Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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A First Synthesis and Physical Properties of Asymmetric Anthracenes-Thiophenes Bridged with Ethylene

  • Hwang, Min Ji (Department of Chemistry and Research Institute of Natural Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Park, Ji Hee (Department of Chemistry and Research Institute of Natural Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Jeong, Eun Bin (Department of Chemistry and Research Institute of Natural Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Kang, Il (School of Nano & Materials and Engineering Research Institute, Gyeongsang National University) ;
  • Lee, Dong Hoon (Polymer Research Institute, Department of Chemical Engineering, Pohang University of Science and Technology) ;
  • Park, Chan Eon (Polymer Research Institute, Department of Chemical Engineering, Pohang University of Science and Technology) ;
  • Singh, O.M. (Department of Chemistry, Manipur University) ;
  • Choi, HoJune (Department of Chemistry and Research Institute of Natural Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Kim, Yoon-Hi (Department of Chemistry and Research Institute of Natural Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Yoon, Yong Jin (Department of Chemistry and Research Institute of Natural Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Kwon, Soon-Ki (School of Nano & Materials and Engineering Research Institute, Gyeongsang National University) ;
  • Lee, Sang-Gyeong (Department of Chemistry and Research Institute of Natural Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University)
  • Received : 2012.08.01
  • Accepted : 2012.09.03
  • Published : 2012.11.20
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Abstract

Here we report our recent result of a new semiconductor material, which has an asymmetric structure. The synthesized molecules consist of anthracene and thiophene connected by bridged ethylene and substituted with hexyl or dodecyl groups as pendants. The semiconductors were synthesized using a McMurry coupling reaction between anthracene-2-carbaldehyde and corresponding 5-hexyl(or dodecyl)thiophene-2-carbaldehyde. A first investigation of synthesized asymmetry AVHT (9a) and AVDT (9b) for the physical properties showed that they have high oxidation potential and thermal stability. The devices prepared by using AVHT (9a) and AVDT (9b) showed the mobility of $2.6{\times}10^{-2}cm^2/Vs$ and $4.4{\times}10^{-3}cm^2/Vs$, respectively, in solution processed OTFTs.

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References

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