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Diagnostic Assay of Phenol Ions in Human Tissue

  • Ly, Suw-Young (Biosensor Research Institute, Seoul National University of Technology) ;
  • Lee, Jin-Hui (Department of Chemical Engineering, Seoul National University of Technology) ;
  • Yoo, So-Dam (Department of Chemistry, Sookmyung Womens University) ;
  • Hong, Ki-Won (Department of Chemical Engineering, Seoul National University of Technology) ;
  • Lee, Kyu-Jung (Department of Chemical Engineering, Seoul National University of Technology)
  • Received : 2011.12.07
  • Accepted : 2011.12.20
  • Published : 2011.12.30

Abstract

A voltammetric assay of phenol ions was investigated using three electrode systems of graphite pencil working, reference and counter electrodes. Under optimum analytical parameters, square wave stripping working ranges were attained at a mili range of 10~80 mg/L and a micro range of 20~90 ug/L using seawater electrolyte. The developed sensor was applied to tap water and the human body system of a smoker. It was found that the methods can be applied to in vivo fluid or medicinal diagnosis.

Keywords

References

  1. H. Yi, K. Wu, S. Hu and D. Cui, Adsorption stripping voltammetry of phenol at Nafion-modified glassy carbon electrode in the presence of surfactants, Talanta 55, 1205-1210(2001). https://doi.org/10.1016/S0039-9140(01)00531-8
  2. R. M. de Carvalho, C. Mello, Lauro T. Kubota, Simultaneous determination of phenol isomers in binary mixtures by differential pulse voltammetry using carbon fibre electrode and neural network with pruning as a multivariate calibration tool, Analytica Chimica Acta 420, 109-121(2000). https://doi.org/10.1016/S0003-2670(00)01012-6
  3. Silvana Andreescu, Daniel Andreescu, Omowunmi A. Sadik, A new electrocatalytic mechanism for the oxidation of phenols at platinum electrodes, Electrochemistry Communications 5, 681-688(2003). https://doi.org/10.1016/S1388-2481(03)00166-8
  4. M. Saeed ,M. Depala I , D. H. Craston and I. G. M. Anderson, Application of Capillary Electrochromatography (CEC) for the Analysis of Phenols in Mainstream and Sidestream Tobacco Smoke, Chromatographia, 49(7/8), 391-398(1999). https://doi.org/10.1007/BF02467612
  5. E. Baltussen,F. David, Pat Sandra, H.-G. Janssen, C. Cramers, Automated Sorptive Extraction-Thermal Desorption-Gas Chromatography-Mass Spectrometry Analysis: Determination of Phenols in Water Samples, J. Microcolumn Separations, 116, 471-474(1999).
  6. T. N. Ermolaeva, T. L. Lavrent''eva, A. E. Seredkin and Ya. I. Korenman, A Sensitive Piezoelectric Crystal Sensor for Analyzing Phenols in Air, Russian Journal of Applied Chemistry, 74(2), 1993204(2001)
  7. V. Andrei, O. Pirogov and A. Shpigun, Application of water-soluble polymers as modifiers in electrophoretic analysis of phenols, Electrophoresis, 24, 2099-2105(2003). https://doi.org/10.1002/elps.200305417
  8. G. Marrubini, E. Calleri, T. Coccini, A. F. Castoldi and L. Manzo, Direct Analysis of Phenol, Catechol and Hydroquinone in Human Urine by Coupled-Column HPLC with Fluorimetric Detection, Chromatographia, 62, July 25-31(2005). https://doi.org/10.1365/s10337-005-0570-3
  9. Y.J. Feng and X.Y. Li, Electro-catalytic oxidation of phenol on several metal-oxide electrodes in aqueous solution, Water Research 37, 2399-2407(2003). https://doi.org/10.1016/S0043-1354(03)00026-5
  10. M. Pakuła, M. Walczyk, S. Biniak and A. S. tkowski, Electrochemical and FTIR studies of the mutual influence of lead(II) or iron(III) and phenol on their adsorption from aqueous acid solution by modified activated carbons, Chemosphere, 69, 209-219(2007). https://doi.org/10.1016/j.chemosphere.2007.04.028
  11. N. G. Simoes, V. V. Cardoso, E. Ferreira, M. J. Benoliel and C. M. M. Almeida, Experimental and statistical validation of SPME-GC-S analysis of phenol and chlorophenols in raw and treated water, Chemosphere 68, 501-510(2007). https://doi.org/10.1016/j.chemosphere.2006.12.057
  12. S. C. Moldoveanu and M. Kiser, Gas chromatography/mass spectrometry versus liquid chromatography/fluorescence detection in the analysis of phenols in mainstream cigarette smoke, Journal of Chromatography A, 1141, 90-97(2007). https://doi.org/10.1016/j.chroma.2006.11.100
  13. D. A. Palnero and J. V. Arean, Analysis of Phenol in an Over-the-Counter Sore Throat Spray by Cyclic Voltammetry, Journal of pharmaceutical sciences, 90, 2, 165- 171(2001). https://doi.org/10.1002/1520-6017(200102)90:2<165::AID-JPS7>3.0.CO;2-E
  14. R.H. Carvalho, M.A.N.D.A. Lemos, F. Lemos, J.M.S. Cabral, F and R. Ribeiro, Electro-oxidation of phenol on zeolite/graphite composite electrodes Part 2. Influence of zeolite type and composition, Journal of Molecular Catalysis A: Chemical, 253, 170-75(2006). https://doi.org/10.1016/j.molcata.2006.03.034
  15. H. Wang, J. Wang, Electrochemical degradation of 4-chlorophenol using a novel Pd/C gas-diffusion electrode, Applied Catalysis B: Environmental, 77, 58-5(2007). https://doi.org/10.1016/j.apcatb.2007.07.004
  16. J. Iniesta, P.A. Michaud, M. Panizza, G. Cerisola, A. Aldaz,Ch. Comninellis, Electrochemical oxidation of phenol at boron-doped diamond electrode, Electrochimica Acta, 46, 3573-3578(2001). https://doi.org/10.1016/S0013-4686(01)00630-2
  17. M. A. Ghanem, R. G. Comptob, B. A. Colesb, E. Psillakis, M. A. Kulandainathan and F. Marken, Microwave activation of electrochemical processes: High temperature phenol and triclosan electro-oxidation at carbon and diamond electrodes, Electrochimica Acta, 53, 1092-1099(2007). https://doi.org/10.1016/j.electacta.2007.01.065
  18. S. Hu, C. Xu, G. Wang and D. Cui, Voltammetric determination of 4-nitrophenol at a sodium montmorillonite-anthraquinone chemically modified glassy carbon electrode, Talanta, 54, 115-123(2001). https://doi.org/10.1016/S0039-9140(00)00658-5
  19. X. Liu, Y. Ji, Y. Zhang, H. Zhang , M. Liu, Oxidized multiwalled carbon nanotubes as a novel solid-phase micro extraction fiber for determination of phenols in aqueous samples, Journal of Chromatography A, 1165, 10-17(2007). https://doi.org/10.1016/j.chroma.2007.07.057
  20. Z. Q. Zhang, H. Liu, H. Zhang and Y. F. Li, Simultaneous cathodic stripping voltammetric determination of mercury, cobalt, nickel and palladium by mixed binder carbon paste electrode containing dimethylglyoxime, Analytica Chimica Acta, 333, 119-124(1996). https://doi.org/10.1016/0003-2670(96)00241-3