Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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BNBTS More than Brominating Agent: Green and One-pot Route for the C-N Bond Formation in Water from Alkenes

  • Kazemi, Foad (Department of Chemistry, Institute of Advanced Studies in Basic Sciences(IASBS)) ;
  • Kakroudi, Mazaher Abdollahi (Department of Chemistry, Institute of Advanced Studies in Basic Sciences(IASBS))
  • Received : 2012.10.27
  • Accepted : 2012.11.19
  • Published : 2013.02.20
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Abstract

In this paper, in addition to introducing efficient method for bromohydrin and bromoether preparation, simple, green and efficient method to C-N bond formation from alkene and N,N'-Dibromo-N,N'-1,2-ethanediyl-bis(p-toluenesulfonamide) [BNBTS] in water was investigated. The reaction between alkenes, ${\beta}$-cyclodexterin, and BNBTS took place in water afterward, by making media basic; it will give the corresponding valuable building blocks in good yields (45-79%).

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References

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