DOI QR코드

DOI QR Code

Characteristics of Gas- and Particle-phase Polycyclic Aromatic Hydrocarbon (PAH) Distribution in Tunnels

터널 내 기체 및 입자상 다환방향족탄화수소(PAH) 분포 특성

  • Lee, Ji Yi (Department of Environmental Engineering, Chosun University) ;
  • Lee, Seung-Bok (Center for Environment, Health and Welfare Research, Korea Institute of Science and Technology) ;
  • Kim, Jin Young (Center for Environment, Health and Welfare Research, Korea Institute of Science and Technology) ;
  • Jin, Hyoun Cher (Center for Environment, Health and Welfare Research, Korea Institute of Science and Technology) ;
  • Lim, Hyung Bae (Department of Environmental Engineering, Chosun University) ;
  • Bae, Gwi-Nam (Center for Environment, Health and Welfare Research, Korea Institute of Science and Technology)
  • 이지이 (조선대학교 환경공학과) ;
  • 이승복 (한국과학기술연구원 환경복지연구단) ;
  • 김진영 (한국과학기술연구원 환경복지연구단) ;
  • 진현철 (한국과학기술연구원 환경복지연구단) ;
  • 임형배 (조선대학교 환경공학과) ;
  • 배귀남 (한국과학기술연구원 환경복지연구단)
  • Received : 2014.07.28
  • Accepted : 2014.11.25
  • Published : 2014.12.31

Abstract

Twenty four individual polycyclic aromatic hydrocarbon (PAH) compounds both in gas- and particle-phase were quantified in three tunnels (Namsan Tunnel 3, Jeongneung Tunnel, Bukak Tunnel) to characterize vehiculate emission of PAHs. Gas phase PAHs were dominant in tunnels which consisted of 85% of total PAHs concentrations. Naphthalene and 2-methyl naphthalene were the most abundant gas phase PAH compounds, while the concentrations of fluoranthene and pyrene were highest in the particle phase. Most (96%) of the gas phase PAH compounds consisted of two- and three-aromatic rings whereas most of the particle phase PAHs were in four and five-rings (67%) in tunnels. Average BaP-eq concentrations of PAHs in the particle phase ($20.8{\pm}11.6ngm^{-3}$) was about twenty fold higher than that in the gas phase ($1.6{\pm}0.6ngm^{-3}$). It means that the particle phase PAHs has more adverse health effect than the gas phase PAHs even though the concentrations of the particle phase PAHs were lower than those of the gas phase PAHs. Compared to previous studies reporting diagnostic ratios for specific PAH compounds, the profile of individual PAH compounds measured in this study reflected well for the vehiculate emissions. We reported, for the first time, on the results of the profile of individual PAH compounds measured in tunnels for both gas and particle phases.

