Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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A New Coumarin-Based Colorimetric and Fluorometric Sensor for Cu2+

  • An, Kyoung-Lyong (Interface Materials & Process Research Group, Korea Research Institute of Chemical Technology) ;
  • Park, Koon Ha (Department of Chemistry, Chungnam National University) ;
  • Jun, Kun (Interface Materials & Process Research Group, Korea Research Institute of Chemical Technology)
  • Received : 2014.03.03
  • Accepted : 2014.03.18
  • Published : 2014.07.20
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Abstract

Keywords

Experimental

Synthesis of Sensor A. To a solution of compound 2 (0.3 g, 1.3 mmol) in absolute ethanol (15 mL), was added 2- hydroxycinnamaldehyde (0.22 g, 1.4 mmol). After the mixture was stirred for 20 h at room temperature, a reddish precipitate was filtered, washed with ethanol (10 mL) and cold acetone (20 mL). It was dried under vacuum to afford a reddish crystalline solid (0.24 g, 50％). HRMS (EI): 362.1627 (calcd. for C22H22N2O3, 362.1630); 1H-NMR (DMSO-d6, 500 MHz) δ 10.14 (s, 1H), 8.85 (d, 1H), 7.69 (s, 1H), 7.59 (d, 1H), 7.46 (d, 1H), 7.43 (s, 1H), 7.18 (t, 1H), 7.10 (m, 1H), 6.89 (d, 1H), 6.83 (t, 1H), 6.72 (d, 1H), 6.55 (s, 1H), 3.43 (m, 4H), 1.12 (t, 6H); 13C NMR (DMSO-d6, 125 MHz) δ 162.7, 158.0, 155.8, 154.2, 149.9, 139.1, 132.9, 130.4, 129.1, 128.5, 127.8, 122.3, 119.3, 116.0, 109.3, 108.3, 96.3, 43.9, 12.2.

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