Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis and Characterization of 1-D BiSI and 2-D BiOI Nanostructures

  • Lee, Juheon (Department of Chemistry, Yeungnam University) ;
  • Min, Bong-Ki (Center for Research Facilities, Yeungnam University) ;
  • Cho, Insu (Department of Chemistry, Yeungnam University) ;
  • Sohn, Youngku (Department of Chemistry, Yeungnam University)
  • Received : 2012.10.09
  • Accepted : 2012.12.08
  • Published : 2013.03.20
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Abstract

We have prepared 1-D BiSI and 2-D BiOI nanostructures, and characterized them by scanning electron microscopy, transmission electron microscopy (TEM), X-ray diffraction crystallography, thermogravimetric analysis/differential scanning calorimetry, and UV-visible absorption. Here, we first report clear HR-TEM image of BiSI. In addition, we first found that the growth direction of BiSI is [12-1] plane, with the neighboring distance of 0.30 nm. The crystal structures of BiSI and BiOI are found to be orthorhombic (Pnam) and tetragonal (P4/nmm), respectively. The absorption band gaps of BiSI and BiOI are measured to be 1.55 and 1.92 eV, respectively. Our study could further highlight the applications of V-VI-VII compounds.

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