The Korean Journal of Pesticide Science (농약과학회지)

The Korean Society of Pesticide Science (한국농약과학회)
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Monitoring of pesticide residues in commercial agricultural products in the northern area of Seoul, Korea

서울 북부지역 유통 농산물의 농약 잔류실태

  • Han, Sung-Hee (Kangbuk Agro-Fishery Products Inspection Center, Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Park, Sung-Kyu (Kangbuk Agro-Fishery Products Inspection Center, Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Kim, Ouk-Hee (Kangbuk Agro-Fishery Products Inspection Center, Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Choi, Young-Hee (Kangbuk Agro-Fishery Products Inspection Center, Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Seoung, Hyun-Jung (Kangbuk Agro-Fishery Products Inspection Center, Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Lee, Young-Ju (Kangbuk Agro-Fishery Products Inspection Center, Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Jung, Jung-Hee (Kangbuk Agro-Fishery Products Inspection Center, Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Kim, Yun-Hee (Kangbuk Agro-Fishery Products Inspection Center, Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Yu, In-Sil (Kangbuk Agro-Fishery Products Inspection Center, Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Kim, Yoo-Kyung (Kangbuk Agro-Fishery Products Inspection Center, Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Han, Ki-Young (Kangbuk Agro-Fishery Products Inspection Center, Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Chae, Young-Zoo (Kangbuk Agro-Fishery Products Inspection Center, Seoul Metropolitan Government Research Institute of Public Health and Environment)
  • 한성희 (서울시보건환경연구원 강북농수산물검사소) ;
  • 박성규 (서울시보건환경연구원 강북농수산물검사소) ;
  • 김욱희 (서울시보건환경연구원 강북농수산물검사소) ;
  • 최영희 (서울시보건환경연구원 강북농수산물검사소) ;
  • 승현정 (서울시보건환경연구원 강북농수산물검사소) ;
  • 이영주 (서울시보건환경연구원 강북농수산물검사소) ;
  • 정희정 (서울시보건환경연구원 강북농수산물검사소) ;
  • 김윤희 (서울시보건환경연구원 강북농수산물검사소) ;
  • 유인실 (서울시보건환경연구원 강북농수산물검사소) ;
  • 김유경 (서울시보건환경연구원 강북농수산물검사소) ;
  • 한기영 (서울시보건환경연구원 강북농수산물검사소) ;
  • 채영주 (서울시보건환경연구원 강북농수산물검사소)
  • Received : 2012.05.02
  • Accepted : 2012.05.25
  • Published : 2012.06.30
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Abstract

This study was conducted to monitor 284 pesticides residue level in 2,914 commercial agricultural products in the northern area of Seoul in 2011 by the multi class pesticide multiresidue analysis methods in Korea Food Code using GC, HPLC, GC-MSD and, LC-MSD. The detection rate of pesticide residues were 14.8% (431/2,914). The order of agricultural products in which the pesticide residues were detected was perilla leaves 40.0% (28/70), chamnamul 35.5% (11/31), amaranth 30.0% (3/10) and spinach 27.7% (38/137) etc. The percentage of products that exceeded the MRLs (maximum residue limits) were 1.0% (31/431). Those products that exceeded MRLs were ginseng (6), perilla leaves (4), leek (4), welsh onion (3) and sedeum (3) etc. The 59 kinds of the pesticides were detected on this study, 21 pesticides of them were detected over MRLs. Detection rate of fungicides (56.4%) was higher than that of insecticides (42.1%). And procymidone was detected with considerable high frequency. Additionally, residual residual violates pesticides were in the order of tolclofos-methyl, endosulfan, dimethomorph, diniconazole and fludioxonil. According to the agricultural marketing channels, detection and excess rate of them were monitored. Detection and excess rate of samples circulated in agricultural traditional market were highest. The estimated daily intakes (EDI) of the pesticides were compared to personal acceptable daily intakes (PADI) in order to risk assessment by food consumption. Diazinon in Korean cabbage showed the highest %ADI, 2.9901 and others showed below 3.0 %ADI. Overall, these results indicate that residue levels of pesticides detected were evaluated as safe.

본 연구는 2011년 서울 북부지역에서 유통되고 있는 농산물 2,914건을 대상으로 GC, HPLC, GC-MSD 및 LC-MSD을 이용한 다종농약다성분분석법에 따라 284종 대한 잔류농약 실태를 조사하였다. 농산물 중 431건에서 농약이 검출되어 14.8%의 검출률을 나타냈으며, 농약 검출빈도가 높은 농산물은 들깻잎 40.0%(28/70), 참나물 35.5%(11/31), 비름나물 30.0%(3/10), 시금치 27.7%(38/137) 순이었다. 이 중 농약잔류허용기준을 초과한 농산물은 31건으로 부적합률은 1.0% 였으며 인삼 6건(19.4%), 들깻잎, 부추 각각 4건(12.9%), 파, 돌나물 각각 3건(9.7%), 시금치, 상추 각각 1건(3.2%)등이었다. 분석대상 농약 284종 중에서 검출된 농약 성분은 59종으로 이 중 잔류허용기준을 초과한 농약은 21종이었다. 농약의 용도별 분포를 보면 살균제(56.4%)가 살충제(42.1%)에 비해 검출빈도가 높았다. Procymidone의 검출빈도가 가장 높았고 이 중 잔류허용기준을 초과한 농약은 tolclofos-methyl, endosulfan, dimethomorph, diniconazole, fludioxonil이였다. 판매점별 분포를 살펴보면 유통되는 농산물의 잔류농약 검출률은 직거래 장터가, 잔류농약기준 초과률은 전통시장이 가장 높았다. 배추에서 검출된 각 농약의 안전성 평가를 위한 PADI 대비 식이섭취율은 diazinon에서 2.9901 %로 가장 높게 나타났고 다른 모든 농약도 3.0% 미만으로 나타나 모두 PADI 대비 위해도가 낮은 것으로 확인되어 안전한 것으로 나타났다.

