DOI QR코드

DOI QR Code

Effects of Pulp Pre-treatment and Grinder Clearance on the Manufacturing Characteristics of Microfibrillated Cellulose

펄프의 전처리 및 그라인더 간격이 MFC 제조 특성에 미치는 영향

  • Yong, Seong Moon (Dept. of Paper Science & Engineering, College of Forest & Environmental Sciences, Kangwon National University) ;
  • Kwak, Gun Ho (Dept. of Paper Science & Engineering, College of Forest & Environmental Sciences, Kangwon National University) ;
  • Cho, Byoung-Uk (Dept. of Paper Science & Engineering, College of Forest & Environmental Sciences, Kangwon National University) ;
  • Lee, Yong Kyu (Dept. of Paper Science & Engineering, College of Forest & Environmental Sciences, Kangwon National University) ;
  • Won, Jong Myoung (Dept. of Paper Science & Engineering, College of Forest & Environmental Sciences, Kangwon National University)
  • 용성문 (강원대학교 산림환경과학대학 제지공학과) ;
  • 곽건호 (강원대학교 산림환경과학대학 제지공학과) ;
  • 조병욱 (강원대학교 산림환경과학대학 제지공학과) ;
  • 이용규 (강원대학교 산림환경과학대학 제지공학과) ;
  • 원종명 (강원대학교 산림환경과학대학 제지공학과)
  • Received : 2015.04.09
  • Accepted : 2015.04.23
  • Published : 2015.04.30

Abstract

A number of researches have been carried out regarding the utilization of nanocellulose(crystalline nanocellulose, microfibrillated cellulose, nanofibrillated cellulose) for the manufacture of various kinds of composites and functional products. However, only few research works on the manufacturing characteristics of nanocellulose could be found, although some companies started already the production of nanocellulose in commercial scale. However, the most important thing in commercializing of production and utilization of nanocellulose is to develop the economical and efficient process. Thus, this study was carried out in order to investigate the effects of refining, alkaline pre-treatment and grinder clearance on the characteristics of microfibrillated cellulose and energy consumption. There was no significant differences in crystalline index with the degree of microfibrillation. The initial fibrillation could be improved by refining pre-treatment, but its effect was not observed anymore since the fibrillation was done up to certain level by grinding. Refining pre-treatment did not improved the energy efficiency. Alkaline pre-treatment can be helpful because the swelling of pulp fiber will facilitate fibrillation. It was found that the decrease in grinder clearance was helpful to improve the energy efficiency.

Keywords

References

  1. Esau, K., Anatomy of seed plants, Wiley and Sons, Chichester(1977).
  2. Turbak, A.F., Snyder, F.W. and Sandberg, K.R., Microfibrillated cellulose, a new cellulose product : Properties, uses and commercial potential, Proceedings of 9th Cellulose Conference, J. Appl. Polym. Sci. : Applied Polymer Symposia 37:815-827(1983).
  3. Herrick, F.W., Casebier, R.L., Hamilton, J.K. and Sandberg, K.R., Microfibrillated cellulose: morphology and accessibility, J. Appl. Polym. Sci.: Appllied Polymer Symposia 37:797-813 (1983).
  4. Saito, T. and Isogai, A., Ion-exchange behavior of carboxylate groups in fibrous cellulose oxidized by the TEMPO-mediated system, Carbohydrate Polymer 61:183-190(2005). https://doi.org/10.1016/j.carbpol.2005.04.009
  5. Saito, T. and Isogai, A., Introduction of aldehyde groups on surfaces of native cellulose fibers by TEMPO-mediated oxidation, Colloids Surface A - Physicochem. Eng. Asp. 289:219-225(2006). https://doi.org/10.1016/j.colsurfa.2006.04.038
  6. Saito, T. and Isogai, A., Wet strength improvement of TEMPO-oxidized cellulose sheets prepared with cationic polymers, Ind. Eng. Chem. Res. 46:773-780 (2007). https://doi.org/10.1021/ie0611608
  7. Saito, T., Hirota, M., Tamura, N., Kimura, S., Fukuzumi, H., Heux, L. and Isogai, A., Individualization of nanosized plant cellulose fibrils by direct surface carboxylation using TEMPO catalyst under neutral conditions, Biomacromolecules 10:1992-1996(2009). https://doi.org/10.1021/bm900414t
  8. Saito, T., Kimura, S., Nishiyama, Y. and Isogai, A., Cellulose nanofibers prepared by TEMPO-mediated oxidation of native cellulose, Biomacromolecules 8:2485-2491(2007). https://doi.org/10.1021/bm0703970
  9. Saito, T., Nishiyama, Y., Putaux, J.L., Vignon, M. and Isogai, A., Homogeneous suspensions of individualized microfibrils from TEMPO-catalyzed oxidation of native cellulose, Biomacromolecules 7:1687-1691(2006). https://doi.org/10.1021/bm060154s
  10. Saito, T., Yanagisawa, M. and Isogai, A., TEMPOmediated oxidation of native cellulose: SEC-MALLS analysis of water-soluble and -insoluble fractions in the oxidized products, Cellulose 12:305-315(2005). https://doi.org/10.1007/s10570-004-5835-8
  11. Henriksson, M., Henriksson, G., Berglund, L.A. and Lindstrom, T., An environmentally friendly method for enzyme-assisted preparation of microfibrillated cellulose nanofibers, European Polymer Journal 43:3434-3441(2007). https://doi.org/10.1016/j.eurpolymj.2007.05.038
  12. Spence, K.L., Venditti, R.A., Habibi, Y., Rojas, O.J. and Pawlak, J.J., Aspects of raw materials and processing conditions on the production and utilization of microfibrillated cellulose, International Conference on Nanotechnology for the Forest Products Industry (2010).
  13. Spence, K.L., Venditti, R.A., Rojas, O.J., Habibi, Y. and Pawlak, J.J., A comparative study of energy consumption and physical properties of microfibrillated cellulose produced by different processing methods, Cellulose 18:1097-1111(2011). https://doi.org/10.1007/s10570-011-9533-z
  14. Meyer, V., Tapin-Lingua, S., Perez, D.D.S, Arndt, T. and Germgard, U., Influence of mechanico-enzymatic and chemical pre-treatment methods on NFC preparation, SUNPAP Workshop(2011).
  15. Paakko, M., Ankerfors, M., Kosonen, H., Nykanen, A., Ahola, S., Osterberg, M., Ruokolainen, J., Laine, J., Larsson, P.T., Ikkala, O. and Lindstrom, T., Enzymatic hysrolysis combined with mechanical shearing and high-pressure homogenization for nanoscale cellulose fibrils and strong gels, Biomacrocules 8:1934-1941(2007). https://doi.org/10.1021/bm061215p
  16. Ryu, J., Youn, H.J., S대, D.J., Yang, J.Y. and Ryu, J.-B., Production of nanofibrillated cellulose using grinder and its characterization, Proceedings of Spring Conference of the KTAPPI, pp. 201-205 (2011).