• Title/Summary/Keyword: UV curing

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A new evaluation method of UV curing process by using electrical properties (I) (전기적 특성을 이용한 UV 경화 프로세스에 대한 새로운 평가방법(I))

  • Lee, Mun-Hag;Kim, Sung-Bin;Lee, Tae-Hoon;Park, Seong-Soo;Son, Se-Mo
    • Journal of the Korean Graphic Arts Communication Society
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    • v.21 no.2
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    • pp.55-65
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    • 2003
  • A novel evaluation method is investigated for UV curing process in printing system. The method is based on the measurement of conducivity change by the photopolymerization of UV curable inks and paints. It is found that the decrease of conductivity is caused by photopolymerization of epoxy monomer during UV curing process of ink film and the by the rate of UV curing. It is possible to make the dynamical evaluation the curing rate of UV curable ink in curing process by this method.

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Preparation of UV protective cotton fabrics by novel UV-curing technique - Using a photocrosslinkable polymer, poly(ethylene glycol) dimethacylate -

  • Kim, Sin-Hee
    • Journal of Fashion Business
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    • v.11 no.6
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    • pp.52-61
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    • 2007
  • To increase the ultraviolet radiation (UVR) protection of cotton fabric, ultraviolet protection (UVP) materials were treated onto cotton fabric using a new technique, UV-curing. A photocrosslinkablepolymer, poly(ethylene glycol) dimethacrylate was used as a UV-curable resin in the presence of a small amount of photoinitiator. Two kinds of UVP materials were used, UV-absorber, 2,2'-dihydroxy-4-methoxy benzophenone, and UV-scatterer, $TiO_2/ZnO$ Pad-dry-cure method in employing these materials onto cotton was also conducted to compare the effectiveness and the washfastness of UVP treatment between curing methods. UVP treated cotton fabric showed a moderate increase in UVP in case of 2,2'-dihydroxy-4-methoxy benzophenone treatment and a high increase in case of $TiO_2/ZnO$. UV-curing method increased the washfastness of UVP property of $TiO_2/ZnO$ treated cotton fabrics. However, in case of 2,2'-dihydroxy-4-methoxy benzophenone, similar wash fastnesses of UV-cured and pad-dry-cured cotton were observed. It can be presumed that 2,2'-dihydroxy-4-methoxy benzophenone was not significantly affected by water since its hydrophobicity. In short, UV-curing of UVP materials onto cotton was successfully done, and treated cotton fabrics showed the increased UVP properties and an increased washfastness in some extent.

Analysis of the shrinkage and warpage of Wafer lens during UV curing (Lens 성형시 UV경화 반응에 따른 수축 및 변형 대한 해석적 접근)

  • Park, Sihwan;Moon, Jong-Sin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.11
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    • pp.6464-6471
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    • 2014
  • The UV curing method is a popular process for lens molding on a unit wafer. This process, however, has several drawbacks including wafer adhesion during the ejection process after curing, errors in lens shape and wafer warpage due to material shrinkage during the curing process, and lens centering errors on both sides of a wafer. Among these, the lens shape error and warpage are influenced directly by the UV curing process due to factors including the UV radiation uniformity, the degree of cure according to UV intensity, and the shrinkage characteristics of the material. Therefore, a theory is needed not only to understand the change in the material characteristics, such as the shrinkage rate due to the curing reaction, but also to establish a model. In addition, an analysis system is needed to realize the model. This study proposes a new analysis method for the wafer lens molding process by Comsol modeling. This method was verified by comparing the results with those of the actual process.

Curing Properties of UV-ccurable Acrylate/Alkyd Resin Blends II (UV-curable Acrylate/Alkyd Resin 혼합계의 경화특성 II)

  • 남수용;이경옥;대평태문;구철회
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.1
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    • pp.157-166
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    • 2000
  • UV-curable resins have adventages of quick set, space saving, clean environment, and efficient use of energy. The polymerization induced phase separation has been studied to solve the problem in UV-curing of thick films and develop the new functional materials. On the exposure to UV irradiation, the dynamic elasticity properties were mesured for mixtures of alkyd resin and UV-cruable monomers which have different molecular structures and molecular weights. The curing rate increases with increasing temperature and UV intensity. In addition, The gel point is strongly influenced by temperature and UV intensity

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Environment-friendly Coating Technology of UV/EB Radiation Curing (친환경 UV/EB 경화형 기능성 코팅 기술)

  • Lee, Jung-Bok;Lee, Jin-Hui;Sung, Ki-Chun
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.1
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    • pp.159-173
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    • 2012
  • UV-Curing technology can be classified into two categories for radical curing and cation curing. It also has mainly focused on surface finishing technology to improve functionality of various substrates such as plastics and metals. On the other hand, EB technology has dealt with cross-linking reactions as well as polymerization process to create novel functional materials. Both technologies have advantages in energy utilizing efficiency and environmental friendly when compared to conventional thermoset coatings. Consequently, UV cured coatings also permits a reduction in the $CO_2$ and VOCs emitted in the drying and curing process. This review mainly shows radical curing technology which is commonly used in UV curing coatings and also describes the technology trends of cation curing which has been attracted attention recently.