Keywords

References

  1. Do J. A., H. J. Lee, Y. W. Shin, W. J. Choe, K. R. Chae, K. C. Soon and W. S. Kim (2010) Monitoring of pesticide residues in domestic agricultural products. Journal of Food Science and Nutrition. 39(6):902-908. https://doi.org/10.3746/jkfn.2010.39.6.902
  2. Hwang Y. S., T. R. Kim, S. J. Jeon, B. C. Choe, J. S. Ahn, Y. J. Lee, M. S. Hong, N. W. Park and S. G. Park (2008) Current status of pesticide residues in commercial agricultural products in the gangseo area of Seoul (2008). Report of Seoul Institute of Health & Environment. 44:58-69.
  3. Jang M. R., H. K. Moon, T. R. Kim, D. H. Yuk, J. H. Kim and S. G. Park (2010) Dietary risk assessment for pesticide residues of vegetable Seoul, Korea. The Korea Journal of Nutrition Society. 43(4):404-412. https://doi.org/10.4163/kjn.2010.43.4.404
  4. JMHW Good Sanitation Division and Food Chemistry Division (1999) Pesticide Residues in Food. Ministry of Health and Welfare Tokyo. Japan.
  5. KFDA (2010) Korean Food Code. 58 Multi class pesticide multiresidue methods. Korea Food and Drug Administration.Korea.
  6. KFDA (2011) Pesticide Residue Database. Available from: http:// fse.foodnara.go.kr/residue/pesticides/pesticides_info.jsp. Korea Food & Drug Administration
  7. Kim M. R., M. A. Na, W. Y. Jung, C. S. Kim, N. K. Sun, E. C. Seo, E. M. Lee, Y. G. Park, J. A. Byun, J. H. Eom, R. S. Jung and J. H. Lee (2008a) Monitoring of pesticide residues in special products. The Korean Journal of Pesticide Science. 12(4): 323-334.
  8. Kim T. R., D. H. Yuk, C. K. Hong, K. H. Hwang, S. A. Jo, E. S. Lee, C. M Choi, E. H. Kim, S. H. Han, E. J. Choi, J. H. Kim, and S. G. Park (2009b) Characteristics of pesticide residues in agricultural products collected from the southern area of Seoul in 2009. Report of Seoul Institute of Health & Environment. 45:21-33.
  9. KREI (2010) Global agricultural. 119:3-13. Korea Rural Economic Institute. Korea.
  10. KRISS (2010) Report of 6th Size Korea. Korea Research Institute of Standard and Science. Korea.
  11. Kwon H. D. and J. H. Lee (2003a) A study on the pesticide residues of circulating agricultural products in Busan Area (IV). Report of Busan Institute of Health & Environment. 13:97-117.
  12. Kwon H. Y., H. D. Lee, J. B. Kim, Y. D. Jin, B. C. Moon, B. J. Park, K. A. Son, O. K. Kwon and M. K. Hong (2009b) Reduction of pesticide residues in field-sprayed leafy vegetables by washing and boiling. Journal of Food Hygiene and Safety. 24(2):182-187.
  13. Kwon S. M., E. H. Park, J. M. Kang, H. C. Jo, S. H. Jin, P. J. Yu, B. S. Ryu and G. H. Jeong (2010c) Pesticide residues survey on agricultural products before auction at whole market in Busan Area during 2006-2008. The Korean Journal of Pesticide Science. 14(2):86-94.
  14. Lee E. Y., H. H. Noh, Y. S. Park, K. W. Kang, J. K. Kim, T. D. Jin, S. S. Yun, C. W. Jin, S. K. Han and K. S. Kyung (2009b) Residual characteristics of Etofenprox and Methoxyfenozide in Chinese Cabbage. The Korean Journal of Pesticide Science. 13(1):13-20.
  15. Lee E. Y., H. H. Noh, Y. S. Park, K. W. Kang, S. Y. Jo, S. R. Lee, I. Y. Park, T. H. Kim, Y. D. Jin and K. S. Kyung (2008a) Monitoring of pesticide residues in agricultural products collected from market in Cheongju and Jeonju. The Korean Journal of Pesticide Science. 12(4):357-362.
  16. MOHW (2009) The Korea National Health & Nutrition Examination Survey. Ministry of Health and Welfare. Korea
  17. Nam H. S., Y. H. Choi, S. H. Yoon, H. M. Hong, Y. C. Park, J. H. Lee, Y. S. Kang, J. O. Lee, Y. P. Hong and H. Y. Kim (2006) Monitoring of residual pesticides in commercial agricultural products. The Korean Journal of Food Science and technology. 30(3):317-324.
  18. NAQS (2010) A Survey on Pesticide Residues of Agricultural Products (2010). National Agricultural Products Quality Management Service. Korea
  19. Seung H. J. S. K. Park, K. T. Ha, O. H. Kim, Y. H. Choi, S. J. Kim, K. A. Lee, J. I. Jang, H. B. Jo and B. H. Choi (2010) Survey on pesticide residues in commercial agricultural products in the northern area of Seoul. Journal of Food Hygiene and Safety. 25(2):106-117.
  20. Song N. S., M. Y. Lee, S. M. Park, J. D. Kim, H. K. Kang, I. S. Park, C. Y. Lee and G. B. Yoo (2000) A study on the residual pesticide of agricultural production in Chungcheongnam- Do. Report of Chungnam Institute of Health & Environment. 11.

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