자원리싸이클링 (Resources Recycling)

  • 제21권6호
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  • Pages.3-11
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  • 2012
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  • 2765-3439(pISSN)
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  • 2765-3447(eISSN)
한국자원리싸이클링학회 (The Korean Institute of Resources Recycling)
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1차(次)/2차(次) 자원(資源)으로부터 Os과 Ru 회수기술(回收技術)

Technology for the Recovery of Os and Ru from Primary/Secondary Resources

  • 손반반 (목포대학교 공과대학 신소재공학과) ;
  • 이만승 (목포대학교 공과대학 신소재공학과)
  • Sun, Pan-Pan (Department of Advanced Materials Science & Engineering, Mokpo National University) ;
  • Lee, Man-Seung (Department of Advanced Materials Science & Engineering, Mokpo National University)
  • 투고 : 2012.09.18
  • 심사 : 2012.10.29
  • 발행 : 2012.12.31
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초록

오스뮴과 루테늄을 함유한 1차와 2차 자원으로부터 두 금속의 회수 방법을 조사했다. 오스뮴과 루테늄은 휘발성이 있는 산화물을 형성하므로 증발법을 통해 다른 백금족금속으로부터 분리가 가능하다. 두 금속은 염산용액에서 다양한 산화상태의 착물을 형성한다. 아민계 또는 아민계 혼합추출제는 침출용액으로부터 루테늄의 추출에 이용된다. 용매화 추출제는 루테늄과 오스뮴의 분리에 사용된다. 기존에 발표된 용매추출공정의 추출과 탈취조건을 조사했다. 용매추출에 대한 대체 공정으로 미량성분의 회수에 이용될 수 있는 고체-액체법을 소개하였다.

Some methods used for the recovery of osmium and ruthenium from primary/secondary sources are reviewed. Both Ru and Os could form volatile oxides which enable their separation from the other PGMs by distillation as a traditional method. In hydrochloric acid solution, they also form chloro-complexes with different valence states. Amines or amine based mixture have been used to extract Ru. Solvating extractants are employed to separate Ru and Os. The detailed extraction and stripping conditions of several solvent extraction processes have been reviewed. As an alternative to solvent extraction, solid-liquid method can be applied to recover trace amount of these metals.

