Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Chain Length Effect of Dialkoxynaphthalene End-Capped Divinylbenzene for OTFT

  • Kim, Ran (Department of Chemistry and RINS, Gyeongsang National University) ;
  • Yun, Hui-Jun (School of Materials Science and Engineering and ERI, Gyeongsang National University) ;
  • Yi, Mi-Hye (Advanced Materials Division, Korea Research Institute of Chemical Technology) ;
  • Shin, Sung-Chul (Department of Chemistry and RINS, Gyeongsang National University) ;
  • Kwon, Soon-Ki (School of Materials Science and Engineering and ERI, Gyeongsang National University) ;
  • Kim, Yun-Hi (Department of Chemistry and RINS, Gyeongsang National University)
  • Received : 2011.10.11
  • Accepted : 2011.11.28
  • Published : 2012.02.20
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Abstract

The new organic semiconductors which are composed of divinylbenzene core unit and alkoxynaphthalene on both sides, 1,4-bis-2-(6-octyloxy)naphthalen-2-ylvinylbenzene (BONVB), 1,4-bis-2-(6-decyloxy)naphthalen-2-ylvinylbenzene (BDNVB) and 1,4-bis-2-(6-dodecyloxy)naphthalen-2-ylvinylbenzene (BDDNVB) were synthesized by Wittig reaction. The structures of obtained BONVB, BDNVB and BDDNVB were confirmed by FT-IR and mass spectroscopy. UV-absorption of thin film showed H-aggregates and J-aggregates due to closely packed structure between adjacent molecules. The characterization of vacuum-evaporated films by Xray diffraction (XRD) and atomic force microscopy (AFM) showed that the chain length of alkoxy group affects the crystallinity and morphology. BONVB with octyloxy group showed the mobility of $0.011cm^2/V{\cdot}s$, on/off ratio of $1.31{\times}10^5$, and a subthreshold slope of 0.93 V.

Keywords

References

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