Advances in environmental research

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High capacity polymer for nickel determination in environmental samples

  • Received : 2013.01.11
  • Accepted : 2013.12.21
  • Published : 2013.12.25
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Abstract

High AA new high capacity sorbent for preconcentration and determination of nickel in environmental samples was synthesized. The sorbent was synthesized by copolymerization of allyl glaycidyl ether / imminodiacetic acid with N,N-dimethylacrylamide as functional monomers in the presence of N,N-bismethylenacryl amid as cross linker and characterized by Fourier transform infra red spectroscopy, elemental analysis, thermogravimetric analysis and scanning electron microscopy. A recovery of 93.6% was obtained for the metal ion with 0.1 M, sulfuric acid as the eluting agent. The sorption capacity of the functionalized sorbent was 55.9 $mgg^{-1}$. The equilibrium sorption data of Ni(II) on polymeric sorbent were analyzed using Langmuir, Freundlich, Temkin and Redlich.Peterson models. Based on equilibrium adsorption data the Langmuir, Freundlich and Temkin constants were determined 0.87 (L mg-1), 25.87 ($mgg^{-1}$) $(Lmg^{-1})^{1/n}$ and 171.4 ($Jmol^{-1}$) respectively at pH 4.5 and $20^{\circ}C$.

Keywords

References

  1. Ahmad Panahi, H., Mehmandost, N., Moniri, E. and Galaev, I.Y. (2012), "Iminodiacetic acid-containing polymer brushes grafted onto silica gel for preconcentration and determination of copper(II) in environmental samples", J. Appl. Polym. Sci., 126(2), 480-487. https://doi.org/10.1002/app.36802
  2. Ahmad Panahi, H., Nikpour Nezhati, M., Abedini Kashkoieh, R., Moniri, E. and Galaev, I.Y. (2012), "A siliceous support grafted with poly [1-(N,N-bis-carboxymethyl)amino-3-allylglycerol-codimethylacrylamide] brushes for removal of nickel from environmental samples", Toxicol. Environ. Chem., 94(5), 860-866. https://doi.org/10.1080/02772248.2012.684689
  3. Ahmad Panahi, H., Mehrdad Sharif, A.A., Bigonah, M. and Moniri, E. (2010), "Determination and Preconcentration of Nickel in Water with Flame Atomic Absorption Spectrometry by Thioureaformaldehhyde as Chelating Resin", Arab. J. Sci. Eng., 35(2A), 149-154.
  4. Ahmad Panahi, H., Sid Kalal, H., Moniri, E., Nikpour Nezhati, M., Taheri Mendarjani, M. and Ranjbar Kelahrody, S. (2010), "Amberlite XAD-4 functionalized with m-phenylendiamine: Synthesis, characterization and applications as extractant for preconcentration and determination of rhodium (III) in water samples by Inductive Couple Plasma Atomic Emission Spectroscopy (ICP-AES)", Microchem. J., 93(1), 49-54.
  5. Ahmad Panahi, H., Morshedian, J., Mehmandost, N., Moniri, E. and Galaev, I.Y. (2010), "Grafting of poly[1-(N,N-bis-carboxymethyl)amino-3-allylglycerol-co-dimethylacrylamide] copolymer onto siliceous support for preconcentration and determination of lead (II) in human plasma and environmental samples", J. Chromatogr. A, 1217(32), 5165-5172. https://doi.org/10.1016/j.chroma.2010.06.012
  6. Atanassova, D., Stefanova, V. and Russeva, E. (1998), "Co-precipitative pre-concentration with sodium diethyldithiocarbamate and ICP-AES determination of Se, Cu, Pb, Zn, Fe, Co, Ni, Mn, Cr and Cd in water", Talanta, 47(5), 1237-1243. https://doi.org/10.1016/S0039-9140(98)00211-2
  7. Carasek, E. (2000), "A low-cost flame atomic absorption spectrometry method for determination of trace metals in aqueous samples", Talanta, 51(1), 173-178. https://doi.org/10.1016/S0039-9140(99)00274-X
  8. Cespon-Romero, R.M., Yebra-Biurrun, M.C. and Bermejo-Barrera, M.P. (1996), "Preconcentration and speciation of chromium by the determination of total chromium and chromium(III) in natural waters by flame atomic absorption spectrometry with a chelating ion-exchange flow injection system", Anal. Chim. Acta, 327(1), 37-45. https://doi.org/10.1016/0003-2670(96)00062-1
  9. Cuesta, A., Todoli, J.L. and Canals, A. (1996), "Flow injection method for the rapid determination of chemical oxygen demand based on microwave digestion and chromium speciation in flame atomic absorption spectrometry", Spectrochim. Acta, Part B, 51(14), 1791-1798. https://doi.org/10.1016/S0584-8547(96)01527-3
  10. Frendlich, H.M.A. (1906), "Uber die Adsorption in Losungen", J. Phys. Chem., 57, 385-470.
  11. Gordeeva, V.P., Statkus, M.A., Sorokina, N.M., Tsizin, G.I. and Zolotov, Y.A. (2002), "X-ray fluorescence determination of heavy metals in solutions after the preconcentration of their pyrrolidinedithiocarbamate complexes on cellulose filters", J. Anal. Chem., 57(8), 701-707. https://doi.org/10.1023/A:1016821808978
  12. Hall, K.L., Eagleton, L.C., Acrivos, A. and Vermeulen, T. (1966), "Pore- and Solid-Diffusion Kinetics in Fixed-Bed Adsorption under Constant-Pattern Conditions", Ind. Eng. Chem. Fundam., 5(2), 212-223. https://doi.org/10.1021/i160018a011
