한국의류학회지 (Journal of the Korean Society of Clothing and Textiles)

  • 제37권3호
  • /
  • Pages.413-423
  • /
  • 2013
  • /
  • 1225-1151(pISSN)
  • /
  • 2234-0793(eISSN)
한국의류학회 (The Korean Society of Clothing and Textiles)
권호 표지
DOI QR코드

DOI QR Code

시금치와 마테 분말을 이용한 클로로필 추출과 직물 염색

Extractions of Chlorophyll from Spinach and Mate Powders and Their Dyeability on Fabrics

  • 유혜자 (서원대학교 의류학과) ;
  • 안춘순 (인천대학교 패션산업학과) ;
  • Yoo, Hye Ja (Dept. of Clothing & Textiles, Seowon University) ;
  • Ahn, Cheunsoon (Dept. of Fashion Industry, Incheon National University) ;
  • Narantuya, Lkhagva (Dept. of Fashion Industry, Incheon National University)
  • 투고 : 2013.01.17
  • 심사 : 2013.03.08
  • 발행 : 2013.04.30
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Chlorophyll is an abundant pigment found in all green plants, algae, and cyanobacteria. This study uses methanol, acetone and water to extract spinach and mate powders in order to examine the possibility of dyeing animal fibers with chlorophyll without chemical alteration. It was shown that methanol extracts of spinach and mate powders can be effectively used to dye wool and silk fabrics if the extract is mixed with water by methanol:water 65:35 v/v. Compared to methanol extract, the acetone extract showed lower chlorophyll yield and lower dye uptake. Water was not an appropriate solvent for chlorophyll extraction and dyeing. Spinach powder showed a higher dye uptake than mate powder due to the higher chlorophyll content than mate powder. It is possible that the chlorophyll dyeing of wool and silk fabrics is due to the hydrogen bonding between the hydroxy amino acids in fiber and the carbonyl groups of chlorophyll. These carbonyl groups are on the heterocyclic ring and the methyl and ethyl side chains of chlorophyll.

