Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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The Bonding Nature and Low-Dimensional Magnetic Properties of Layered Mixed Cu(II)-Ni(II) Hydroxy Double Salts

  • Park, Seong-Hun (Department of Chemistry, Faculty of Liberal Art and Teacher Education, University of Seoul) ;
  • Huh, Young-Duk (Department of Chemistry, Institute of Nanosensor and Biotechnology, Dankook University)
  • Received : 2012.10.26
  • Accepted : 2012.12.04
  • Published : 2013.03.20
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Abstract

Layered mixed metal hydroxy double salts (HDS) with the formulas $(Cu_{0.75}Ni_{0.25})_2(OH)_3NO_3$ ((Cu, Ni)-HDS) and $Cu_2(OH)_3NO_3$ ((Cu, Cu)-HDS) were prepared via slow hydrolysis reactions of CuO with $Ni(NO_3)_2$ and $Cu(NO_3)_2$, respectively. The crystal structures, morphologies, bonding natures, and magnetic properties of (Cu, Ni)-HDS and (Cu, Cu)-HDS were characterized with X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transformation infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and a superconducting quantum interference device (SQUID). Even though (Cu, Ni)-HDS has a similar layered structure to that of (Cu, Cu)-HDS, the bonding nature of (Cu, Ni)-HDS is slightly different from that of (Cu, Cu)-HDS. Therefore, the magnetic properties of (Cu, Ni)-HDS are significantly different from those of (Cu, Cu)-HDS. The origin of the abnormal magnetic properties of (Cu, Ni)-HDS can be explained in terms of the bonding natures of the interlayer and intralayer structures.

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References

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