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Characteristics of high energy density hybrid capacitor using metal oxide electrode

금속산화물 전극을 사용한 고 에너지밀도 하이브리드 커패시터 특성

  • Yoon, Hong-Jin (Department of Chemical Engineering, Chungbuk National Univ.) ;
  • Shin, Yoon-Sung (Department of Chemical Engineering, Chungbuk National Univ.) ;
  • Lee, Jong-Dae (Department of Chemical Engineering, Chungbuk National Univ.)
  • Received : 2011.09.03
  • Accepted : 2011.09.23
  • Published : 2011.09.30

Abstract

The electrochemical performances of an asymmetric hybrid capacitor were investigated using $LiFePO_4$ as the positive electrode and active carbon fibers(ACF) as the negative electrode. The electrochemical behaviors of a nonaqueous hybrid capacitor were characterized by constant current charge/discharge test. The specific capacitance using $LiFePO_4$/ACF electrode turned out to be $0.87F/cm^2$ and the unit cell showed excellent cycling performance. This hybrid capacitor was able to deliver a specific energy as high as 178 Wh/kg at a specific power of 1,068 W/kg.

Keywords

References

  1. B. E. Conway, Transition from 'Supercapacitor' to 'Battery' Behavior in Electrochemical Energy Storage, J. Electrochem. Soc., 138, 1539(1991). https://doi.org/10.1149/1.2085829
  2. X. W. Huang, Z. W. Xie, X. Q. He, H. Z. Sun, C. Y. Tong, and D. M. Xie, Electric double layer capacitors using activated carbon prepared from pyrolytic treatment of sugar as their electrodes, Synth. Met., 135, 235(2003).
  3. B. E. Conway, "Electochemical Superconducts: sientific fundmentals and technological appliaction", Kluwer Academic, New York, 105(1999).
  4. C. Y. Kang, M. G. Kang, and J. D. Lee, Preparation of mesoporous carbon using ion exchange, J. Kor. Oil Chem. Soc., 26, 328(2009).
  5. T. Aida, I. Murayama, K. Yamada, and M. Morita, Analyses of capacity loss and improvement of cycle performance for a high-voltage hybrid electrochemical capacitor, J. Electrochem. Soc., 154, 798(2007).
  6. I. H. Kim, and K. B. Kim, Electrochemical characterization of hydrous ruthenium oxide thin-film electrodes for electrochemical capacitor applications, J. Electrochem. Soc., 153, 383(2006). https://doi.org/10.1149/1.2147406
  7. M. S. Wu, Y. A. Huang, C. H. Yang, and J. J. Jow, Electrodeposition of nanoporous nickel oxide film for electrochemical capacitors, Int. J. Hydrogen Energy, 32, 4153(2007). https://doi.org/10.1016/j.ijhydene.2007.06.001
  8. B. E. Conway, and W. G. Pell, Doublelayer and pseudocapacitance types of electrochemical capacitors and their applications to the development of hybrid devices, J. Solid State Electrochem., 7, 637(2003). https://doi.org/10.1007/s10008-003-0395-7
  9. S. W. Woo, K. Dokko, and K. Kanamura, Composite electrode composed of bimodal porous carbon and polypyrrole for electrochemical capacitors, J. Power Sources, 185, 1589(2008). https://doi.org/10.1016/j.jpowsour.2008.08.035
  10. B. C. Kim, J. M. Ko, and G. G. Wallace, A novel capacitor material based on Nafion-doped polypyrrole, J. Power Sources, 177, 665(2008). https://doi.org/10.1016/j.jpowsour.2007.11.078
  11. J. Zhang, L. B. Kong, B. Wang, Y. C. Luo, and L. Kang, In-situ electrochemical polymerization of multi-walled carbon nanotube/polyaniline composite films for electrochemical supercapacitors, Synth. Met., 159, 260(2009). https://doi.org/10.1016/j.synthmet.2008.09.018
  12. Y. G. Wang, and Y. Y. Xia, A new concept hybrid electrochemical surpercapacitor Carbon/$LiMn_{2}O_{4}$ aqueous system, Electrochem. Commun., 7, 1138(2005). https://doi.org/10.1016/j.elecom.2005.08.017
  13. S. B. Ma, K. W. Nam, W. S. Yoon, X. Q. Yang, K. Y. Ahn,K. H. Oh, and K. B. Kim, A novel concept of hybrid capacitor based on manganese oxide materials, Electrochem. Commun., 9, 2807(2007). https://doi.org/10.1016/j.elecom.2007.09.015
  14. J. H. Yoon, H. J. Bang, J. Prakash, and Y. K. Sun, Comparative study of $Li[Ni_{1/3}Co_{1/3}Mn_{1/3}]O_{2}$ cathode material synthesized via different synthetic routes for asymmetric electrochemical capacitor applications, Matt. Chem. Phy., 110, 222(2008). https://doi.org/10.1016/j.matchemphys.2008.01.032
  15. M. S. Lee, Y. S. Sing, and J. D. Lee, Effect of pore structure on electrochemical performance of EDLC, J. Kor. Oil Chem. Soc., 27, 310(2011).
  16. H. J. Yoon, C. H. Lee, and J. D. Lee, The electrochemical characteristics of EDLC with various activated carbons, J. Kor. Oil Chem. Soc., 28, 225(2011).
  17. C. Y. Kang, Y. S. Sin, and J. D. Lee, The electrochemical characteristics of mesopore carbon fiber for EDLC electrode, Korean Chem. Eng. Res., 49, 10(2011). https://doi.org/10.9713/kcer.2011.49.1.010