키워드

참고문헌

  1. Arnon, D. I. (1949). Copper enzymes in isolated chloroplasts. Polyphenoloxidase in Beta vulgaris. Plant Physiology, 24 (1), 1-15. https://doi.org/10.1104/pp.24.1.1
  2. Berezin, B. D., Berezin, M. B., Moryganov, A. P., Rumyantseva, S. V., & Dymnikova, N. S. (2003). Chlorophyll and its derivatives, chlorins and porphyrins, as a promising class of environmentally friendly dyes. Russian Journal of Applied Chemistry, 76(12), 1958-1961. https://doi.org/10.1023/B:RJAC.0000022447.81026.1a
  3. Burris, K. P., Harte, F. M., Davidson, P. M., Stewart, C. N. Jr., & Zivanovic, S. (2012). Composition and bioactive properties of yerba mate (Ilex paraguariensis A. St.-Hil.): A review. Chilean Journal of Agricultural Research, 72(2), 268-274. https://doi.org/10.4067/S0718-58392012000200016
  4. Brix, H. (2009, March 2). Chlorophylls and carotenoids in plant material. Institut for Bioscience. Retrieved November 27, 2012, from http://bios.au.dk/fileadmin/www.biology. au.dk/Plantebiologi/Plants_Chl_a_b_carotenoids_ethanol_ UK_20090302.pdf
  5. Braun, P., Vegh, A. P., von Jan, M., Strohmann, B., Hunter, C. N., Robert, B., & Scheer, H. (2003). Identification of intramembrane hydrogen bonding between $13^{1}$ keto group of bacteriochlorophyll and serine residue $\alpha$27 in the LH2 light-harvesting complex. Biochimica et Biophysica Acta, 1607(1), 19-26. https://doi.org/10.1016/j.bbabio.2003.08.004
  6. Eremin, V. V. (2009-2011). Glossary of nanotechnology and related terms. RUSNANO. Retrieved December 31, 2012, from http://eng.thesaurus.rusnano.com/wiki/article1955
  7. Erge, H. S., Karadeniz, F., Koca, N., & Soyer, Y. (2008). Effect of heat treatment on chlorophyll degradation and color loss in green peas. GIDA, 33(5), 225-233.
  8. Fukusumi, T., Matsuda, K., Mizoguchi, T., Miyatake, T., Ito, S., Ikeda, T., Tamiaki, H., & Oba, T. (2012). Non-enzymatic conversion of chlorophyll-a into chlorophyll-d in vitro: A model oxidation pathway for chlorophyll-d biosynthesis. FEBS Letters, 586(16), 2338-2341. https://doi.org/10.1016/j.febslet.2012.05.036
  9. Garski, P. (2012, February 27). Nutrition facts and chemical composition of yerba mate: Caffeine, antioxidants, minerals and other. YerbaMateInfo.com. Retrieved December 7, 2012, from http://www.yerbamateinfo.com/nutrition-factsactive- ingredients-caffeine.html
  10. Heck, C. I., & de Mejia, E. G. (2007). Yerba Mate Tea (Ilex paraguariensis): A comprehensive review on chemistry, health implications, and technological considerations. Journal of Food Science, 72(9), R138-R151. https://doi.org/10.1111/j.1750-3841.2007.00535.x
  11. Henry, B. S. (1996). Natural food colours. In G. A. F. Hendry & J. D. Houghton (Eds.), Natural food colorants (pp. 40-79). Glasgow: Blackie Academic & Professional.
  12. Holm-Hansen, O., & Riemann, B. (1978). Chlorophyll a determination: Improvements in methodology. Oikos, 30(3), 438- 447. https://doi.org/10.2307/3543338
  13. Hou, X., Yang, R., Xu H., & Yang, Y. (2012). Adsorption kinetic and thermodynamic studies of silk dyed with sodium copper chlorophyllin. Industrial & Engineering Chemistry Research, 51(25), 8341-8347. https://doi.org/10.1021/ie300201j
  14. Inglesby, M. K., & Zeronian, S. H. (2001). Diffusion coefficients for direct dyes in aqueous and polar aprotic solvents by the NMR pulsed-field gradient technique. Dyes and Pigments, 50(1), 3-11. https://doi.org/10.1016/S0143-7208(01)00035-3
  15. Institute of Molecular Development LLC. (2001). Physical properties of solvents. Molecular Techniques and Methods. Retrieved October 5, 2012, from http://www.molecularinfo. com/MTM/D/D4/D4-1.html
  16. Iqbal, S. A., & Mido, Y. (2005). Food chemistry. New Delhi: Discovery Publishing House.
  17. Kanazawa, H., & Yashima, Y. (1991). Temperature effect on the dyeing of cotton fabrics with reactive dyes. 福島大學理科報告, 47, 9-18. Retrieved January 3, 2013, from http://ir. lib.fukushima-u.ac.jp/dspace/bitstream/10270/1537/1/8-308. pdf
  18. Kidmose, U., Edelenbos, M., Christensen, L. P., & Hegelund, E. (2005). Chromatographic determination of changes in pigments in spinach (Spinacia oleracea L.) during processing. Journal of Chromatographic Science, 43(9), 466- 472. https://doi.org/10.1093/chromsci/43.9.466
  19. Kim, D. Y., Chung, Y. M., Eun, J. B., & Park, K. H. (1991). Effect of different shading condition on the chlorophyll pigment in tea shoots. Agricultural Science & Technology Review, 26, 25-28.
  20. Lee, L. S., Park, J. D., Cha, H. S., Lee, Y. M., Park, J. W., & Kim, S. H. (2010). Physicochemical properties of powdered green teas in Korea. Korean Journal of Food Science and Technology, 42(1), 33-38.