키워드

과제정보

연구 과제 주관 기관 : 환경부

참고문헌

  1. Abel Engh, T., 1992: Principles of metal refining, pp 166-167. Oxford, USA.
  2. Malik, P., and Paiva, A. P., 2011: Liquid-liquid extraction of ruthenium from chloride media by N, N'-Dimethyl- N, N'-Dicyclohexylmalonamide, Solvent Extr. Ion Exch., 29, pp 176-189. https://doi.org/10.1080/07366299.2011.539463
  3. The application of Os. General internet address http:// www.cnmn.com.cn/ShowNews1.aspx?id=184521 (accessed on February 2007).
  4. Rao, C.R.M., Reddi, G. S., 2000: Platinum group metals (PGM); occurrence, use and recent trends in their determination, Trends Anal. Chem., 19, pp 565-586. https://doi.org/10.1016/S0165-9936(00)00031-5
  5. Zhang M. J., 1999: Separation and purification of Ru, Os and Ir from residue of manufacture of fountain pen tips (In chinese), China writing instr., 73, pp 32-38.
  6. Gindin, L.M., 1974: solvent extraction of elements of the platinum group, edited by Marinsky, J.A., and Marcus, Y., pp 311-368, Marcel Dekker, Inc., New York.
  7. Cleare, M.J., Charlesworth, P., and Bryson, D. J., 1979: Solvent extraction in platinum group metal processing, J. Chem. Tech. Biotechnol., 29, pp 210-214.
  8. Bernardis, F. L., Grant, R. A., Sherrington, D. C., 2005: A review of methods of separation of the platinum-group metals through their chloro-complexes, React. Funct. Polym., 65, pp 205-217. https://doi.org/10.1016/j.reactfunctpolym.2005.05.011
  9. Yang, H.M., Ling, W. L., 2006: measure method of Re-Os isotopes in geological and the development of their application, Adv. Earth sci., 21, pp 1014-1021.
  10. Pearson, D.G., Woodland, S. J., 2000: Solvent extraction/ anion exchange separation and determination of PGEs (Os, Ir, Pt, Pd, Ru) and Re-Os isotopes in geological samples by isotope dilution ICP-MS, Chem. Geol., 165, pp 87-107. https://doi.org/10.1016/S0009-2541(99)00161-8
  11. Cohen, A.S., Waters, F.G., 1996: Separation of osmium from geological materials by solvent extraction for analysis by thermal ionization mass spectrometry. Anal. Chim. Acta, 332, pp 269-275. https://doi.org/10.1016/0003-2670(96)00226-7
  12. Diamantatos, A.,1977: An intergrated scheme for the recovery of the six platinum-group metals and gold after lead fusion and perchloric acid parting and a comparison with the lead cupellation, tin, and nickel sulphide collection schemes, Anal. Chim. Acta., 94, pp 49-55. https://doi.org/10.1016/S0003-2670(01)83630-8
  13. Zhu, W. N., Liu, S.C., 2007: Recovery of ruthenium from Waste Catalysts, Henan Chem. Ind. (in chinese), 4, pp 31-34.
  14. Liu, L., Cui, W.Q., Pan, X., 2010: Recovery of ruthenium from waste Ru/$Al_{2}O_{3}$catalyst, Inorg. Chem. Ind. (in chinese), 5, pp 48-49, 55.
  15. Cox, M., 2004: Solvent extraction principles and practice, edited by Rydberg, J., Cox, M., Musikas, C., Choppin, G. R., pp 482-484, Marcel Dekker, Inc., New York.
  16. Chen, J., 1984: The relationship between the stability of platinum group metals complexing compound and their atomic structure, Precious Met. (In chinese), 5, pp 1-9.
  17. Kedari, C. S., Coll, M. T., Fortuny, A., Goralska, E., and Sastre, A. M., 2005: Liquid-liquid extraction of Ir, Ru and Rh from chloride solutions and their separation using different commercially available solvent extraction reagents, Separ. Sci. Technol., 40(9), pp 1927-1946. https://doi.org/10.1081/SS-200064551
  18. Goralska, E., Coll, M. T., Fortuny, A., Kedari, C. S., and Sastre, A. M., 2007: Studies on the selective separation of Ir(IV), Ru(III) and Rh(III) from chloride solutions using Alamine336 in kerosene, Solvent Extr. Ion Exch., 25(1), pp 65-77. https://doi.org/10.1080/07366290601067820
  19. Kedari, C. S., Coll, M. T., Fortuny, A., Goralska, E., and Sastre, A. M., 2006: Recovery and partitioning of Ir(IV) and Ru(III) from chloride solutions by solvent extraction using Cyanex923/kerosene, Hydrometallurgy, 82, pp 40-47. https://doi.org/10.1016/j.hydromet.2006.01.002
  20. Afzaletdinova, N.G., Ryamova, L.M., Murinov, Y.I., and Kunakova, R.V., 2006: Extraction of ruthenium (III) by dihexyl sulfoxide from hydrochloric solutions, Russ. J. Inorg. Chem., 51(7), pp 1139-1145. https://doi.org/10.1134/S0036023606070199
  21. Rechnitz, G.A., Goodkin, S.C., 1963: some properties of Ru(III) and (IV) in acid solution. A review of recent research. Platinum Met. Rev., 7(1), pp 25-29.
