Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Identification of Coffee Fragrances Using Needle Trap Device-Gas Chromatograph/Mass Spectrometry (NTD-GC/MS)

  • Eom, In-Yong (Department of Life Chemistry, College of Natural Science, Catholic University of Daegu) ;
  • Jung, Min-Ji (Department of Life Chemistry, College of Natural Science, Catholic University of Daegu)
  • Received : 2013.02.07
  • Accepted : 2013.03.14
  • Published : 2013.06.20
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Abstract

A fast and simple sampling and sample preparation device, (NTD) has been developed and applied to sample and analyze volatile components from ground coffee beans. Coffee fragrances and other volatile organic compounds (VOCs) were sampled by the NTD and then analyzed by gas chromatograph-mass spectrometry (GC/MS). Divinylbenzene (DVB) particles (80/100 mesh size) were the sorbent bed of the NTD. More than 150 volatile components were first identified based on the database of the mass library and then finally 30 fragrances including caffeine were further confirmed by comparing experimental retention indices (i.e. Kovat index) with literature retention indices. Total sampling time was 10 minutes and no extra solvent extraction and/or reconstitution step need. Straight n-alkanes (C6-C20) were used as retention index probes for the calculation of experimental retention indices. In addition, this report suggests that an empty needle can be an alternative platform for analyzing polymers by pyrolysis-GC/MS.

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References

  1. Kim, K.-H.; Jahan, S. A.; Kabir, E. TrAC 2012, 33, 1.
  2. http://www.cctfa.ca/scented/policy_workplace_scents.html
  3. http://www.national-toxic-encephalopathy-foundation.org/epafragban.pdf
  4. Zachariadis, G. A.; Rosenberg, E. J. Sep. Sci. 2012, 35, 1132. https://doi.org/10.1002/jssc.201101041
  5. Arthur, C. L.; Pawliszyn, J. Anal. Chem. 1990, 62, 2145. https://doi.org/10.1021/ac00218a019
  6. McComb, M. E.; Oleschuk, R. D.; Giller, E.; Gesser, H. D. Talanta 1997, 44, 2137. https://doi.org/10.1016/S0039-9140(97)00093-3
  7. Eom, I.-Y.; Risticevic, S.; Pawliszyn, J. Anal. Chimi. Acta 2012, 716, 2. https://doi.org/10.1016/j.aca.2011.06.010
  8. David, F.; Sandra, P. J Chromatogr. A 2007, 1152, 54. https://doi.org/10.1016/j.chroma.2007.01.032
  9. Eom, I.-Y. Bull. Korean Chem. Soc. 2011, 32, 1463. https://doi.org/10.5012/bkcs.2011.32.5.1463
  10. Harper, M. J. Chromatogr. A 2000, 885, 129. https://doi.org/10.1016/S0021-9673(00)00363-0
  11. Eom, I.-Y.; Tugulea, A.-M.; Pawliszyn J. J. Chromatogr. A 2008, 1196-1197, 3. https://doi.org/10.1016/j.chroma.2008.02.090
  12. Eom, I.-Y.; Niri, V. H.; Pawliszyn, J. J. Chromatogr. A 2008, 1196-1197, 10. https://doi.org/10.1016/j.chroma.2008.03.036
  13. Eom, I.-Y.; Pawliszyn, J. J. Sep. Sci. 2008, 31, 2283. https://doi.org/10.1002/jssc.200800024
  14. Gong, Y.; Eom, I.-Y.; Da-Wei Lou, D.-W.; Hein, D.; Pawliszyn, J. Anal. Chem. 2008, 80, 7275. https://doi.org/10.1021/ac800884f
  15. Heidari, M.; Bahrami, A.; Ghiasvand, A.; Shahna, F. G.; Soltanian, A. R. Talanta 2012, 101, 314. https://doi.org/10.1016/j.talanta.2012.09.032
  16. Lord, H. L.; Zhan, W.; Pawliszyn, J. Anal. Chimi. Acta 2010, 677, 3. https://doi.org/10.1016/j.aca.2010.06.020
  17. Risticevic, S.; Carasekb, E.; Pawliszyn, J. J. Anal. Chimi. Acta 2008, 617, 72. https://doi.org/10.1016/j.aca.2008.04.009
  18. Liu, F.; Liang, Y.; Cao, C.; Zhou, N. J. Anal. Chimi. Acta 2007, 594, 279. https://doi.org/10.1016/j.aca.2007.05.023
  19. Scholze, B.; Meier, D. J. Anal. & Applied Pyrolysis 2001, 60, 41. https://doi.org/10.1016/S0165-2370(00)00110-8

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