Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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One-pot Synthesis of Benzimidazoles and Benzothiazoles in the Presence of Fe(HSO4)3 as a New and Efficient Oxidant

  • Eshghi, Hossein (Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad) ;
  • Rahimizadeh, Mohammad (Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad) ;
  • Shiri, Ali (Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad) ;
  • Sedaghat, Parisa (Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad)
  • Received : 2011.09.05
  • Accepted : 2011.12.07
  • Published : 2012.02.20
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Abstract

A series of substituted benzimidazoles and benzothiazoles were prepared through the one-pot reaction of ophenylenediamine and o-aminothiophenol with various aldehydes in the presence of ferric hydrogensulfate both in EtOH and water as solvent. The reactions proceed smoothly in excellent yield, high chemoselectivity and with an easy work-up.

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References

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