DOI QR코드

DOI QR Code

Carrier Gas Assisted Solvent Vapor Treatment for Surface Nanostructuring of Molecular Thin Films

  • Received : 2011.11.11
  • Accepted : 2011.12.21
  • Published : 2012.03.20

Abstract

In this study, the variation in surface morphology of copper phthalocyanine (CuPc) thin films treated with a flow of acetone vapor assisted by nitrogen carrier gas was investigated. The CuPc nanorods with similar dimensions were well dispersed throughout the whole film surfaces after ~20 min. of treatment. However, the electronic absorption spectra only changed slightly, which indicates that molecular stacking was not altered during treatment. This treating method is simple and more advantageous compared to other solvent treating technologies such as mixed solvent spray treatment using organic solvents and water since it requires relatively mild treating conditions and does not need the presence of water.

Keywords

References

  1. Forrest, S. R. Chem. Rev. 1997, 97, 1793. https://doi.org/10.1021/cr941014o
  2. Gundlach, D. J.; Lin, Y. Y.; Jackson, T. N.; Nelson, S. F.; Schlom, D. G. IEEE Electron Device Lett. 1997, 18, 87. https://doi.org/10.1109/55.556089
  3. Steudel, S.; De Vusser, S.; De Jonge, S.; Janssen, D.; Verlaak, S.; Genoe, J.; Heremans, P. Appl. Phys. Lett. 2004, 85, 4400. https://doi.org/10.1063/1.1815042
  4. Cheyns, D.; Vasseur, K.; Rolin, C.; Genoe, J.; Poortmans, J.; Heremans, P. Nanotechnology 2008, 19, 424016. https://doi.org/10.1088/0957-4484/19/42/424016
  5. Wang, D. H.; Choi, D.-G.; Lee, K.-J.; Jeong, J.-H.; Jeon, S. H.; Park, O. O.; Park, J. H. Org. Electron. 2010, 11, 285. https://doi.org/10.1016/j.orgel.2009.11.007
  6. Nanditha, D. M.; Dissanayake, M.; Adikaari, A. A. D. T.; Curry, R. J.; Hatton, R. A.; Silva, S. R. P. Appl. Phys. Lett. 2007, 90, 253502. https://doi.org/10.1063/1.2749863
  7. Castro, F. A.; Benmansour, H.; Graeff, C. F. O.; Nesch, F.; Tutis, E.; Hany, R. Chem. Mater. 2006, 18, 5504. https://doi.org/10.1021/cm061660r
  8. Orozco, M. C.; Tsoi, W. C.; O'Neil, M.; Aldred, M. P.; Vlachos, P.; Kelly, S. M. Adv. Mater. 2006, 18, 1754. https://doi.org/10.1002/adma.200502008
  9. Liang, X.; Chen, T.; Jung, Y.-S.; Miyamoto, Y.; Han, G.; Cabrini, S.; Ma, B.; Olynick, D. L. ACS Nano 2010, 4, 2627. https://doi.org/10.1021/nn100075t
  10. Xi, H.; Wei, Z.; Duan, Z.; Xu, W.; Zhu, D. J. Phys. Chem. C 2008, 112, 19934. https://doi.org/10.1021/jp8080673
  11. Kim, J.; Park, C. R.; Yim, S. RSC Adv. submitted.
  12. Riede, M.; Mueller, T.; Tress, W.; Schueppel, R.; Leo, K. Nanotechnology 2008, 19, 424001. https://doi.org/10.1088/0957-4484/19/42/424001
  13. Rand, B. P.; Genoe, J.; Heremans, P.; Poortmans, J. Prog. Photovolt: Res. Appl. 2007, 15, 659. https://doi.org/10.1002/pip.788
  14. Radivojevic, I.; Varotto, A.; Farley, C.; Drain, C. M. Energy Environ. Sci. 2010, 3, 1897. https://doi.org/10.1039/c0ee00009d
  15. Senthilarasu, S.; Baek, S.-J.; Chavhan, S. D.; Lee, J.; Lee, S.-H. J. Nanosci. Nanotechnol. 2008, 8, 5414. https://doi.org/10.1166/jnn.2008.1050
  16. Yim, S.; Jones, T. S. Phys. Rev. B 2006, 73, 161305(R).
  17. Park, G.; Heo, I.; Ryu, I.; Yim, S. Bull. Kor. Chem. Soc. 2011, 32, 943. https://doi.org/10.5012/bkcs.2011.32.3.943
  18. Leznoff, C. C., Lever, A. B. P., Eds.; Phthalocyanines: Properties and Applications; VCH Publishers: New York, 1996.
  19. Snow, A. W.; Jarvis, N. L. J. Am. Chem. Soc. 1984, 106, 4706. https://doi.org/10.1021/ja00329a012

Cited by

  1. Controlled growth of ZnPc nanostructures via heat assisted solvent vapour treatment method and application in photovoltaic devices vol.27, pp.10, 2016, https://doi.org/10.1007/s10854-016-5170-5
  2. Efficient solvent-assisted external treatment for planar heterojunction small-molecule organic solar cells vol.2, pp.26, 2012, https://doi.org/10.1039/c4ta01154f