Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Highly Selective Synthesis of β-Amino Carbonyl Compounds over ZSM-5-SO3H under Solvent-free Conditions

  • Massah, Ahmad Reza (Department of Chemistry, Islamic Azad University Shahreza Branch) ;
  • Kalbasi, Roozbeh Javad (Department of Chemistry, Islamic Azad University Shahreza Branch) ;
  • Samah, Neda (Department of Chemistry, Islamic Azad University Shahreza Branch)
  • Received : 2010.12.10
  • Accepted : 2011.02.17
  • Published : 2011.05.20
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Abstract

ZSM-5-$SO_3H$ efficiently catalyzed the one-pot three-component Mannich reaction of aldehydes, anilines, and ketones. ${\beta}$-Aminocarbonyl compounds were obtained in reasonable yields and excellent stereoselectivities when the reaction was carried out at room temperature under solvent-free conditions. Simple experimental conditions and product isolation procedure makes this protocol potential for the development of clean and environment-friendly strategy for the synthesis of ${\beta}$-amino-ketones. The catalyst was recovered and reused for subsequent runs.

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References

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