Induced phase separation configuration and property of UV curable resin and Alkyd resin blend material (UV경화수지와 알키드수지 복합재료의 상분리 구조와 물성)

  • ;;;;大評泰文
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.2
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    • pp.13-27
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    • 2000
  • The UV curing industry is one of the most wide application fields in the coating and printing inks industry. Applications extend to general coating for paper, board, wood tapes, compact discs and holograms, ink, photoresists for imaging processes and adhesives for welding and sealing in circuit boards. The UV-curing resins have advantages of quick set, space saving, clean environment and efficient use of energy. The purpose of this study has been to control of morphology structures consist of UV-curing resins and alkyd resins. Therefore, we are investigated with regard to rheology properties on the exposure to UV-curing, structures and mechanical properties for curing films.

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Curing Properties of UV-LED Curable Color Coating (UV-LED 경화형 칼라 코팅의 경화특성 연구)

  • Ho, Shin-Chan;Kim, Jong-Gu;Hong, Jin-Who;Ahn, Tae-Jung;Kim, Hyun-Kyoung
    • Journal of Adhesion and Interface
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    • v.13 no.1
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    • pp.31-37
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    • 2012
  • In this study, we investigated the curing properties of UV-LED curable color coating. Specially, the effects of UV-LED wavelength (365, 395, and 405 nm), inert gas, the concentration of photosensitizer, and dual curing on the curing behavior of UV-LED coating systems were studied. The photopolymerization behaviors and the unreacted acrylate groups at Film-air (FA) interface and Film-substrate (FS) interface were investigated by photo differential scanning calorimetry (Photo-DSC) and Fourier-transform infrared spectroscopy with attenuated total reflection (FT-IR/ATR), respectively. Photo-DSC results showed that the heat flow and the ultimate conversion for coating system cured by 405 nm UV-LED were higher than the corresponding values for coating systems cured by 395 and 365 nm UV-LED. FT-IR/ATR results showed that the UV-LED curing systems improved interior and through curing of the coating film, but significantly are affected by oxygen inhibition at FA-interface. The inert environment such as nitrogen purging and the dual curing improved the surface and interior curing of the coating films.

Nondestructive Damage Sensing and Cure Monitoring of Carbon Fiber/Epoxyacrylate Composite with UV and Thermal Curing using Electro-Micromechanical Technique (Electro-Micromechanical 시험법을 이용한 탄소섬유 강화 Epoxyacrylate 복합재료의 UV 및 열경화에 따른 비파괴적 손상 감지능 및 경화 Monitoring)

  • Kong, Jin-Woo;Kim, Dae-Sik;Park, Joung-Man;Lee, Jae-Rock
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.261-264
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    • 2002
  • Interfacial evaluation, damage sensing and cure monitoring of single carbon fiber/thermosetting composite with different curing processes was investigated using electro-micromechanical test. After curing, residual stress was monitored by measurement of electrical resistance (ER) and then it was compared to correlate with various curing processes. In thermal curing, curing shrinkage appeared significantly by matrix shrinkage and residual stress due to the difference in thermal expansion coefficient (TEC). The change in electrical resistance (ΔR) on thermal curing was higher than that on ultraviolet (UV) curing. For thermal curing, apparent modulus was the highest and reaching time until same strain was faster. So far thermal curing shows strong durability on the IFSS after boiling test.

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The Effect of Temperature and Exposure Time on UV-curing of Urethane Acrylate (UV 챔버 내부 온도 및 체류시간이 Urethane Acrylate의 경화속도에 미치는 영향)

  • Moon, Seung-Ho;Kim, Kwang-Hee;Kim, Jeong-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.9
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    • pp.3822-3826
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    • 2012
  • We have studied the effect of temperature and exposure time on the UV curing rate of Urethane Acrylate. UV dose has been modulated by changing the electric power, and temperature has been controled by coating rate and water temperature of the coating roll. Curing rate was evaluated by measuring gel fraction of the cured film. It has been found that effect of coating velocity on the gel fraction of the final film is predominant, but role of temperature of the UV chamber is negligible. These observations imply that exposure time of UV light is critical to have a fully cured film. To better understand the effect of design and operating condition of UV coater on the behavior of UV curing of Urethane Acrylate, we have also conducted heat-flux analysis of UV chamber.

A New Evaluation Method of UV Curing Process by Using Electrical Properties (전기적 특성을 이용한 UV 경화 프로세스에 대한 새로운 평가방법)

  • Lee, Mun-Hag;Kim, Sung-Bin;Son, Se-Mo;Cheon, Jae-Kee
    • Korean Chemical Engineering Research
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    • v.43 no.3
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    • pp.393-400
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    • 2005
  • A novel evaluation method was investigated for measuring the ability of acid amplification of acid amplifier. The method was based on the measurement of conductivity change by the acid generation according to UV radiation. It was found that the decrease of conductivity was caused by photopolymerization of epoxy monomer during UV curing process of ink film and by the rate of UV curing. In this paper, the novel acid amplifiers were synthesized and measured thermal stability by means of DSC. It was found that mono-type acid amplifiers were more stable than di-type. It was possible to make the dynamical evaluation of the curing rate of UV curable ink in curing process by this method.