Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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A Carbazole-Attached NO2S2-Macrocycle Exhibiting Hg2+ and Cu2+ Selectivity

  • Lee, Seul-Gi (Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University) ;
  • Kang, Eun-Ju (Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University) ;
  • Lee, Shim Sung (Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University)
  • Received : 2013.02.04
  • Accepted : 2013.02.13
  • Published : 2013.05.20
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Abstract

A synthesis and cation-induced fluorescent behavior of the carbazole-attached $NO_2S_2$-macrocycle (L) is described and structurally characterized by single crystal X-ray analysis. The photoluminescence spectrum of L in 80% $CH_3CN/CH_2Cl_2$ displays a peak maximum at 431 nm (blue emission). In the metal-induced fluorometric experiment, L showed a drastic chelation-enhanced fluorescence quenching (CHEQ) effect only with $Hg^{2+}$ and $Cu^{2+}$. In ESI-mass study, a 1:1 stoichiometry for complexation of L with $Hg^{2+}$ was confirmed, suggesting the unique sensing behavior of the proposed ligand L due to the selective complexation affinity for $Hg^{2+}$. The observed results indicate that L is a promising turn-off type fluoroionophore for $Hg^{2+}$ and $Cu^{2+}$ detections. Additionally, the $Ag^+$ complex of the precursor macrocycle was prepared and its solid structure was crystallographically characterized.

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