Keywords

References

  1. Fang, G.C., Y.S. Wu, M.H. Chen, T.T. Ho, S.H. Huang, and Y. Rau (2004) Polycyclic aromatic hydrocarbons study in Taichung, Taiwan, during 2002-2003, Atmos. Environ., 38, 3385-3391. https://doi.org/10.1016/j.atmosenv.2004.03.036
  2. Ghim, Y.S., N.H. Kyung, S.H. Cho, J.E. Son, K.C. Moon, Y. P. Kim, N.J. Baik, and T.O. Kim (1993) Measurements of gaseous pollutants in major tunnels in Seoul, J. Korean Soc. Atmos. Environ., 9(4), 320-328. (in Korean with English abstract)
  3. Gogou, A.I., N. Stratigakis, M. Kanakidou, and E.G. Stephanou (1996) Organic aerosols in Eastern Mediterranean: components source reconciliation by using molecular markers and atmospheric back trajectories, Org. Geochem., 25, 79-96. https://doi.org/10.1016/S0146-6380(96)00105-2
  4. Guo, H., S.C. Lee, K.F. Ho, X.M. Wang, and S.C. Zou (2003) Particle-associated polycyclic aromatic hydrocarbons in urban air of Hong Kong, Atmos. Eviron., 37, 5307-5317.
  5. Ho, K.F., S.S.H. Ho, S.C. Lee, Y. Cheng, J.C. Chow, J.G. Watson, P.K.K. Louie, and L. Tian (2009) Emissions of gas- and particle-phase polycyclic aromatic hydrocarbons (PAHs) in the Shing Mun Tunnel, Hong Kong, Atmos. Environ., 43, 6343-6351. https://doi.org/10.1016/j.atmosenv.2009.09.025
  6. IARC (2013) Agents classfied by the IARC monographs, volume 1-107, available at http://monographs.iarc.fr/ENG/Classification/index.php.
  7. Khalili, N.R., P.A. Scheff, and T.M. Holsen (1995) PAH source fingerprints for coke ovens, diesel and gasoline engines, highway tunnels, and wood combustion emissions, Atmos. Eviron., 29, 533-542.
  8. Kim, J.Y., J.Y. Lee, S.-D. Choi, Y.P. Kim, and Y.S. Ghim (2011) Gaseous and particulate polycyclic aromatic hydrocarbons at the Gosan background site in East Asia, Atmos. Environ., 49, 311-319.
  9. Kim, J.Y., J.Y. Lee, Y.P. Kim, S.-B. Lee, H.C. Jin, and G.-N. Bae (2012) Seasonal characteristics of the gaseous and particulate PAHs at a roadside station in Seoul, Korea, Atmos. Res., 116, 142-150. https://doi.org/10.1016/j.atmosres.2012.03.011
  10. Lee, J.Y. and D.A. Lane (2009) Unique products from the reaction of naphthalene with the hydroxyl radical, Atmos. Environ., 43, 4886-4893. https://doi.org/10.1016/j.atmosenv.2009.07.018
  11. Lee, J.Y. and D.A. Lane (2010) Formation of oxidized products from the reaction of gaseous phenanthrene with the OH radical in a reaction chamber, Atmos. Environ., 44, 2469-2477. https://doi.org/10.1016/j.atmosenv.2010.03.008
  12. Lee, J.Y. and Y.P. Kim (2007) Source apportionment of the particulate PAHs at Seoul, Korea: impact of long range transport to a megacity, Atmos. Chem. Phys., 7, 3587-3596. https://doi.org/10.5194/acp-7-3587-2007
  13. Mandalakis, M., M. Tsapakis, A. Tsoga, and E.G. Stephanou (2002) Gas-particle concentrations and distribution of aliphatic hydrocarbons, PAHs, PCBs and PCDD/Fs in the atmosphere of Athens (Greece), Atmos. Environ., 36, 4023-4035. https://doi.org/10.1016/S1352-2310(02)00362-X
  14. NIER (2012) Annual report of air quality in Korea 2011, National Institute of Environmental Research (NIER) of MOE, 12 pp.
  15. Park, S.S., Y.J. Kim, and C.H. Kang (2002) Atmospheric polycyclic aromatic hydrocarbons in Seoul, Korea, Atmos. Environ., 36, 2917-2924. https://doi.org/10.1016/S1352-2310(02)00206-6
  16. Ramirez, N., A. Cuadras, E. Rovira, R.M. Marce, and F. Borrull (2011) Risk assessment related to atmospheric polycyclic aromatic hydrocarbons in gas and particle phases near industrial sites, Environ. Health Perspect., 119, 1110-1116. https://doi.org/10.1289/ehp.1002855
  17. Ravindra, K., E. Wauters, S.K. Taygi, S. Mor, and R. Van Grieken (2006b) Assessment of air quality after the implementation of CNG as fuel in public transport in Delhi, India, Environ. Monit. Assess., 115, 405-417. https://doi.org/10.1007/s10661-006-7051-5
  18. Ravindra, K., L. Bences, E. Wauters, J. de Hoong, F. Deutsch, E. Roekens, N. Bleux, P. Bergmans, and R. Van Grieken (2006a) Seasonal and site specific variation in vapor and aerosol phase PAHs over Flanders (Belgium) and their relation with anthropogenic activities, Atmos. Environ., 40, 771-785. https://doi.org/10.1016/j.atmosenv.2005.10.011
  19. Rogge, W.F., L.M. Hildemann, M.A. Mazurek, G.R. Cass, and B.R.T. Simoneit (1993a) Sources of fine organic aerosol: 2. Noncatalyst and catalyst-equipped automobiles and heavy-duty diesel trucks, Environ. Sci. Technol., 27, 636-651. https://doi.org/10.1021/es00041a007
  20. Rogge, W.F., L.M. Hildemann, M.A. Mazurek, G.R. Cass, and B.R.T. Simoneit (1993b) Sources of fine organic aerosol: 5. Natural gas home appliances, Environ. Sci. Technol., 27, 2736-2744. https://doi.org/10.1021/es00049a012
  21. Schauer, J.J., M.J. Kleeman, G.R. Cass, and B.R.T. Simoneit (1999) Measurement of emissions from air pollution sources. 2. C1 through $C_{30}$ organic compounds from medium duty diesel trucks, Environ. Sci. Technol., 33, 1578-1587. https://doi.org/10.1021/es980081n
  22. Schauer, J.J., M.J. Kleeman, G.R. Cass, and B.R.T. Simoneit (2002) Measurement of emissions from air pollution sources. 5. $C_1-C_{32}$ organic compounds from gasoline-powered motor vehicles, Environ. Sci. Technol., 36, 1169-1180. https://doi.org/10.1021/es0108077
  23. WHO(2000) Air quality guidelines for Europe. 2nd ed. Copenhagen: WHO, Regional office for Europe (Copenhagen).
  24. Wingfors, H., A. Sjodin, P. Haglund, and E. Brorstrom-Lunden (2001) Characterization and determination of profiles of polycyclic aromatic hydrocarbons in a traffic tunnel in Gothenberg, Sweden, Atmos. Eviron., 35, 6361-6369.