Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Solution Processable Symmetric 4-Alkylethynylbenzene End-Capped Anthracene Derivatives

  • Jang, Sang-Hun (Department of Chemistry, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Kim, Hyun-Jin (Department of Chemistry, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Hwang, Min-Ji (Department of Chemistry, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Jeong, Eun-Bin (Department of Chemistry, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Yun, Hui-Jun (School of Nano & Materials and Engineering Research Institute, Gyeongsang National University) ;
  • Lee, Dong-Hoon (Polymer Research Institute, Department of Chemical Engineering, Pohang University of Science and Technology) ;
  • Kim, Yun-Hi (Department of Chemistry, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Park, Chan-Eon (Polymer Research Institute, Department of Chemical Engineering, Pohang University of Science and Technology) ;
  • Yoon, Yong-Jin (Department of Chemistry, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Kwon, Soon-Ki (School of Nano & Materials and Engineering Research Institute, Gyeongsang National University) ;
  • Lee, Sang-Gyeong (Department of Chemistry, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University)
  • Received : 2011.11.03
  • Accepted : 2011.12.09
  • Published : 2012.02.20
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Abstract

New candidates composed of anthracene and 4-alkylethynylbenzene end-capped oligomers for OTFTs were synthesized under Sonogashira coupling reaction conditions. All oligomers were characterized by FT-IR, mass, UV-visible, and PL emission spectrum analyses, cyclic voltammetry (CV), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), $^1H$-NMR, and $^{13}C$-NMR. Investigation of their physical properties showed that the oligomers had high oxidation potential and thermal stability. Thin films of DHPEAnt and DDPEAnt were characterized by spin coating them onto Si/$SiO_2$ to fabricate top-contact OTFTs. The devices prepared using DHPEAnt and DDPEAnt showed hole field-effect mobilities of $4.0{\times}10^{-3}cm^2$/Vs and $2.0{\times}10^{-3}cm^2$/Vs, respectively, for solution-processed OTFTs.

Keywords

References

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