Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Chromium(III) Complex Obtained from Dipicolinic Acid: Synthesis, Characterization, X-Ray Crystal Structure and Electrochemical Studies

  • Ghasemi, Khaled (Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan) ;
  • Rezvani, Ali Reza (Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan) ;
  • Razak, Ibrahim Abdul (X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia) ;
  • Moghimi, Abolghasem (Department of Chemistry, Imam Hossein University) ;
  • Ghasemi, Fatemeh (Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan) ;
  • Rosli, Mohd Mustaqim (X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia)
  • Received : 2013.06.05
  • Accepted : 2013.07.30
  • Published : 2013.10.20
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Abstract

The synthesis, X-ray crystallography, spectroscopic (IR, UV-vis), and electrochemical properties of the title compound, $[H_3O][Cr(dipic)_2][H_3O^+.Cl^-]$ (1), ($H_2dipic$ = 2,6-pyridinedicarboxylic acid), are reported. This complex crystallizes in the monoclinic space group Cc with a = 14.9006(10) ${\AA}$, b = 12.2114(8) ${\AA}$, c = 8.6337(6) ${\AA}$, ${\alpha}=90.00^{\circ}$, ${\beta}=92.7460(10)^{\circ}$, ${\gamma}=90.00^{\circ}$, and V = 1569.16(18) ${\AA}^3$ with Z = 4. The hydrogen bonding and noncovalent interactions play roles in the stabilization of the structure. In order to gain a better understanding of the most important geometrical parameters in the structure of the complex, atoms in molecules (AIM) method at B3LYP/6-31G level of theory has been employed.

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References

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