  13. Ho, Y.S. and Ofomaja, A.E. (2006), "Biosorption thermodynamics of cadmium on coconut copra meal as biosorbent", Biochem. Eng. J., 30(2), 117-123. https://doi.org/10.1016/j.bej.2006.02.012
  14. Holynska, B., Ostachwicz, B. and Wegrzynek, D. (1996), "Simple method of determination of copper, mercury and lead in potable water with preliminary pre-concentration by total reflection X-ray fluorescence spectrometry", Spectrochim. Acta, Part B, 51(1), 769-773. https://doi.org/10.1016/0584-8547(96)01470-X
  15. Kagaya, S., Saiki, M., Malek, Z.A., Araki, Y. and Hasegawa, K. (2001), "Coprecipitation Using Lanthanum Phosphate as a Separation and Preconcentration Technique for Iron(III) and Lead", Fresenius' J. Anal. Chem., 371(3), 391-397. https://doi.org/10.1007/s002160100976
  16. Kara, D. and Alkan, M. (2001), "Selective preconcentration, separation and speciation of ferric iron in different samples using N,N′-bis(2-hydroxy-5-bromo-benzyl)1,2 diaminopropane", Talanta, 55(2),415-422. https://doi.org/10.1016/S0039-9140(01)00443-X
  17. Kojima, I. and Katsuzaki, M. (1997), "Selective extraction and "One-Drop" flame atomic absorption spectrometric determination of silver in biological standard reference materials", Anal. Sci., 13(6), 1021-1027. https://doi.org/10.2116/analsci.13.1021
  18. Kristiansen, J., Christensen, J.M., Henriksen, T., Nielsen, N.H. and Menne, T. (2000), "Determination of nickel in fingernails and forearm skin (stratum corneum)", Anal. Chim. Acta, 403(1-2), 265-273. https://doi.org/10.1016/S0003-2670(99)00568-1
  19. Langmuir, I. (1918), "The adsorption of gases on plane surfaces of glass, mica and platimun", J. Am. Chem. Soc., 40(9), 1361-1368. https://doi.org/10.1021/ja02242a004
  20. Matsumiya, H., Iki, N., Miyano, S. and Hiraide, M. (2004), "Preconcentration of copper, cadmium, and lead with a thiacalix[4]arenetetrasulfonate-loaded Sephadex A-25 anion-exchanger for graphite-furnace atomic-absorption spectrometry", Anal. Bioanal. Chem., 379(5-6), 867-873.
  21. Ohta, K., Ishida, K., Itoh, S., Kaneco, S. and Mizuno, T. (1998), "Determination of nickel in water by electrothermal atomic absorption spectrometry with preconcentration on a tungsten foil", Mikrochim. Acta, 129(1-2), 127-132. https://doi.org/10.1007/BF01246860
  22. Otero-Romani, J., Moreda-Pineiro, A., Bermejo-Barrera, P. and Martin-Esteban, A. (2009), "Ionic imprinted polymer for nickel recognition by using the bi-functionalized 5-vinyl-8-hydroxyquinoline as a monomer:Application as a new solid phase extraction support", Microchem. J., 93(2), 225-232. https://doi.org/10.1016/j.microc.2009.07.011
  23. Persson, Per O., Andersson, Per S., Zhang, J. and Porcelli, D. (2011), "Determination of Nd isotopes in water: A chemical separation technique for extracting Nd from seawater using a chelating resin", Anal.Chem., 83(4), 1336-1341. https://doi.org/10.1021/ac102559k
  24. Sabarudin, A., Noguchi, O., Oshima, M., Higuchi, K. and Motomizu, S. (2007), "Application of chitosan functionalized with 3,4-dihydroxy benzoic acid moiety for on-line preconcentration and determination of trace elements in water samples", Microchim. Acta, 159(3-4), 341-347. https://doi.org/10.1007/s00604-007-0734-y
  25. Shemirani, F. and Abkenar, S.D. (2004), "Preconcentration and Determination of Trace Nickel Using 1-(2-Pyridylazo)-2-Naphtol (PAN) Immobilized on Surfactant-Coated Alumina", J. Anal. Chem., 59(4),327-330. https://doi.org/10.1023/B:JANC.0000022783.94966.68
  26. Singh, D.K. and Shraddha, M. (2010), "Synthesis, characterization and analytical applications of Ni(II)-ion imprinted polymer", Appl. Surf. Sci., 256(24), 7632-7637. https://doi.org/10.1016/j.apsusc.2010.06.018
  27. Taher, M.A., Balani, S. and Puri, B.K. (2000), "Atomic absorption spectrometric determination of trace amounts of nickel after preconcentration with [1-(2-Pyridylazo)-2-Naphthol]-Naphthalene adsorbent or after adsorption of its complex on microcrystalline naphthalene", J. Anal. Chem., 55(10), 972-977. https://doi.org/10.1007/BF02756089
  28. Tokman, N., Akman, S. and Bakircioglu, Y. (2004), "Preconcentration of Nickel and Cobalt prior to their determination by graphite furnace atomic absorption spectrometry using the water-soluble polymer poly (Vinyl Pyrrolidinone)", Microchim. Acta, 146(1), 31-34. https://doi.org/10.1007/s00604-003-0172-4
  29. Tsai, S.J.J., Jan, C.C. and Chang, L.L. (1994), "Determination of lead and bismuth in nickel-base alloys by graphite furnace atomic absorption spectrometry using continuum source background correction",Spectrochim. Acta, 49(8), 773-785. https://doi.org/10.1016/0584-8547(94)80069-3

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