Advances in environmental research

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Photocatalytic degradation of textile dye CI Basic Yellow 28 wastewater by Degussa P25 based TiO2

  • Konecoglu, Gulhan (Yildiz Technical University, Chemical Engineering Department, Davutpasa Campus) ;
  • Safak, Toygun (Yildiz Technical University, Chemical Engineering Department, Davutpasa Campus) ;
  • Kalpakli, Yasemen (Yildiz Technical University, Chemical Engineering Department, Davutpasa Campus) ;
  • Akgun, Mesut (Yildiz Technical University, Chemical Engineering Department, Davutpasa Campus)
  • Received : 2014.01.28
  • Accepted : 2015.02.25
  • Published : 2015.03.25
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Abstract

Wastewaters of textile industry cause high volume colour and harmful substance pollutions. Photocatalytic degradation is a method which gives opportunity of reduction of organic pollutants such as dye containing wastewaters. In this study, photocatalytic degradation of C.I. Basic Yellow 28 (BY28) as a model dye contaminant was carried out using Degussa P25 in a photocatalytic reactor. The experiments were followed out at three different azo dye concentrations in a reactor equipped UV-A lamp (365 nm) as a light source. Azo dye removal efficiencies were examined with total organic carbon and UV-vis measurements. As a result of experiments, maximum degradation efficiency was obtained as 100% at BY28 concentration of $50mgL^{-1}$ for the reaction time of 2.5 h. The photodegradation of BY28 was described by a pseudo-first-order kinetic model modified with the langmuir-Hinshelwood mechanism. The adsorption equilibrium constant and the rate constant of the surface reaction were calculated as $K_{dye}=6.689{\cdot}10^{-2}L\;mg^{-1}$ and $k_c=0.599mg\;L^{-1}min^{-1}$, respectively.

Keywords

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