Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis and Characterization of Zn(1-x)NixAl2O4 Spinels as a New Heterogeneous Catalyst of Biginelli's Reaction

  • Akika, Fatima-Zohra (Departement de Chimie, Faculte des Sciences Exactes et Informatique, Universite de Jijel) ;
  • Kihal, Nadjib (Departement de Chimie, Faculte des Sciences Exactes et Informatique, Universite de Jijel) ;
  • Habila, Tahir (Departement de Chimie, Faculte des Sciences Exactes et Informatique, Universite de Jijel) ;
  • Avramova, Ivalina (Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences) ;
  • Suzer, Sefik (Department of Chemistry, Bilkent University) ;
  • Pirotte, Bernard (Laboratoire de chimie pharmaceutique, CHU Tour 4, B36, Universite de liege) ;
  • Khelili, Smail (Departement de Chimie, Faculte des Sciences Exactes et Informatique, Universite de Jijel)
  • Received : 2012.11.30
  • Accepted : 2013.02.14
  • Published : 2013.05.20
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Abstract

$Zn_{(1-x)}Ni_xAl_2O_4$ (x = 0.0-1.0) spinels were prepared at $800^{\circ}C$ by co-precipitation method and characterized by infrared spectroscopy, X-ray diffraction, scanning electron microscopy and X-ray photoelectron spectroscopy. The specific surface area was determined by BET. SEM image showed nano sized spherical particles. XPS confirmed the valence states of the metals, showing moderate Lewis character for the surface of materials. The powders were successfully used as new heterogeneous catalysts of Biginelli's reaction, a one-pot three-component reaction, leading to some dihydropyrimidinones (DHPMs). These new catalysts that produced good yields of DHPMs, were easily recovered by simple filtration and subsequently reused with persistent activity, and they are non-toxic and environmentally friendly. The optimum amount of catalyst is 20% by weight of benzaldehyde derivatives, while the doping amount has been found optimal for x = 0.1.

Keywords

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