Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis and Characterization of a Tetrathiafulvalene-Based Polymer

  • Lee, Se-Hyun (Department of Polymer-Nano Science Technology and Polymer Materials Fusion Research Center, Chonbuk National University) ;
  • Wang, Lei (Department of Materials Physics and Chemistry, University of Science and Technology Beijing) ;
  • Hwang, Seok-Ho (Department of Polymer Science and Engineering, Dankook University) ;
  • Lee, Myong-Hoon (Department of Polymer-Nano Science Technology and Polymer Materials Fusion Research Center, Chonbuk National University) ;
  • Jeong, Kwang-Un (Department of Polymer-Nano Science Technology and Polymer Materials Fusion Research Center, Chonbuk National University)
  • Received : 2011.05.10
  • Accepted : 2011.11.22
  • Published : 2012.05.20
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Abstract

A novel tetrathiafulvalene (TTF)-based main-chain polymer (6TTF-polymer) was successfully synthesized via a condensation polymerization between a newly synthesized dihydroxy TTF derivative and a malonyl chloride, and its chemical structure was characterized by spectroscopic techniques. Molecular weight of the 6TTF-polymer (9,030 g/mol by gel permeation chromatography) was large enough to form the ductile film. The electrochemical and optical properties of the 6TTF-polymer were further estimated by cyclic voltammetry, ultraviolet and photoluminescence spectroscopes. The highest occupied molecular orbital level ($E_{HOMO}$=-4.79 eV) and band-gap energy ($E_g$=1.91 eV) of the 6TTF-polymer suggested that TTF-based polymer could act as a good electron donating material for the optoelectronic applications.

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References

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