and Purification Technology, 38, 11-41. https://doi.org/10.1016/j.seppur.2003.10.006
  5. Hwang, Y. J., Lim, S. E., Kim, S. S., Park, N. S. and Wang, C. K. (2009) Evaluation of Head Loss within In-Line Mixer for Water Treatment using CFD Technique, Journal of Korean Society of Water and Wastewater, 23(1), 107-112.
  6. Jayanti, S. and Narayanan, S. (2004) Computational Study of Particle-Eddy Interaction in Sedimentation Tanks, ASCE, Journal of Environmental Engineering, 130, 37-49. https://doi.org/10.1061/(ASCE)0733-9372(2004)130:1(37)
  7. Jonnalagadda, S. B. and Nadupalli, S. (2004) Effluent Treatment Using Electrochemically Bleached Seawater-Oxidative Degradation of Pollutants, Talanta, 64, 18-22. https://doi.org/10.1016/j.talanta.2003.11.045
  8. Laminie, J. and Dicks, A. (2003) Fuel Cell System Explained, Chapter 6, 2nd Ed., John Wiley and Sons, New York.
  9. Lee, S. J., Shin, E, H., Kim, S. H and Park, H K. (2011a) Dead Zone Analysis for Estimating Hydraulic Efficiency in Rectangular Disinfection Chlorine Contactors, Environmental Engineering Science, 28(1) 25-33. https://doi.org/10.1089/ees.2010.0035
  10. Lee, S. J., Kim, T. Y., and Park, H. K. (2011b) Comparison of Multi-Inlet and Serpentine Channel Design on Water Production of PEMFCs, Chemical Engineering Science, 66(8) 1748-1758 https://doi.org/10.1016/j.ces.2011.01.007
  11. Lee, A., Park, N., Kim, S. and Kim, N. (2012) Physical Modifications to Improve a Channel's Flow Distribution. Korean Journal of Chemical Engineering, 29(2), 201-208. https://doi.org/10.1007/s11814-011-0163-9
  12. Lee, S. J., Park, N. S., and Park, H. K. (2016) Development of New Disinfection Indicator in Chlorine Contact Tanks, Environmental Engineering Science, 33(6), 374-383. https://doi.org/10.1089/ees.2015.0458
  13. Park, D. J., Park, Y. O., Park, N. S., Kim, S. S. and Wang, C. K. (2008) Evaluation of Flow Characteristics within In-Line Mixer for Water Treatment using CFD Technique, Journal of Korean Society of Water and Wastewater, 22(3), 351-358.
  14. Park, N. S. and Park, H. (2002) Analysis of Local Velocity Gradients in Rapid Mixer Using Particle Image Velocimetry Technique, Water Science and Technology: Water Supply, 2(5-6), 47-55. https://doi.org/10.2166/ws.2002.0149
  15. Park, N. S., Yoon, S. M., Jeong, W. C. and Lee, S. J. (2016) Improving Flow Distribution in Influent Channels Using Computational Fluid Dynamics, Water Science and Technology, 74(8), 1855-1866. https://doi.org/10.2166/wst.2016.358
  16. Park, Y. O., Park, N. S., Kim, S. S., Kim, K. D and Lim, K. H. (2008) Evaluation of Coagulation Dispersion in Pump Diffusion Mixer for Water Treatment, Journal of Korean Society of Water and Wastewater, 22(1), 49-63.
  17. Stovin, V. R. and Saul A. J. (1996) Efficiency Prediction for Storage Chambers Using Computational Fluid Dynamics, Water Science and Technology, 33(9), 163-170. https://doi.org/10.1016/0273-1223(96)00383-6
  18. Yu, J. and Kupferle, M. J. (2008) Two-stage Sequential Electrochemical Treatment of Nitrate Brine Wastes, Water Air Soil Pollution, 8, 379-385. https://doi.org/10.1007/s11267-007-9153-7