한국지역사회생활과학회지 (The Korean Journal of Community Living Science)

  • 제24권2호
  • /
  • Pages.243-249
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  • 2013
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  • 1229-8565(pISSN)
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  • 2287-5190(eISSN)
한국지역사회생활과학회 (The Korean Society of Community Living Science)
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전통 칠 유래 성분의 확인

Identification of the Derivated Species from Traditional Coating Films

  • 신정화 (한국기초과학지원연구원 서울센터) ;
  • 안윤경 (한국기초과학지원연구원 서울센터)
  • 투고 : 2013.06.14
  • 심사 : 2013.06.24
  • 발행 : 2013.06.30
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초록

Identification of coating film species from ancient coating materials is needed to maintaine their surfaces without loss of their original beauty for a long time and understand the historical background of manufacturing techniques. A pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) was applied to identify the origine of films in ancient coating materials. The pyrolysis products, which reflect the source from which they originate were detected distinctively at $500^{\circ}C$. This is a rapid technique that does not require large amounts of sample or any sample preparation. Sesquiterpenes are a class of terpenes that consist of three isoprene units were identified as cadienes, selinenes, cubebenes from the raw material of dendropanax morbifera. On the other hand, alkanes(tetra~heptadecanes), alkenes (tri~heptadecenes), allkyphenols, catechols and fatty acids were detected from the raw material of the lacquer film. Based on these results, the origine of historic coatings artifacts was identified using py-GC/MS by comparison with their pyrolysis products.

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참고문헌

  1. Ahn JC, Kim SH, Kim MY, Kim OT, Kim KS, Hwang B(2003) Seasonal Variations in Yields of Hwangchil Lacquer and Major Sesquiterpene Compounds from Selected Superior Individuals of Dendropanax morbifera Ldv. J Plant Biology 46(1), 38-40 https://doi.org/10.1007/BF03030299
  2. Choi SC, Kim SD, Yi YH, Ko SR, Ham SW(2011) Studies on analysis of Joseon lacquer layer. J Conserv Sci 27(4), 371-380
  3. Chung IM, Kim MY, Park SD, Park WH, Moon HI(2009) In vitro evaluation of the antiplasmodial activity of Dendropanax morbifera against chloroquinesensitive strains of Plasmodium falciparum. Phytother Res 23(11), 1634-1637 https://doi.org/10.1002/ptr.2838
  4. Hu J(1980) Conservation and restoration of cultural property: Conservation of far eastern objects. Tokyo, Tokyo National Research Institute of Cultural Property 89-112
  5. Hyun TK, Kim MO, Lee HK, Kim YJ, Kim EK, Kim JS(2013) Evaluation of anti-oxidant and anti-cancer properties of Dendropanax morbifera Leeveille. Food Chemistry 141(3), 1947-1955 https://doi.org/10.1016/j.foodchem.2013.05.021
  6. Jo JS, Kim JI(2001) Durability and properties of coating film on lumbers coated with Hwangchil. Furniture 12(1), 11-20
  7. Kim HJ, Lee BH(2002) Development trends of natural coatings -Rhus lacquer, Dendropanax lacquer and Cashew Nutshell Liquid (CNSL) lacquer. Prospectives Industrial Chem 5(5), 35-43
  8. Kim SC, Lee KH, Kang HT, Shin SP, Han MS(2010) Lacquer Manufacturing Method for the Wooden Coffins of King Muryeong's Tomb based on the Scientific Analysis. Korean J society of conservation science for cultural properties 26(3), 247-258
  9. Kim SH, Jang YS, Han JG, Chung HG, Lee SW, Cho KJ(2006) Genetic variation and population structure of Dendropanax morbifera Lev. Araliaceae in Korea. Silvae Genetica 55(1), 7-13
  10. Kumanotani J(1995) Urushi oriental lacquer - a natural aesthetic durable and future-promising coating. Prog Org Coat 26, 163-195 https://doi.org/10.1016/0300-9440(95)00559-5
  11. Lambert JB, Frye JS, Carriveau GW(1991) The structure of oriental lacquer by solid state nuclear magnetic resonance spectroscopy. Archaeometry 33, 87-93 https://doi.org/10.1111/j.1475-4754.1991.tb00687.x
  12. Lee BH, Kim HJ(2004) Curing behaviors of Korean Dendropanax Lacquer determined by chemical and physical measures. J Appl Polymer Sci 92, 625-630 https://doi.org/10.1002/app.20094
  13. Lee KW(2009) The study regarding formative characteristics of a Chosun Dynasty Lacquer ware inlaid with mother of pearl pattern. Korean Soc Basic Design Art 10(2), 311-318
  14. Niimura N, Miyakoshi T(2003) Characterization of Natural Resin Films and Identification of Ancient Coating. Jpn J Mass Spectrom Soc 51(4), 439-457 https://doi.org/10.5702/massspec.51.439
  15. Niimura N, Miyakoshi T, Onodera J, Higuchi T(1996) Characterization of Rhus vernicifera and Rhus succedanea lacquer films and their pyrolysis mechanisms studied using two-stage pyrolysis-gas chromatography/mass spectrometry. J Anal Appl Pyrolysis 37, 199-209 https://doi.org/10.1016/0165-2370(96)00945-X

피인용 문헌

  1. 인천 옹진군 영흥도선 출수 도기병의 보존처리와 내용물 분석 vol.32, pp.4, 2013, https://doi.org/10.12654/jcs.2016.32.4.01
  2. Py-GC/MS 분석법을 이용한 첨가물 혼합 옻칠 접착제의 정성분석 vol.33, pp.1, 2013, https://doi.org/10.12654/jcs.2017.33.1.07