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모사 디젤 화학반응 메커니즘의 각 성분이 화학적 점화 지연 시간에 미치는 영향에 관한 기초 연구

Fundamental Study on the Chemical Ignition Delay Time of Diesel Surrogate Components

  • 김규진 (서울대학교 기계항공공학부) ;
  • 이상열 (서울대학교 협동과정 자동차공학과) ;
  • 민경덕 (서울대학교 기계항공공학부)
  • Kim, Gyujin (Department of Mechanical and Aerospace, Seoul National University) ;
  • Lee, Sangyul (Interdisciplinary Program in Automotive Engineering, Seoul National University) ;
  • Min, Kyoungdoug (Department of Mechanical and Aerospace, Seoul National University)
  • 투고 : 2012.06.21
  • 심사 : 2012.08.28
  • 발행 : 2013.05.01

초록

Due to its accuracy and efficiency, reduced kinetic mechanism of diesel surrogate is widely used as fuel model when applying 3-D diesel engine simulation. But for the well-developed prediction of diesel surrogate reduced kinetic mechanism, it is important to know some meaningful factors which affect to ignition delay time. Meanwhile, ignition delay time consists of two parts. One is the chemical ignition delay time related with the chemical reaction, and the other is the physical ignition delay time which is affected by physical behavior of the fuel droplet. Especially for chemical ignition delay time, chemical properties of each fuel were studied for a long time, but researches on their mixtures have not been done widely. So it is necessary to understand the chemical characteristics of their mixtures for more precise and detailed modeling of surrogate diesel oil. And it shows same ignition trend of paraffin mixture with those of single component, and shorter ignition delay at low/high initial temperature when mixing paraffin and toluene.

키워드

참고문헌

  1. W. J. Pitz and C. J. Mueller, "Recent Progress in the Development of Diesel Surrogate Fuels," Progress in Energy and Combustion Science, Vol.37, Issue 3, pp.330-350, 2011. https://doi.org/10.1016/j.pecs.2010.06.004
  2. U. B. Azimov and K. S. Kim, "Large-eddy Simulation of Air Entrainment during Diesel Spray Combustion with Multi-dimensional CFD," Int. J. Automotive Technology, Vol.12, No.6, pp.795-812, 2011. https://doi.org/10.1007/s12239-011-0092-y
  3. U. B. Azimov, K. S. Kim, D. S. Jeong and Y. G. Lee, "Evaluation of Low-temperature Diesel Combustion Regimes with n-Heptane Fuel in a Constant-volume Chamber," Int. J. Automotive Technology, Vol.10, No.3, pp.265-276, 2009. https://doi.org/10.1007/s12239-009-0031-3
  4. S. Lee, K. Min and J. Chung, "The Effects of Injection Timing and Piston Bowl Shape on PHCCI Combustion with Split Injections," SAE 2010-01-0359, 2010.
  5. V. P. Zhukov, V. A. Sechenov and A. Yu. Starikovskii, "Autoignition of n-Decane at High Pressure," Combustion and Flame, Vol.153, Issues 1-2, pp.130-136, 2008. https://doi.org/10.1016/j.combustflame.2007.09.006
  6. K. Narayanaswamy, G. Blanquart and H. Pitsch, "A Consistent Chemical Mechanism for Oxidation of Substituted Aromatic Species," Combustion and Flame, Vol.157, Issue 10, pp.1879-1898, 2010. https://doi.org/10.1016/j.combustflame.2010.07.009
  7. M. Hartmann, I. Gushterova, M. Fikri, C. Schulz, R. Schiessl and U. Maas, "Auto-ignition of Toluene Doped n-Heptane and Iso-octane/air Mixtures: High-pressure Shock-tube Experiments and Kinetic Modeling," Combustion and Flame, Vol.158, Issue 1, pp.172-178, 2011. https://doi.org/10.1016/j.combustflame.2010.08.005
  8. Y. Kim, A Study on the CAI Combustion Characteristics Using a Reduced Chemical Kinetic Mechanism, Ph. D. Dissertation, Seoul National University, Seoul, 2007.
  9. K. Lee, Y. Kim and K. Min, "Development of a Reduced Chemical Kinetic Mechanism for a Gasoline Surrogate for Gasoline HCCI Combustion," Combustion Theory and Modelling, Vol.15, No.1, pp.107-124, 2011.
  10. S. Lee, G. Kim and K. Min, "Development of Reduced Normal Dodecane Chemical Kinetics," SAE 120120017, 2012.
  11. J. B. Heywood, Internal Combustion Engine Fundamentals, McGraw-Hill, New York, pp.539-540, 1988.
  12. S. National Laboratories, CHEMKIN-IV: A Fortran Chemical Kinetics Package for the Analysis of Gas-phase Chemical and Plasma Kinetics, 1994.
  13. S. S. Vasu, D. F. Davidson, Z. Hong, V. Vasudevan and R. K. Hanson, "n-Dodecane Oxidation at High Pressures: Measurements of Ignition Delay Times and OH Concentration Time Histories," Proc. Combust. Inst, Vol.32, pp.173-180, 2009. https://doi.org/10.1016/j.proci.2008.05.006
  14. Y. Briker, Z. Ring, A. Iacchelli, N. Mclean, P. M. Rahimi and C. Fairbrige, "Diesel Fuel Analysis by GC-FIMS: Aromatics, n-Paraffins and Isoparaffins," Energy and Fuels, Vol.15, pp.23-37, 2001. https://doi.org/10.1021/ef000106f