  21. Lichtenthaler, H. K., & Buschmann, C. (2001). Chlorophylls and carotenoids: Measurement and characterization by UVVis spectroscopy. In R. E. Wrolstad, T. E. Acree, E. A. Decker, M. H. Penner, D. S. Reid, S. J. Schwartz, C. F. Shoemaker, D. M. Smith, & P. Sporns (Eds.), Current protocols in food analytical chemistry (pp. F4.3.1-F4. 3.8). New Jersey: John Wiley & Sons, Inc.
  22. Lorenzen, C. J. (1966). A method for the continuous measurement of the in vivo chlorophyll concentration. Deep Sea Research, 13(2), 223-227.
  23. Mattila, P., & Hellstrom, J. (2007). Phenolic acids in potatoes, vegetables, and some of their products. Journal of Food Composition and Analysis, 20(3-4), 152-160. https://doi.org/10.1016/j.jfca.2006.05.007
  24. May, P. (2012-2013). Chlorophyll. University of Bristol. Retrieved January 1, 2013, from http://www.chm.bris.ac.uk/ motm/chlorophyll/chlorophyll_h.htm
  25. Murov, S. (2012, April 5). Properties of organic solvents. Homepage of Dr. Steven L. Murov. Retrieved November 24, 2012, from http://murov.info/orgsolvents.htm
  26. Pinto, A. M. F., Von Sperling, E., & Moreira, R. M. (2001). Chlorophyll-a determination via continuous measurement of plankton fluorescence: methodology development. Water Research, 35(16), 3977-3981. https://doi.org/10.1016/S0043-1354(01)00102-6
  27. Porra, R. J. (2002). The chequered history of the development and use of simultaneous equation for the accurate determination of chlorophylls a and b. Photosynthesis Research, 73(1-3), 149-156. https://doi.org/10.1023/A:1020470224740
  28. Sartory, D. P., & Grobbelaar, J. U. (1984). Extraction of chlorophyll a from freshwater phytoplankton for spectrophotometric analysis. Hydrobiologia, 114(3), 177-187. https://doi.org/10.1007/BF00031869
  29. Schmalko, M. E., & Alzamora, S. M. (2001). Color, chlorophyll, caffeine, and water content variation during yerba maté processing. Drying Technology: An International Journal, 19(3-4), 599-610. https://doi.org/10.1081/DRT-100103937
  30. Shipman, L. L., Janson, T. R., Ray, G. J., & Katz, J. J. (1975). Donor properties of the three carbonyl groups of chlorophyll a:ab initio calculations and $^{13}C$ magnetic resonance studies. Proceedings of the National Academy of Science of the United States of America, 72(8), 2873-2876. https://doi.org/10.1073/pnas.72.8.2873
  31. Sims, D. A., & Gamon, J. A. (2002). Relationships between leaf pigment content and spectral reflectance across a wide range of species, leaf structures and developmental Stages. Remote Sensing of Environment, 81(2-3), 337-354. https://doi.org/10.1016/S0034-4257(02)00010-X
  32. Song, K. H., Yoo, H. J., Lee, H. J., Kim, J. H., Rhie, J. S., Ahn, C. S., & Han Y. S. (2009). 의류재료학 [Textiles]. Seoul: Hyungseul Publishing Co.
  33. Ulatowska-Jarza, A., Bindig, U., Podbielska, H., Holowacz, I., Strek, W., Muller, G., & Eichler, H. J. (2005). Spectroscopic properties of a chlorophyll-based photosensitive dye entrapped in sol-gel fibre-optic applicators. Materials Science- Poland, 23(1), 111-122.
  34. Vernet, M., & Lorenzen, C. J. (1987). The presence of chlorophyll b and the estimation of phaeopigments in marine phytoplankton. Journal of Plankton Research, 9(2), 255- 265. https://doi.org/10.1093/plankt/9.2.255
  35. Wikipedia. (2012a, December 14). Chlorophyll. Wikipedia, the free encyclopedia. Retrieved December 29, 2012, from http://en.wikipedia.org/wiki/Chlorophyll
  36. Wikipedia. (2012b, December 5). Chlorophyllin. Wikipedia, the free encyclopedia. Retrieved January 1, 2013, from http:// en.wikipedia.org/wiki/Chlorophyllin
  37. Wikipedia. (2012c, December 16). Photosynthetic pigment. Wikipedia, the free encyclopedia. Retrieved December 31, 2012, from http://en.wikipedia.org/wiki/Photosynthetic_pigment
  38. Zvezdina, S. V., Berezin, M. B., & Berezin, B. D. (2010). Natural dyes based on chlorophyll and protoporphyrin derivatives. Russian Journal of Coordination Chemistry, 36 (9), 711-714. https://doi.org/10.1134/S1070328410090125

피인용 문헌

  1. A Study on the Dyeability of Urtica Dioica L. Extract vol.20, pp.4, 2016, https://doi.org/10.12940/jfb.2016.20.4.128
  2. Study on the Improvement of Dyeability of Commercial Indigo Leaf Powder for the Purpose of Utilizing It in Indigo Dyeing vol.38, pp.4, 2014, https://doi.org/10.5850/JKSCT.2014.38.4.540
  3. The Dyeing Properties and Functionality of Water Lily(Nymphaea tetragona) Leaves Extract as a New Natural Dye Resource(1): Dyeing of Cotton Fiber vol.28, pp.4, 2016, https://doi.org/10.5764/TCF.2016.28.4.290