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Study of the Inhibition on the Combustion of PEBAX/AP Thermoplastic Propellant

PEBAX/AP 열가소성 고체추진제의 연소 억제 방안 연구

  • Lee, Hyoungjin (PGM R&D Lab., LIG Nex1 Co., Ltd.) ;
  • Jung, Haeyoung (Research and Development Team, LIG Poongsan Protech) ;
  • Cho, Junhyun (Research and Development Team, LIG Poongsan Protech) ;
  • Lee, Youngguen (Research and Development Team, LIG Poongsan Protech) ;
  • Lee, Hojin (Research and Development Team, LIG Poongsan Protech)
  • Received : 2013.07.11
  • Accepted : 2013.08.26
  • Published : 2013.10.01

Abstract

This study suggested techniques to reduce burning rate and their effects for the AP thermoplastic composite propellant. Burning rate obtained through ground tests using a small size motor were analyzed to investigate the effects of AP particle size and LiF of 0.5~2.0% on the inhibition reaction for the PEBAX/AP thermoplastic propellant. The results showed that utilization of large size particle of AP and addition of LiF under 2.0% can reduce the burning rate sufficiently and their quantitative effects were suggested in this paper.

AP 기반의 혼합형 열가소성 고체 추진제의 연소 억제 방안과 그 효과를 제시하였다. 입자 사이즈가 다른 AP를 적용한 효과와 0.5%~2.0%의 LiF가 미치는 영향을 분석하기 위해 PEBAX/AP 열가소성 고체 추진제에 대한 지상연소 시험을 통해 연소속도 및 압력 지수를 산출한 후 비교 분석하였다. 분석결과, 큰 AP 입자 사이즈를 적용하는 것과 2.0% 이내의 LiF 첨가는 연소속도를 감소시키는 효과를 보였으며 본 논문에서는 이에 대한 각각의 영향을 정량적으로 제시하였다.

Keywords

References

  1. Yim Y., "The Tendency in Solid Propellant Technolgoy for Missiles," Journal of the Korean Society of Propulsion Engineers, Vol. 9, No. 1, pp. 112-120, 2005.
  2. Davenas, A., Solid Rocket Propulsion Technolgy, Pergamon Press, 1993.
  3. Bakhman, N.N., Nikiforov, V.S., Avdyunin, V.I., Fogelzan, A.E., Kichin, Y.S., "Catalytic Effect of Ferrous Oxide on Burning Rate of Condensed Mixtures," Combustion and Flame, Vol. 22, No. 77, pp. 77-87, 1974. https://doi.org/10.1016/0010-2180(74)90012-1
  4. Korobeinichev, O.P., Anisiforov, G.I., Tereschenko, A.G., "High Temperature Decomposition of Ammonium Perchlorate -Polystyrene - Catalyst Mixtures," AIAA Journal, Vol. 13, No. 5, pp. 628-633, 1975. https://doi.org/10.2514/3.49776
  5. Krishnan, S., Jeenut, R., "Combustion Characteristics of AP/HTPB Propellants with Burning Rate Modifiers," Journal of Propulsion and Power, Vol. 8, No. 4, pp. 748-755, 1992. https://doi.org/10.2514/3.23545
  6. Charavarthy, S.R., Price, E.W., Sigman, R.K., "Mechanism of Burning Rate Enhancement of Composite Solid Propellants by Ferric Oxide," Journal of Propulsion and Power, Vol. 13, No. 4, pp. 471-480, 1997. https://doi.org/10.2514/2.5208
  7. Ma, Z., Li, F., Bai, H., "Effect of $Fe_{2}O_{3}$ in $Fe_{2}O_{3}$/AP Composite Particles on Thermal Decomposition of AP and on Burning Rate of the Composite Propellant," Propellant, Explosive, Pyrotechnics, Vol. 31, No. 6, pp. 447-451, 2006. https://doi.org/10.1002/prep.200600060
  8. Hwang, K., Yim, Y., Kim, C., "The Effect of Fe Compounds for Burning Catalyst on HTPB/AP Propellant," Journal of The Korean Society for Aeronautical & Space Sciences, Vol. 25, No. 4, pp. 39-48, 1997.
  9. Kim C., Yoo J., Hwang, K., Yim Y., "Properties of HTPB/AP/Butacene Propellants," Journal of the Korean Society of Propulsion Engineers, Vol. 9, No. 2, 2005.
  10. Kim, J., Yim, Y., Kim, I., Park, Y., Seo, T., Jung, J., Yoo, J., "Increasing the burning rate of solid propellants," 2009 KSPE Spring Conference, pp. 169-172, 2009.
  11. Yim, Y., Kim, J., Yoo, J., "Effect of FeOOH on Burn Rate for AP Propellant," 2010 KSPE Spring Conference, pp. 390-393, 2010.
  12. Poulter, L.W., Nelson, R.W., Smalley Jr., R.B., Hawkins, M.C., "Robust Propellant Liner and Interfacial Propellant Burn Rate Control," US Patent 5767221, Thiokol Corporation, Ogden, UT, USA., 1998.
  13. Chai, Y., Tao, Z., Jiang, Y., "Study on the Catalytic Thermal Decomposition of Sodium Azide and its Correlation with the Burning Rates of Nitrogen Generating Propellants," Journal of Propulsion Technology, Vol. 16, No. 52, 1995.
  14. Kubota, N., Hirata, N., "Inhibition reaction of LiF on the Combustion of Ammonium Percholorate Propellants." Twentieth Symposium International Symposium on Combustion, The Combustion Institute, pp. 2051-2056, 1984.
  15. Yoo, J., Jung, J., Y., Yim, Y., Ko, S., "The Measurement Technique of Burning Rate in Solid Proplellant at High Pressure," Journal of the Korean Society of Propulsion Engineers, Vol. 12, No. 4, pp. 1-6, 2008.