한국염색가공학회지 (Textile Coloration and Finishing)

  • 제23권2호
  • /
  • Pages.100-106
  • /
  • 2011
  • /
  • 1229-0033(pISSN)
  • /
  • 2234-036X(eISSN)
한국염색가공학회 (The Korean Society of Dyers and Finishers)
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UV/Ozone 조사에 의한 PET 직물의 편면 발수가공

One-side Water-repellent Finish of PET Fabrics using UV/Ozone

  • 김수진 (금오공과대학교 나노바이오텍스타일공학과) ;
  • 장진호 (금오공과대학교 나노바이오텍스타일공학과)
  • Kim, Su-Jin (Department of Nano-Bio Textile Engineering, Kumoh National Institute of Technology) ;
  • Jang, Jin-Ho (Department of Nano-Bio Textile Engineering, Kumoh National Institute of Technology)
  • 투고 : 2011.05.12
  • 심사 : 2011.06.22
  • 발행 : 2011.06.27
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초록

UV-curable water-repellent finish was carried out to impart one-side repellency to the PET fabrics using a formulation of a UV-active fluorocarbon agent and a water soluble photoinitiator. The aqueous formulation was padded on the PET fabrics and it was subsequently UV-cured. The unirradiated side of the cured fabrics was made to wetteable to water by the prolonged UV/ozone irradiation. The influence of photoinitiator concentration, agent concentration and UV energy for photodegradation on the performance of the finished fabrics were investigated. The difference in the functional property of front and back sides was examined by measuring water repellency at each side of the treated fabrics, which resulted in four rating difference between two-side. The UV-cured and photodegraded PET surfaces were characterized by ATR, ESCA and FE-SEM.

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참고문헌

  1. C. W. Nam, Y. C. Park, H. J. Lee, and S. K. Song, The Recent Development Trend of Textile Finishing Agent and Technology, Fiber Technol. Ind., 7(3), 273-291(2003).
  2. K. Hong and S. Hong, The Measurement and Application of Clothing Comfort, Fiber Technol. Ind., 2(4), 451-469(1998).
  3. G. Y. Moon, Fiber Wetting and Water Repellent Finish, J. Korean Fiber Soc., 7(2), 99-106(1970).
  4. E. Kissa,"Fluorinated Surfactants and Repellents", Marcel Dekker Inc., N.Y., pp.516-551, 2001.
  5. D. Heywood, "Textile Finishing", Society of Dyers and Colourists, Bradford, pp.176-210, 2003.
  6. F. Audenaert, H. Lens, D. Rolly, and P. V. Elst, Fluorochemical Textile Repellent-Synthesis and Application, J. Text. Inst., 90, 76-94(1999). https://doi.org/10.1080/00405009908659480
  7. E. G. Shafrin and W. A. Zisman, Constitutive Relations in the Wetting of Low Energy Surfaces and the Theory of the Retraction Method of Preparing Monolayers, J. Phys. Chem., 64, 519-524(1960). https://doi.org/10.1021/j100834a002
  8. G. Cho and J. Choi, Effect of Water- and Oil-Repellent Finish on Barrier Properties of Nonwoven Fabrics, J. Korean Soc. Clothing Textiles, 17(4), 577-586(1993).
  9. D. W. Tyner, Evaluation of Repellent Finishes Applied by Atmospheric Plasma, Master Thesis, NC State Univesity, 2007.
  10. H. Miao, F. Bao, L. Cheng, and W. Shi, Cotton Fabric Modification for Imparting High Water and Oil Repellency uisng Perfluoroalkyl Phosphate Acrylate gray-induced Grafting, Radition Physics and Chemistry, 17, 786-790(2010).
  11. H. J. Ha and J. S. Lee, The Effect of Water- and Oil Repellent Finishes on the Surface Characteristics of Polyester Fabrics, J. Korean Home Economics Association, 35(3), 275-286(1997).
  12. S. Park, J. Kim, I. Kwon, B. Song, J. Kim, T. Baek, J. Jeong, G. Koo, J. Choi, S. Park, Korea Pat. 100902119(2009).
  13. R. Davis, A. Shafei, and P. Hauser, Use of Atmospheric Pressure Plasma to Confer Durable Water Repellent Functionality and Antimicrobial Functionality on Cotton/polyester Blend, Surface & Coatings Technology, 205, 4791-4797(2011). https://doi.org/10.1016/j.surfcoat.2011.04.035
  14. S. P. Pappas, "UV Curing: Science and Technology", Technology Marketing Corporation, Stanford, 1985.
  15. P. K. T. Oldring, "Chemistry & Technology of UV & EB Formulation for Coatings, Inks & Paints", Vol. I -IV SITA Technology, London, 1991.
  16. J. P. Fouassier and J. F. Rabek, "Radiation Curing in Polymer Science and Technology", Vol. I -IV, Elsevier Science Publisher, London, 1993.
  17. C. Roffey, "Photogeneration of Reactive Species for UV Curing", John Wiley & Sons, Chichester, 1997.
  18. D. C. Nechers and W. Jager, "Photoinitiation for Polymerization: UV & EB at the Millenium", SITA Technology, London, 1991.
  19. M. Ueda and S. Tokino, Physicochemical Modifications of Fibres and Their Effect on Coloration and Finishing, Rev. Prog. Color ., 26, 9-19(1996).
  20. H. Hong, S. Lee, T. Kim, M. Chung, and C. Choi, Surface Modification of the Polyethyleneimide Layer on Silicone Oxide Film via UV Radiation, Applied Surface Science, 255, 6103-6106(2009). https://doi.org/10.1016/j.apsusc.2009.01.090
  21. E. Kim and J. Jang, Surface Modification of Meta-aramid Films by UV/ozone Irradiation, Fibers and Polymers, 11(5), 677-682(2010). https://doi.org/10.1007/s12221-010-0677-5
  22. J. Jang, S. I. Eom, and Y. H. Kim, Continuous Surface Modification of PET Film via UV Irradiation: Effect of Spectral Irradiance, J. Korean Fiber Soc., 39(1), 100-107(2002).
  23. J. Jang, M. J. Kim, and Y. J. Jeong, Cationic Dyeable Treatment of PET and PTT Fabrics by Continuous $UV/O_3$ Irradiation, J. Korean Fiber Soc., 40(5), 423-430(2003).
  24. Y. K. Jeong, Y. Jeong, and J. Jang, Preferential Face Coating of Knitted PET Fabrics via UV Curing for Water- and Oil-repellent Finish, Textile Coloration and Finishing, 17(6), 27-35(2005).