한국수소및신에너지학회논문집 (Journal of Hydrogen and New Energy)

  • 제24권4호
  • /
  • Pages.282-287
  • /
  • 2013
  • /
  • 1738-7264(pISSN)
  • /
  • 2288-7407(eISSN)
한국수소및신에너지학회 (The Korean Hydrogen and New Energy Society)
권호 표지
DOI QR코드

DOI QR Code

용액 공정 CIGS 박막 태양 전지를 이용한 물 분해 수소 생산

Electrolytic Hydrogen Production Using Solution Processed CIGS thin Film Solar Cells

  • 전효상 (한국과학기술연구원, 청정에너지 연구센터) ;
  • 박세진 (한국과학기술연구원, 청정에너지 연구센터) ;
  • 민병권 (한국과학기술연구원, 청정에너지 연구센터)
  • Jeon, Hyo Sang (Clean Energy Research Center, Korea Institute of Science and Technology) ;
  • Park, Se Jin (Clean Energy Research Center, Korea Institute of Science and Technology) ;
  • Min, Byoung Koun (Clean Energy Research Center, Korea Institute of Science and Technology)
  • 투고 : 2013.06.24
  • 심사 : 2013.08.31
  • 발행 : 2013.08.31
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Hydrogen production from water using solar energy is attractive way to obtain clean energy resource. Among the various solar-to-hydrogen production techniques, a combination of a photovoltaic and an electrolytic cell is one of the most promising techniques in term of stability and efficiency. In this study, we show successful fabrication of precursor solution processed CIGS thin film solar cells which can generate high voltage. In addition, CIGS thin film solar cell modules producing over 2V of open circuit voltage were fabricated by connecting three single cells in series, which are applicable to water electrolysis. The operating current and voltage during water electrolysis was measured to be 4.23mA and 1.59V, respectively, and solar to hydrogen efficiency was estimated to be 3.9%.

키워드

참고문헌

  1. J. A. Turner, "A Realizable Renewable Energy Future", Science, Vol. 285, 1999, PP. 687-689. https://doi.org/10.1126/science.285.5428.687
  2. J. Nowotny, C. C. Sorrell, L. R. Sheppard and T. Bak, "Solar-hydrogen Environmentally Safe Fuel for The Future", Int. J. Hydrogen. Energy, Vol. 30, 2005, pp. 521-544. https://doi.org/10.1016/j.ijhydene.2004.06.012
  3. T. N. Veziroglu, "Dawn of the hydrogen age", Int. J. Hydrogen. Energy, Vol. 23, 1998, pp. 1007-1078. https://doi.org/10.1016/S0360-5442(98)00039-5
  4. A. Fujishima and K. Honda, "Electrochemical Photolysis of Water at a Semiconductor Electrode", Nature, Vol. 238, 1972, pp. 37-38. https://doi.org/10.1038/238037a0
  5. A. J. Bard, and M. A. Fox, "Artificial Photosynthesis: Solar Splitting of Water to Hydrogen and Oxygen", Acc. Chem. Res, Vol. 28 No. 3, 1995, p. 141-145. https://doi.org/10.1021/ar00051a007
  6. O. Khaselev and J. A. Turner, "A Monolithic Photovoltaic-photoelectrochemical Device for Hydrogen Production via Water Splitting", Sciecne, Vol. 280, 1998, pp. 425-427 https://doi.org/10.1126/science.280.5362.425
  7. T. Bak, J. Nowotny, M. Rekas and C.C. Sorrell, "Photo-electrochemical Properties of the $TiO_2$-Pt system in aqueous solutions", Int. J. Hydrogen. Energy, Vol. 28, 1995, pp.141-145.
  8. P. Jackson, D. Hariskos, E. Lotter, S. Paetel, R. Wuerz, R. Nebber, W. Wischmann and M. Powalla, "New World Record Efficiency for $Cu(In,Ga)Se_2$ Thin-film Solar Cells beyond 20%", Prog. Photovolt: Res. Appl, Vol. 19, 2011, pp. 894-897. https://doi.org/10.1002/pip.1078
  9. C. J. Hibberd, E. Chassaing, W. Lie, D. B. Mitzi, D. Lincont and A. N. Tiwari, "Non-vacuum Methods for Formation of Cu(In,Ga)(Se,S)2 Thin Film Photovoltaic Absorbers", Prog. Photovolt: Res. Appl, Vol. 18, 2010, pp. 434-452. https://doi.org/10.1002/pip.914
  10. S. E. Habas, H. A. S. Platt, M. Hest and D. S. Ginley, "Low-cost Inorganic Solar Cells: From Ink to Printed Device", Chem. Rev, Vol. 110, 2010, pp. 6571-6594. https://doi.org/10.1021/cr100191d
  11. S. J. Park, J. W. Cho, J. K. Lee, K. Shin, J-H, Kim and B. K. Min, "Solution Processed High Bandgap $CuInGaS_2$ Thin Film for Solar Cell Applications", 2013, DOI: 10.1002/pip.2354.
  12. Z. B. Chen, T. F. Jaramillo, T. G. Deutsch, A. Kleiman-Shwarsctein, A. J. Forman, N. Gaillard, R. Garland, K. Takanabe, C. Heske, M. Sunkara, E. W. McFarland, K. Domen, E. L. Miller, J. A. Turner and H. N. J. Dinh, "Accelerating Materials Development for Photoelectrochemical Hydrogen Production: Standards for Methods, Definitions, and Reporting Protocols", Vol. 25, 2010, pp. 3-16. https://doi.org/10.1557/JMR.2010.0020
  13. O. Khaselev, A. Bansal and J. A. Turner, " High-efficiency Integrated Multijunction Photovoltaic/electrolysis System for Hydrogen Production", Vol. 26, 2001, pp. 127-132. https://doi.org/10.1016/S0360-3199(00)00039-2