Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis and Characterization of Schiff Base Metal Complexes and Reactivity Studies with Malemide Epoxy Resin

  • Lakshmi, B. (Department of Chemistry, Bangalore University) ;
  • Shivananda, K.N. (Schulich Faculty of Chemistry, Technion-Israel Institute of Technology) ;
  • Prakash, Gouda Avaji (Department of Chemistry, Karnatak University) ;
  • Isloor, Arun M. (Organic Chemistry Division, Department of Chemistry, National Institute of Technology) ;
  • Mahendra, K.N. (Department of Chemistry, Bangalore University)
  • Received : 2011.08.10
  • Accepted : 2011.12.05
  • Published : 2012.02.20
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Abstract

A novel malemide epoxy containing Co(II), Ni(II) and Cu(II) ions have been synthesized by curing malemide epoxy resin (MIEB-13) and Co(II), Ni(II) and Cu(II) complexes of macrocyclic bis-hydrazone Schiff base. The Schiff base was synthesized by reacting 1,4-dicarbnyl phenyl dihydrazide with 2,6-diformyl-4-methyl phenol. The Schiff base and its Co(II), Ni(II) and Cu(II) complexes have been characterized by elemental analyses, spectral (IR, $^1H$ NMR, UV-vis., FAB mass, ESR), thermal and magnetic data. The curing reaction of maleimide epoxy compound with metal complexes was studied as curing agents. The stability of cured samples was studied by thermo-gravimetric analyses and which have excellent chemical (acid/alkali/solvent) and water absorption resistance. Further, the scanning electron microscopy (SEM) and definitional scanning colorimetric (DSC) techniques were confirmed the phase homogeneity of the cured systems.

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References

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