  22. Zarhloul, R., Due, G., Deloume, J.P., 1989: Reactions of ruthenium (III) and (IV) chlorocomplexes with nitrogen oxides NO and $NO_{2}$, Inorg. Chim. Acta, 160(1), pp 59-63. https://doi.org/10.1016/S0020-1693(00)85399-2
  23. Kankekar, P.S., Wagh, S.J., and Mahajani, V.V., 2010: Process intensification in extraction by liquid emulsion membrane (LEM) process: A case study; enrichment of ruthenium from lean aqueous solution, Chem. Eng. Process., 49, pp 441-448. https://doi.org/10.1016/j.cep.2010.02.005
  24. Mhaske, A., Dhadke, P., 2002: extraction studies of platinum group metals with Cyanex 925 in toluene-role of tin(II) chloride in their separation, Separ. Sci. Technol., 37 (8), pp 1861-1875. https://doi.org/10.1081/SS-120003048
  25. Mhaske, A., and Dhadke, P., 2002: Extraction separation studies of Os, Ru and Ir using Cyanex 921 in toluene, Hydrometallurgy, 63, pp 207-214. https://doi.org/10.1016/S0304-386X(01)00218-3
  26. Meadows, J.W.T., Marlack, G.M., 1962: Radiochemical determination of ruthenium by solvent extraction and preparation of carrier free ruthenium activity, Anal. Chim., 34, pp 89-91. https://doi.org/10.1021/ac60181a025
  27. Morgan, J.W., 1965: The simultaneous determination of rhenium and osmium in rocks by neutron activation analysis, Anal. Chim. Acta, 32, 8-16. https://doi.org/10.1016/S0003-2670(00)88886-8
  28. Crocket, J.H., Keays, R.R., Hsieh, S., 1968: Determination of some precious metals by neutron activation analysis. J. Radioanal. Nucl. Ch., 1(6), pp 487-507. https://doi.org/10.1007/BF02518480
  29. Afzaletdinova, N. G., Murinov, Y. I., Ryamova, L. M., and Bondareva, S. O., 2005: Extraction of ruthenium(III) by bisacylated triethylenetetramine from hydrochloric acid solutions, Russ. J. Inorg. Chem., 50(8), pp 1288-1293.
  30. Afzaletdinova, N.G., Ryamova, L.M., Murinov, Y.I., and Kunakova, R.V., 2006: Extraction of ruthenium (III) by dihexyl sulfoxide from hydrochloric solutions, Russ. J. Inorg. Chem., 51(7), pp 1139-1145. https://doi.org/10.1134/S0036023606070199
  31. Narita, H., Tanaka, M., and Morisaku, K., 2005: Extraction properties of platinum group metals with diamide compounds, In Conference Proceeding Editorial Department (Ed.), pp. 227-232, Proceedings of the International Solvent Extraction Conference-ISEC 2005, Beijing, People's Republic of China, 19-23 September 2005.
  32. Druškoviæ, V., Vojkoviæ, V., and Antoniae, T., 2005: Extraction of ruthenium (III) and its separation from rhodium and palladium with 4-pyridone derivatives, Croat. Chem. Acta, 78(4), pp 617-626.
  33. Lokhande, T., Kolekar, G. B., Anuse, M. A., and Chavan, M. B., 1999: Extraction of ruthenium (III) from hydrochloric acid medium with N-octylaniline and its determination spectrophotometrically with pyrimidine-2- thiol, Separ. Sci. Technol., 35(1), pp 153-168.
  34. Lu, Z. E.,1981: N,N-Di-sec-octylacetamide(DOAA) as a stationary phase in reversed paper chromatography for the separation of ruthenium-osimum, rhodium-iridium, palladiumplatinum and some other couples and their Rf graphs, Chinese J. Anal. Chem., 9(2), pp 152-155.
  35. Cao, Z.B., Lu, Z.E., 1983: DEHSO as a stationary phase in reversed paper chromatography for the separation of Ru- Os, Rh-Ir, Pt-Pd couple metals and their Rf graphs, Chem. Res. Chinese U., 4(1), pp 43-46.
  36. Chen, L. P., Li, G.Z. Ding, L.G., 1998: The study on the extraction separation of precious metals by two kinds of Sisothiourea hydrochlorides, Inner Mongolia Petrochem.(in chinese), 24(4) pp 6-8.
  37. Kokate, S. J., Aher, H. R., Han, S.H., Kuchekar, S. R., 2012: Reverse phase extraction chromatographic separation of osmium(VIII) with N-n-octylamine, Indian J. Chem. Technol., 19, pp 239-243.
  38. Lokhande, T. N., Anuse, M.A., and Chavan, M.B., 2000: Solvent extraction and determination of osmium(VIII), J. Saudi. Chem. Soc., 4, pp 1.
  39. Losev, V. N., Bakhtina, M. P., Kudrina, Y. V., Trofimchuk, A. K., and Komozin, P. N., 2005: Sorption of osmium and ruthenium in various oxidation states by silica chemically modified with N-(2, 6-dimethyl-4-methylenetriphenylphosphonium chloride) phenyl-N'-propylthiourea groups, Russ. J. Inorg. Chem., 50(5), pp 705-710.
  40. Kasaini, H., Goto, M., and Furusaki, S., 2000: Selective separation of Pd(II), Rh(III), and Ru(III) ions from a mixed chloride solution using activated carbon pellets, Separ. Sci. Technol., 35(9), pp 1307-1327. https://doi.org/10.1081/SS-100100226