Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Oxidation of Ethylbenzene Using Nickel Oxide Supported Metal Organic Framework Catalyst

  • Received : 2014.05.12
  • Accepted : 2014.07.09
  • Published : 2014.11.20
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Abstract

A metal organic framework-supported Nickel nanoparticle (Ni-MOF-5) was successfully synthesized using a simple impregnation method. The obtained solid acid catalyst was characterized by Powder X-ray diffraction (XRD), scanning electron microscopy (SEM), nitrogen adsorption-desorption and thermogravimetric analysis (TGA). The catalyst was highly crystalline with good thermodynamic stability (up to $400^{\circ}C$) and high surface area ($699m^2g^{-1}$). The catalyst was studied for the oxidation of ethyl benzene, and the results were monitored via gas chromatography (GC) and found that the Ni-MOF-5 catalyst was highly effective for ethyl benzene oxidation. The conversion of ethyl benzene and the selectivity for acetophenone were 55.3% and 90.2%, respectively.

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References

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