DOI QR코드

DOI QR Code

A Study on the Development of the Mercury Emission Factor from Coal-fired Power Plant

석탄 화력발전시설에서의 수은 배출계수 개발에 관한 연구

  • Kim, Hyung-Chun (Air Pollution Engineering Division, National Institute of Environmental Research) ;
  • Park, Jung-Min (Air Pollution Engineering Division, National Institute of Environmental Research) ;
  • Jang, Kee-Won (Air Pollution Engineering Division, National Institute of Environmental Research) ;
  • Lee, Sang-Bo (Air Pollution Engineering Division, National Institute of Environmental Research) ;
  • Jung, No-El (Air Pollution Engineering Division, National Institute of Environmental Research) ;
  • Song, Deok-Jong (Air Pollution Engineering Division, National Institute of Environmental Research) ;
  • Hong, Ji-Hyung (Air Pollution Engineering Division, National Institute of Environmental Research) ;
  • Lee, Suk-Jo (Air Pollution Engineering Division, National Institute of Environmental Research) ;
  • Kim, Sang-Kyun (Air Pollution Engineering Division, National Institute of Environmental Research)
  • 김형천 (국립환경과학원 대기공학연구과) ;
  • 박정민 (국립환경과학원 대기공학연구과) ;
  • 장기원 (국립환경과학원 대기공학연구과) ;
  • 이상보 (국립환경과학원 대기공학연구과) ;
  • 정노을 (국립환경과학원 대기공학연구과) ;
  • 송덕종 (국립환경과학원 대기공학연구과) ;
  • 홍지형 (국립환경과학원 대기공학연구과) ;
  • 이석조 (국립환경과학원 대기공학연구과) ;
  • 김상균 (국립환경과학원 대기공학연구과)
  • Received : 2012.01.11
  • Accepted : 2012.03.20
  • Published : 2012.04.30

Abstract

Mercury is one of the most hazardous air pollutants. Recently, mercury has been a concern in domestic and overseas because it has lethal toxicity, long distance transport, persistence and bioaccumulation in the environment. Stationary combustion sources such as coal-fired power plants, waste incinerators, and cement kilns are the major sources of mercury emissions. The objectives of this study were to measure the concentration for mercury from coal-fired power plants and to calculate emission factor to estimate its emission. The results showed that the mercury concentrations in the flue gas were 1.63-3.03 mg/$Sm^3$ in anthracite-fired power plants (average 2.32 mg/$Sm^3$) and 1.95-3.33 mg/$Sm^3$ in bituminous-fired power plants (average 2.6 mg/$Sm^3$). Mercury emission factor was estimated as 25.74 mg/ton for anthracite-fired power plants and 12.48 mg/ton for bituminous-fired power plants. Because actual measurements are limited in quantity, it is desirable to refine our estimates by extending the actual measurements.

Keywords

References

  1. Gale, T.K., B.W. Lani, and G.R. Offen (2008) Mechanisms governing the fate of mercury in coal-fired power systems, Fuel Processing Technology, 89, 139-151. https://doi.org/10.1016/j.fuproc.2007.08.004
  2. Jang, K.-W., H.-C. Kim, Y.-M. Lee, D.-J. Song, N. Jung, S.-K. Kim, J.-H. Hong, S.-J. Lee, and J.-S. Han (2011) Estimating PM Emission Factor from Coal-Fired Power Plants in Korea, Journal of Korea Society for Atmospheric Environment, 27(5), 485-493. (in Korean with English abstract) https://doi.org/10.5572/KOSAE.2011.27.5.485
  3. Jurng, J.-S. and S.-G. Shim (2009) Mercury Research and Management in Korea, Journal of Korea Society for Atmospheric Environment, 25(2), 99-107. (in Korean with English abstract) https://doi.org/10.5572/KOSAE.2009.25.2.099
  4. Kevin, C.G. and C.J. Zygarlicke (1996) Mercury Speciation in Coal Combustion and Gasification Flue Gases, Environmental Science & Technology, 30(8), 2421-2426. https://doi.org/10.1021/es950935t
  5. Kim, J.-H., J.-M. Park, S.-B. Lee, D. Pudasainee, and Y.-C. Seo (2010) Anthropogenic mercury emission inventory with emission factors and total emission in Korea, Atmospheric Environment, 44, 2714-2721. https://doi.org/10.1016/j.atmosenv.2010.04.037
  6. Korea Electric Power Corporation (2009) Statistics of Electric Power in Korea, KEPC Official Press Release No. 2009-08460528-0020.
  7. Li, P., X.B. Feng, G.L. Qui, L.H. Shang, and Z.G. Li (2009) Mercury pollution in Asia, Journal of Hazardous Materials, 168, 591-601. https://doi.org/10.1016/j.jhazmat.2009.03.031
  8. NIER (2002) Emission Characteristic of Mercury in Air Emission Sources No. 2002-05-644.
  9. NIER (2006) Development of analytical methods for Organomercury and Studies of field applications in the environment (I) No. 2006-45-827.
  10. NIER (2009) Stationary sources of mercury emission research.
  11. NIER (2010) A Study on Integrated Management of Mercury Using and Emission Faciliteies (I) No. 2010-14-1189.
  12. Park, J.-M., S.-B. Lee, H.-C. Kim, D.-J. Song, M.-S. Kim, M.-J. Kim, Y.-H. Kim, S.-H. Lee, J.-C. Kim, and S.-J. Lee (2010) Emission Characteristics of Mercury in Zn Smelting Process, Journal of Korea Society for Atmospheric Environment, 26(5), 507-516. (in Korean with English abstract) https://doi.org/10.5572/KOSAE.2010.26.5.507
  13. Park, K.-S., J.-H. Lee, J.-H. Kim, S.-H. Lee, and Y.-C. Seo (2008) A Study on Emission Characteristics of Mercury from Coal Combustion at a Lab-scale Furnace, Journal of Korea Society for Atmospheric Environment, 24(2), 238-248. (in Korean with English abstract) https://doi.org/10.5572/KOSAE.2008.24.2.238
  14. Prestbo, E.M. and N.S. Bloom (1993) Recent Advances in the Measurement of Mercury species in Combustion Flue gas using solid phase adsorption and cold vapor atomic fluorescence spectroscopy, Journal of the Air & Waste Management Association for Presentation at the 86th Annual meeting & exhibition, 93TA-32.05.
  15. Pudasainee, D., J.-H. Kim, and Y.-C. Seo (2009) Mercury emission trend influenced by stringent air pollutants regulation for coal-fired power plants in Korea, Atmospheric Environment, 43, 6254-6259. https://doi.org/10.1016/j.atmosenv.2009.06.007
  16. UNEP (2008) Technical Background Report to the Global Atmospheric Mercury Assessment.
  17. Yudovich, Y.E. and M.P. Ketris (2005) Mercury in coal: a review: Part 1. Geochemistry, International Journal of Coal Geology, 62, 107-134. https://doi.org/10.1016/j.coal.2004.11.002

Cited by

  1. A Study on the Comparison of Measuring Methods and Development of Emssion Factor on Mercury from Large-Scale Emission Sources vol.32, pp.2, 2016, https://doi.org/10.5572/KOSAE.2016.32.2.184
  2. Estimation of Mercury Emission from Major Sources in Annex D of Minamata Convention and Future Trend vol.32, pp.2, 2016, https://doi.org/10.5572/KOSAE.2016.32.2.193